The purpose of this research was to explore two ways of the application of chitosan, a biopolymer, for ink jet printing of textiles. 1) To apply chitosan as a post-treatment on the fabric ink jet printed with pigment based inks for the fixation of pigments on the fabric. 2) To incorporate chitosan as a binder in pigment based ink jet ink formulations. The incorporation of chitosan was carried out in two ways. 1) Direct addition of chitosan into the ink formulations containing surface modified pigments. 2) Preparation of chitosan encapsulated pigment nanoparticles using complex coacervation technique and using these nanoparticles for the formulation of ink jet ink. The degree of deacetylation (DD) was determined using FTIR spectroscopy. Various protocols proposed by researchers were used to determine the DD of chitosan samples used in the present study. The protocol proposed by Raut was found to be fairly accurate in determining the DD of chitosan samples. The molecular weight of chitosan was estimated using dilute solution viscometry method. The characterisation of the film forming ability of chitosan was evaluated using scanning electron microscopy (SEM). The colour strength (K/S), colour difference, colour characteristics and colour fastness to laundering and rubbing of ink jet printed fabrics post treated with chitosan were evaluated using standard methods. Post-treatment (pad-dry-cure method) of cotton fabric ink jet printed with pigment based inks revealed that chitosan could effectively fix the pigments on cotton compared to the commercial textile binders and the water-soluble derivative of chitosan. The chemical interaction between chitosan and cotton fabric was illustrated by FTIR-ATR analysis and through determination of carboxyl group content. The ink jet printed cotton fabric post treated with 3gpl chitosan (MW 156,156) maintained almost 86% of bacterial reduction against Klebsiella Pneumoniae even after 50 launderings. Inks containing chitosan were formulated and were found to be stable in terms of mean particle size and viscosity over a period of one month and for 4 freeze/thaw cycles. A magenta ink containing chitosan was selected for ink jet printing of cotton fabric. It was found that the DF was around 97% for magenta ink containing chitosan compared to around 53% fixation for magenta ink without chitosan on cotton fabric. Surface modified carbon black pigment with carboxylated (COO-) surface functionality was selected to prepare chitosan encapsulated pigment nanoparticles by complex coacervation technique. Chitosan encapsulated pigment nanoparticles with mean particle size diameter of 876 nm and 742 nm were formed when 5 ml of 0.1% w/v pigment was mixed with 2ml and 3ml of 0.1% w/v chitosan, respectively. However, no correlation was found between the particle size of the nanoparticles formed and the concentration of chitosan. The DF with ink containing chitosan encapsulated pigment nanoparticles was found to be around 98% while the blank ink with only surface modified carbon black pigment showed 44% fixation.

<p>Flexographic printing is a process that employs a flexible printing form and low viscous ink, often water-based. The flexible printing form is favourable for printing on rough surfaces, but the high surface tension of the ink may cause printability problems.</p><p>This work has focused on the interaction between paper/paperboard coating and water-based flexographic ink, aimed at increasing the knowledge about the printing process in form of physical/chemical parameters that are important for ink setting. The effects of printing conditions on print quality, such as printing pressure and temperature, have also been in focus.</p><p>The work has shown that fluids of different polarities, i.e. different dipole moments, behave differently when being absorbed by a coating layer. Due to their chemical compatibility to the coating layer, fluids with large dipole moment fill the pore matrix of the coating to a lesser extent but penetrate further into the coating than fluids with small dipole moments. On the other hand, polarity of the coating layer also affects the print. When printing on coatings with different polarities, higher print densities was obtained on the more polar substrates. As a tentative explanation, it is proposed that the ink builds different layer structures during drying depending on the coating polarity.</p><p>Print gloss is related to the ink setting which, in turn, is affected by the solvent retaining capacity of the ink. Large water holding capacity allows the ink components to smoothen out before the structure is set, resulting in a higher print gloss. The rheology of inks is affected by temperature; at a higher temperature the viscosity is reduced. The reduction in ink viscosity at higher temperature has been shown to affect the print quality, e.g., print density and dot gain. It is suggested that a thicker layer is immobilised during impression due to the lower viscosity and that it is an explanation of the higher print density at a higher printing temperature.</p><p>The influence of impression pressure on dot gain has been experimentally evaluated and mathematically modelled with good agreement. The dot gain is shown to respond non-linearly to the applied printing pressure.</p><p>Studies based on pilot coated and printed paperboards is also reported, and it is shown that the print quality, e.g. print density, print gloss and dot gain, is largely dependent on the type of ink chosen and on the coating characteristics. Higher clay content in the coating resulted in increased dot gain and a decreased mottling.</p>

A numerical model has been developed to simulate the firing of an inkjet printhead. The model evaluates the heat generation and diffusion within the thin film structure, the phase change and vapor bubble growth in the ink, and the subsequent flow of ink from the orifice. The heat transfer is modeled numerically throughout the printhead's thin film structure and ink through an asymptotic integration algorithm. The bubble growth and fluid flow are coupled and modeled through conservation of momentum, conservation of energy, and state equations. The heat transfer model has been validated with simple theoretical solutions and ink drop weight and velocity have been compared to empirical data. To test the usefulness of the model as a design tool, parametric studies have been made which characterize pen performance as a function of several system parameters. The results show that although the model does not reflect every detail in the firing process, it is useful for predicting trends and investigating new design concepts. / Graduation date: 1997

There is much debate in the design community concerning how to make an easy-to-understand graph. While expert designers recommend including as little non-data ink as possible, there is little empirical evidence to support their arguments. Non-data ink refers to any ink on a graph that is not required to display the graph's data. As a result of the lack of strong evidence concerning how to design graphs, there is widespread confusion when it comes to best practices. This paper describes a preliminary study of graph perception and learning using an eye-tracking system at UNC's School of Information and Library Science.

Additive manufacturing processes, which utilize selective deposition of material rather than traditional subtractive methods, are very promising due to their ability to build complex, highly specific geometries in short periods of time. Three-dimensional direct inkjet printing is a relatively new additive process that promises to be more efficient, scalable, and financially feasible than others. Due to its novelty, however, numerous technical challenges remain to be overcome before it can attain widespread use. This thesis identifies those challenges and finds that material limitations are the most critical at this point. In the case of deposition of high viscosity polymers, for example, it is found that droplet formation is a limiting factor. Acoustic resonance jetting, a technology recently developed at Georgia Institute of Technology, may have the potential to address this limitation because it generates droplets using a physical mechanism different from those currently in use. This process focuses ultrasonic waves using cavity resonances to form a standing wave with high pressure gradients near the orifice of the nozzle, thereby ejecting droplets periodically. This thesis reports initial exploratory testing of this technologys performance with various material and process parameters. In addition, analytical and numerical analyses of the physical phenomena are presented. Results show that, while the pressures generated by the system are significant, energy losses due to viscous friction within the nozzle may prove to be prohibitive. This thesis identifies and begins evaluation of many of the process variables, providing a strong basis for continued investigation of this technology.

Flexographic printing is a process that employs a flexible printing form and low viscous ink, often water-based. The flexible printing form is favourable for printing on rough surfaces, but the high surface tension of the ink may cause printability problems. This work has focused on the interaction between paper/paperboard coating and water-based flexographic ink, aimed at increasing the knowledge about the printing process in form of physical/chemical parameters that are important for ink setting. The effects of printing conditions on print quality, such as printing pressure and temperature, have also been in focus. The work has shown that fluids of different polarities, i.e. different dipole moments, behave differently when being absorbed by a coating layer. Due to their chemical compatibility to the coating layer, fluids with large dipole moment fill the pore matrix of the coating to a lesser extent but penetrate further into the coating than fluids with small dipole moments. On the other hand, polarity of the coating layer also affects the print. When printing on coatings with different polarities, higher print densities was obtained on the more polar substrates. As a tentative explanation, it is proposed that the ink builds different layer structures during drying depending on the coating polarity. Print gloss is related to the ink setting which, in turn, is affected by the solvent retaining capacity of the ink. Large water holding capacity allows the ink components to smoothen out before the structure is set, resulting in a higher print gloss. The rheology of inks is affected by temperature; at a higher temperature the viscosity is reduced. The reduction in ink viscosity at higher temperature has been shown to affect the print quality, e.g., print density and dot gain. It is suggested that a thicker layer is immobilised during impression due to the lower viscosity and that it is an explanation of the higher print density at a higher printing temperature. The influence of impression pressure on dot gain has been experimentally evaluated and mathematically modelled with good agreement. The dot gain is shown to respond non-linearly to the applied printing pressure. Studies based on pilot coated and printed paperboards is also reported, and it is shown that the print quality, e.g. print density, print gloss and dot gain, is largely dependent on the type of ink chosen and on the coating characteristics. Higher clay content in the coating resulted in increased dot gain and a decreased mottling.

No description available.

No description available.

Exegesis (MA--Art and Design) -- AUT University, 2007. / Includes bibliographical references. Also held in print (ii, 50 leaves : col. ill. ; 21 x 30 cm.) in City Campus Collection (T 779.0993 XU)

Thesis (DDes) - National Institute for Design Research, Swinburne University of Technology, 2008. / Submitted in partial fulfillment of the requirements of the degree of Professional Doctorate in Design, National Institute for Design Research, Faculty of Design, Swinburne University of Technology - 2008. Typescript. Submitted in partial fulfilment of the requirements for the degree of Professional Doctorate in Design, National Institute for Design Research, Faculty of Design Research, Swinburne University of Technology, 2008. Bibliography: p. 108-115.