Hearing loss, as a result of old age, has been linked to a decline in speech perception despite the use of additional listening devices. Even though the relationship between hearing loss and decreased speech perception has been well established, research in this area has often focused on the behavioral aspects of language and not on the functionality of the brain itself. In the present study, the mismatch negativity, an event related potential, was examined in order to determine the differences in speech perception between young adult participants, geriatric normal hearing participants, and geriatric hearing-impaired participants. It was hypothesized that a significantly weaker mismatch negativity would occur in the geriatric hearing-impaired participants when compared to the young adult participants and the geriatric normal hearing participants. A passive same/different discrimination task was administered to 10 young adult controls (5 male, 5 female) and eight older adult participants with and without hearing loss (4 male, 4 female). Data from behavioral responses and event related potentials were recorded from 64 electrodes placed across the scalp. Results demonstrated that the mismatch negativity occurred at various amplitudes across all participants tested; however, an increased latency in the presence of the mismatch negativity was noted for the geriatric normal hearing and the geriatric hearing-impaired participants. Dipoles reconstructed from temporal event related potential data were located in the cortical areas known to be instrumental in auditory and language processing for the young adult participants; however, within the geriatric normal hearing and the geriatric hearing-impaired participants, dipoles were seen in multiple locations not directly associated with language and auditory processing. Although not conclusive, it appears that within the geriatric normal hearing and the geriatric hearing-impaired participants there is slower processing of the speech information, as well as some cognitive confusion which leads to fewer available resources for interpretation.

Interstellar plasma — interstellar clouds in particular — play an important role in determining the structure and evolution of galaxies. Understanding the time evolution of such plasmas requires knowledge of the chemical processes that drive their dynamics. Two processes are studied in this dissertation: radiative electron attachment (REA) via dipole-bound states (DBSs) and dissociative recombination (DR). Of the several hundred molecules detected in the interstellar medium, only eight anions have been detected: CN-, C3N-, C5N-, C7N-, C4H-, C6H-, C8H-, and C10H-. Their production mechanism is not well known; REA was suggested as a possible formation pathway, but previous theoretical studies have found that REA rate coefficients were too low to explain the formation of CN-, C3N-, and C5N-. It was later suggested that including DBSs — an electron weakly bound at a large distance to the large dipole moment of a neutral molecule — could appreciably enhance the REA rate coefficients. The first portion of this study is dedicated to investigating the role of the large dipole moment of rotating C3N using an accurate \it ab initio approach with electronic and rotational resolution. DBS wavefunctions of C3N- are calculated and used to obtain REA cross sections that produce even smaller rate coefficients, suggesting that C3N- is efficiently formed by a different process. The second part of this study investigates DR in the difficult case of molecules with low-lying eletronic resonances, although these are not necessary for the approach. An approach to treat both direct and indirect mechanisms of DR in a diatomic ion with electronic, vibrational, and rotational resolution using R-matrix scattering calculations, frame transformation theory, and multichannel quantum defect theory is presented and applied to the CH+ and CF+ molecular ions at low collision energies. The calculated CH+ cross sections agree well with recent rotationally state-resolved experimental results and overall better than previous theoretical results. The calculated CF+ cross sections agree well with experimental results, although these do not have rotational resolution, and overall better than previous theoretical results at low energies. Additionally, the method can study rovibronic (de-)excitation — a process in competition with DR. These are calculated and compared to previous theoretical calculations for CH+, which which our results agree well with the exception of dipole-driven rotational excitation cross sections. This discrepancy is tentatively attibuted to negelcting the contribution of higher partial waves in the description of the incident electron, which will be incorporated in future studies.

In this dissertation we have studied nearield phenomena in dipole radiation. We have studied first the energy flow patterns of the radiation emitted by an electric dipole located in between parallel mirrors. The field lines of the Poynting vector have intricate structures, including many singularities and vortices. For a dipole parallel to the mirror surfaces, vortices appear close to the dipole. Vortices are located where the magnetic field vanishes. Also, a radiating electric dipole near the joint of two orthogonal mirrors is considered, and also here we find numerous singularities and vortices in the energy flow patterns. We have also studied the current density in the mirrors. Next we have studied the reflection of radiation by and the transmission of radiation through an interface with an  -near-zero (ENZ) material. For p polarization, we find that the reflection coefficient is -1, and the transmission coefficient is zero for all angles of incidence. The transmitted electric field is evanescent and circularly polarized. The transmitted magnetic field is identically zero. For s polarization, the transmitted electric field is s polarized and the transmitted magnetic field is circularly polarized. The next topic was the study of the force exerted on the dipole by its own reflected field near an ENZ interface. We found that, under certain circumstances, it could be possible that the dipole would levitate in its reflected field. This levitation is brought about by evanescent reflected waves. Finally, power emission by an electric dipole near an interface was considered. We have derived expressions for the emitted power crossing an interface. The power splits in contributions from traveling and evanescent incident waves. We found that for an ENZ interface, only evanescent dipole waves penetrate the material, but there is no net power flow into the material.

No description available.

This dissertation consists of three major studies. The first study, described in Chapter 3, focuses on the experimental work we carried out; experimental study of the electronic transition dipole moment matrix elements (TDMM) for the and electronic transitions of the sodium dimer molecule. Here we obtained the electronic transition dipole moments through Autler-Townes and resolved fluorescence spectroscopy and compared them to the theory. The second study, described in Chapter 4, is on sodium dimer ion-pair states. In this work, we calculated the radiative lifetimes and electronic transition dipole moments between Na2 ion-pair states ( , , , ) and state. This study was published in 2015. The last study, described in Chapter 5, is the total lifetime (bound-bound plus bound-free) and transition dipole moment calculations of the ion-pair electronic states, , of the lithium dimer molecule. / Physics

Yes / In this letter a novel on-chip array antenna is investigated which is based on CMOS 20μm Silicon technology for operation over 0.6-0.65 THz. The proposed array structure is constructed on three layers composed of Silicon-Ground-Silicon layers. Two antennas are implemented on the top layer, where each antenna is constituted from three sub-antennas. The sub-antennas are constructed from interconnected dual-rings. Also, the sub-antennas are interconnected to each other. This approach enhances the aperture of the array. Surface waves and substrate losses in the structure are suppressed with metallic via-holes implemented between the radiation elements. To excite the structure, a novel feeding mechanism is used comprising open-circuited microstrip lines that couple electromagnetic energy from the bottom layer to the antennas on the top-layer through metasurface slot-lines in the middle ground-plane layer. The results show the proposed on-chip antenna array has an average radiation gain, efficiency, and isolation of 7.62 dBi, 32.67%, and -30 dB, respectively. / H2020-MSCA-ITN-2016 SECRET-722424 and the financial support from the UK Engineering and Physical Sciences Research Council (EPSRC) under grant EP/E0/22936/1

Yes / The main objective of this work is to investigate the combinatory effects of both uniaxial magnetic and electrical anisotropies on the input impedance, resonant length and the mutual coupling between two dipoles printed on an anisotropic grounded substrate. Three different configurations: broadside, collinear and echelon are considered for the coupling investigation. The study is based on the numerical solution of the integral equation using the method of moments through the mathematical derivation of the appropriate Green’s functions in the spectral domain. In order to validate the computing method and evaluated Matlab® calculation code, numerical results are compared with available literature treating particular cases of uniaxial electrical anisotropy; good agreements are observed. New results of dipole structures printed on uniaxial magnetic anisotropic substrates are presented and discussed, with the investigation of the combined electrical and magnetic anisotropies effect on the input impedance and mutual coupling for different geometrical configurations. The combined uniaxial (electric and magnetic) anisotropies provide additional degrees of freedom for the input impedance control and coupling reduction. / This work is part of the POSITION-II project funded by the ECSEL joint Undertaking under grant number Ecsel-7831132-Postitio-II-2017-IA,www. position-2.eu and partly funded by FCT/MCTES through national funds and when applicable co-funded EU funds under the project UIDB/50008/2020- UIDP/50008/2020. This work was also supported in part by the DGRSDT (General Directorate of Scientific Research and Technological Development) - MESRS (Ministry of Higher Education and Scientific Research), Algeria, and RTI2018-095499-B-C31, Funded by Ministerio de Ciencia, Innovación y Universidades, Gobierno de España (MCIU/AEI/FEDER,UE).

In the search for molecular species in the interstellar medium and extraterrestrial planetary atmospheres, theoretical methods continue to be an invaluable tool to astronomically minded chemists. Using state-of-the art methods, this doctoral work characterizes the electronically excited states of interstellar radicals, cations, and even rare anions and also predicts the gas phase fundamental vibrational frequencies of the cis and trans-HOCO radicals, as well as the cis-HOCO anion. First, open-shell coupled cluster methods of singles and doubles (CCSD) and singles and doubles with triples-inclusion (CC3) are tested on the C₂H and C₄H radicals. The significant double-excitation character, as well as the quartet multiplicity of some states yields inaccurate excitation energies and large spin contamination with CCSD. CC3 somewhat improves this for select states, but discrepancies between CC and multireference results for certain states exist and likely arise from the lack of spin adaptation in conventional spin-orbital CC. Next, coupled-cluster methods predict the presence of an excited state of the closed-shell allyl cation and its related H₂CCCHCH₂⁺ cousin at 443 nm near an unidentified laboratory peak at 442.9 nm which is also close to one of the largest unattributed interstellar absorption features. Additionally, the dipole moments, electron binding energies, and excited states of neutral radicals and corresponding closed-shell anions of interstellar interest are also computed. These are calibrated against experimental data for CH₂CN⁻ and CH₂CHO⁻. Since coupled cluster theory closely reproduces the known experimental data, dipole-bound excited states for eight previously unknown anions are predicted: CH2SiN⁻ , SiH₂CN⁻, CH₂SiHO⁻, SiN⁻, CCOH⁻, HCCO⁻, SiCCN⁻, and SiNC⁻. In addition, we predict the existence of one rare valence-bound excited state of CH₂SiN⁻ and also SiCCN⁻ as well as even rarer two valence-bound states of CCSiN⁻. Lastly, the reaction of CO + OH and its transient potential intermediate, the HOCO radical, may be responsible for the regeneration of CO₂ in the Martian atmosphere, but past spectroscopic observations have not produced a full gas-phase set of the fundamental vibrational frequencies of the HOCO radical. Using established, highly-accurate quantum chemical coupled cluster tech- niques and quartic force fields, all six fundamental vibrational frequencies for 1 ²A′ cis and trans-HOCO and 1 ¹A′ cis-HOCO⁻ are computed in the gas phase. / Ph. D.

After being theorized by Veselago in 1967, recent developments in metamaterials over the last two decades have allowed scientists and researchers to physically demonstrate that artificial composite media can be engineered to exhibit exotic material properties, such as negative refractive index, by exploiting features in arrays of sub-wavelength unit inclusions. These unconventional electromagnetic properties are realized through the coupling of the microscopic unit inclusions, which govern the macroscopic properties of the structure. After demonstrating that a periodic array of capacitively-loaded loop (CLL) inclusions paired with continuous wire results in negative refraction, this study performs numerical simulations to characterize random metamaterial structures. These structures consist of CLLs that are randomized in both position and orientation. In addition, this thesis introduces an innovative antenna enhancing structure consisting of capacitively-loaded loop (CLL) metamaterial elements loaded radially around a standard dipole antenna at an electrically small distance. As a result of this innovative arrangement, the dipole antenna is easily transformed into a directive mechanically scanned antenna with high realized gain. The desired directivity and gain can be tuned based on the number of radial CLL fins placed around the dipole. Interactions between the antenna and metamaterial elements result in significant enhancement of the maximum radiated field amplitude and front-to-back ratio. This innovative CLL-loaded dipole antenna is compared to the conventional Yagi-Uda antenna. The structures presented in this thesis are modeled using full-wave simulation, and one antenna structure is experimentally verified as a proof-of-concept. / Master of Science

The Super Dual Auroral Radar Network (SuperDARN) is an international collaboration of researchers interested in Earth's near-space plasma environment. This group uses high frequency (HF) radars and backscatter from magnetic field-aligned plasma irregularities to study space weather manifested in the Earth's magnetosphere and ionosphere. Space weather impacts many technological systems including Global Positioning System (GPS), spacecraft orbits, power distribution, surveillance radar, HF communications and transpolar aviation. This thesis explores, in detail, the techniques and challenges of constructing, testing, and operating a newly designed SuperDARN HF radar. In modern times, the use of such frequencies for radar is limited to very specific applications and thus the topics presented are not common place. A new antenna design, the twin terminated folded dipole (TTFD), is analyzed along with the modeling results for several proposed and constructed phased arrays for this design. Finally, an initial radiation pattern measurement for the TTFD is presented and notes on how a similar measurement might be conducted on a TTFD phased array. / Master of Science