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Multiscale modeling of diffusion in elastic composite materialsKaessmair, Stefan, Steinmann, Paul 13 February 2020 (has links)
Our research features diffusion in elastically deformable solids with complex microstructure. A
prominent example are electrodes of Li-ion batteries which are typically a porous compound consisting
of a binder, conductive particles, and active particles, filled with an electrolyte. The charge and discharge
processes are complex multi-physics problems. Based on the used materials, they may include chemical
reactions, electrochemically driven diffusion, separation into lithium poor and lithium rich regions in
the active particles, or swelling phenomena [1]. Here, we consider a simplified version of this problem
restricting ourselves to diffusion in an elastic matrix-particle composite. In the matrix, the transport of
the mobile species is described using a Fickian-type flux driven by the gradient of the chemical potential.
In the particles, the mobile species tends to accumulate and build separate regions of equal concentration
– either high or low. This behavior is modeled using the Cahn-Hilliard equation.
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