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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Multiscale modeling of diffusion in elastic composite materials

Kaessmair, Stefan, Steinmann, Paul 13 February 2020 (has links)
Our research features diffusion in elastically deformable solids with complex microstructure. A prominent example are electrodes of Li-ion batteries which are typically a porous compound consisting of a binder, conductive particles, and active particles, filled with an electrolyte. The charge and discharge processes are complex multi-physics problems. Based on the used materials, they may include chemical reactions, electrochemically driven diffusion, separation into lithium poor and lithium rich regions in the active particles, or swelling phenomena [1]. Here, we consider a simplified version of this problem restricting ourselves to diffusion in an elastic matrix-particle composite. In the matrix, the transport of the mobile species is described using a Fickian-type flux driven by the gradient of the chemical potential. In the particles, the mobile species tends to accumulate and build separate regions of equal concentration – either high or low. This behavior is modeled using the Cahn-Hilliard equation.

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