Intraplate volcanism is a worldwide phenomenon producing volcanoes away from active plate boundaries, a process that cannot yet be sufficiently explained by plate tectonic processes, and thus is still a missing piece in the understanding of the dynamics and evolution of our planet. Models for the formation of intraplate volcanism are dominated by mantle plumes, but alternative explanations, such as adiabatic decompression triggered by lithospheric delamination, and edge driven convection (EDC), could be responsible for magmatism. This dissertation explores intraplate volcanic locations that do not fit the mantle plume model, and presents geochemical evidence for lithospheric delamination and edge driven convection for the cause of volcanism. I studied an Eocene volcanic swarm exposed in the Appalachian Valley and Ridge Province of Virginia and West Virginia, which are the youngest known igneous rocks along the Eastern North American Margin (ENAM). These magmas provide the only window into the most recent deep processes contributing to the post-rift evolution of this margin. This study presents the first high precision 40Ar/39Ar ages along with new geochemical data, and radiogenic isotopes that constrain the melting conditions and the timing of emplacement. Modeling of the melting conditions suggests that melting occurred under conditions slightly higher than average mantle beneath mid-ocean ridges. Asthenosphere upwelling related to localized lithospheric delamination is a possible process that can explain the intraplate signature of these magmas that lack evidence of a thermal anomaly. The Virginia-West Virginia region of the ENAM also preserves a second post-rift magmatic event in the Late Jurassic. By studying both the Late Jurassic and Eocene magmatic events we can better understand the post-rift evolution of passive margins. This study presents a comprehensive set of geochemical data that includes new 40Ar/39Ar ages, major and trace-element compositions, and analysis of radiogenic isotopes to further constrain their magmatic history. Modeling suggests that the felsic volcanics from both the Late Jurassic and Eocene events are consistent with fractional crystallization. Lithospheric delamination is the best hypothesis for magmatism in Virginia/West Virginia, due to tectonic instabilities that are remnant from the long-term evolution of this margin, resulting in a 'passive-aggressive' margin that records multiple magmatic events long after rifting ended. Finally, Bermuda is an intraplate volcano that has been historically classified as mantle plume related but evidence to support the plume model is lacking. Instead, geophysics have argued that EDC is the best model to explain Bermuda volcanism. This study presents the first geochemical analysis of Bermuda volcanism, and found that Bermuda was built by two different magmatic processes: melting of carbonated peridotite to produce silica under-saturated, trace element enriched volcanics and melting of an enriched upper mantle component that produced silica saturated volcanics. We attribute the cyclicity of silica under-saturated and silica saturated volcanics to EDC melting. / Ph. D.

Continental rifting is an important geodynamic process during which the Earth's outer-most rigid shell undergoes continuous stretching resulting in continental break-up and theformation of new oceanic basins. The East African Rift System, which has two continentalsegments comprising largely of the East African Rift (EAR) to the West and the easternmostsegment Madagascar, is the largest narrow rift on Earth. However, the driving mechanismsof continental rifting remain poorly understood due to a lack of numerical infrastructure tosimulate rifting, the lack of knowledge of the underlying mantle dynamics, and poor knowl-edge of mantle rheology. Here, we use state-of-art computational modeling of the upper660 km of the Earth to: 1) provide a better understanding of mantle flow patterns and themantle rheology beneath Madagascar, 2) to elucidate the main driving forces of observedpresent-day∼E-W opening in the EAR, and 3) to investigate the role of multiple plumesor a superplume in driving surface deformation in the EAR. In chapter 1, we simulate EdgeDriven convection (EDC), constrained by a lithospheric thickness model beneath Madagas-car. The mantle flow associated with the EDC is used to calculate induced olivine aggregates'Lattice Preferred Orientation (LPO), known as seismic anisotropy. The predicted LPO isthen used to calculate synthetic seismic anisotropy, which were compared with observationsacross the island. Through a series of comparisons, we found that asthenospheric flow result-ing from undulations in lithospheric thickness variations is the dominant source of the seismicanisotropy, but fossilized structures from an ancient shear zone may play a role in southern Madagascar. Our results suggest that the rheological conditions needed for the formationof seismic anisotropy, dislocation creep, dominates the upper asthenosphere beneath Mada-gascar and likely other continental regions. In chapter 2, we use a 3D numerical model ofthe lithosphere-asthenosphere system to simulate instantaneous lithospheric deformation inthe EAR and surroundings. We test the hypothesis that the∼E-W extension of the EAR isdriven by large scale forces arising from topography and internal density gradients, known aslithospheric buoyancy forces. We calculate surface deformation solely driven by lithosphericbuoyancy forces and compare them with surface velocity observations. The lithosphericbuoyancy forces are implemented by imposing observed topography at the model surfaceand lateral density variations in the crust and mantle down to a compensation depth of 100km. Our results indicate that the large-scale∼E-W extension across East Africa is driven bylithospheric buoyancy forces, but not along-rift surface motions in deforming zones. In chap-ter 3, we test the hypothesis that the anomalous northward rift-parallel deformation observedin the deforming zones of the EAR is driven by viscous coupling between the lithosphereand deep upwelling mantle material, known as a superplume, flowing northward. We testtwo end-member plume models including a multiple plumes model simulated using high res-olution shear wave tomography-derived thermal anomaly and a superplume model (Africansuperplume) simulated by imposing a northward mantle-wind on the multiple plumes model.Our results suggest that the horizontal tractions from northward mantle flow associated withthe African Superplume is needed to explain observations of rift-parallel surface motions indeforming zones from GNSS/GPS data and northward oriented seismic anisotropy beneaththe EAR. Overall, this work yields a better understanding of the geodynamics of Africa. / Doctor of Philosophy / Continental rifting is an important geodynamic process during which the Earth's outer-most rigid shell undergoes continuous stretching resulting in continental break-up and theformation of new oceanic basins. The East African Rift System, which has two continentalsegments comprising largely of the East African Rift (EAR) to the West and the easternmostsegment Madagascar, is the largest narrow rift on Earth. However, the driving mechanismsof continental rifting remain poorly understood due to a lack of numerical infrastructure tosimulate rifting, the lack of knowledge of the underlying mantle dynamics, and poor knowl-edge of mantle rheology. Here, we use state-of-art computational modeling of the upper660 km of the Earth to: 1) provide a better understanding of mantle flow patterns and themantle rheology beneath Madagascar, 2) to elucidate the main driving forces of observedpresent-day∼E-W opening in the EAR, and 3) to investigate the role of multiple plumesor a superplume in driving surface deformation in the EAR. In chapter 1, we simulate EdgeDriven convection (EDC), constrained by a lithospheric thickness model beneath Madagas-car. The mantle flow associated with the EDC is used to calculate induced olivine aggregates'Lattice Preferred Orientation (LPO), known as seismic anisotropy. The predicted LPO isthen used to calculate synthetic seismic anisotropy, which were compared with observationsacross the island. Through a series of comparisons, we found that asthenospheric flow result-ing from undulations in lithospheric thickness variations is the dominant source of the seismicanisotropy, but fossilized structures from an ancient shear zone may play a role in southern Madagascar. Our results suggest that the rheological conditions needed for the formationof seismic anisotropy, dislocation creep, dominates the upper asthenosphere beneath Mada-gascar and likely other continental regions. In chapter 2, we use a 3D numerical model ofthe lithosphere-asthenosphere system to simulate instantaneous lithospheric deformation inthe EAR and surroundings. We test the hypothesis that the∼E-W extension of the EAR isdriven by large scale forces arising from topography and internal density gradients, known aslithospheric buoyancy forces. We calculate surface deformation solely driven by lithosphericbuoyancy forces and compare them with surface velocity observations. The lithosphericbuoyancy forces are implemented by imposing observed topography at the model surfaceand lateral density variations in the crust and mantle down to a compensation depth of 100km. Our results indicate that the large-scale∼E-W extension across East Africa is driven bylithospheric buoyancy forces, but not along-rift surface motions in deforming zones. In chap-ter 3, we test the hypothesis that the anomalous northward rift-parallel deformation observedin the deforming zones of the EAR is driven by viscous coupling between the lithosphereand deep upwelling mantle material, known as a superplume, flowing northward. We testtwo end-member plume models including a multiple plumes model simulated using high res-olution shear wave tomography-derived thermal anomaly and a superplume model (Africansuperplume) simulated by imposing a northward mantle-wind on the multiple plumes model.Our results suggest that the horizontal tractions from northward mantle flow associated withthe African Superplume is needed to explain observations of rift-parallel surface motions indeforming zones from GNSS/GPS data and northward oriented seismic anisotropy beneaththe EAR. Overall, this work yields a better understanding of the geodynamics of Africa.