Part 1: The emergence of environmentally friendly commercial products and their impact on fire debris analysis. Environmentally friendly products (i.e. green products) are environmentally preferable choices relative to comparable commercial products. They are readily available to the public, often highly flammable, and can be used by criminals as accelerants to facilitate the start and/or spread of fire. It is critical for analysts to have an understanding of their composition and chromatographic characteristics. Green products include paint thinners, solvents, removers, and cleaning and surface preparation products. As the composition of commercial products continually change over time, the fire debris community needs to be aware of the variety of environmentally friendly ignitable liquids that could be encountered during casework. Traditionally, when fire debris analysts have been trained, they are taught that most of the ignitable liquid residues they will encounter in casework are petroleum-based products. With the increasing emergence of non-petroleum based green products in the consumer marketplace, such products may be encountered more often than ever before in fire debris evidence submitted to forensic laboratories. Analysts should become familiar with the chromatographic features of these products as neat liquids as well as when present in fire debris samples. The purpose of this study is to introduce fire debris analysts to the prevalence of green products and increase knowledge regarding a variety of green product compositions and the characteristics they exhibit when analyzed as neat liquids and in "mock" fire debris samples. Several green products were analyzed as neat liquid samples and subsequently extracted from fire debris samples using typical fire debris extraction and analysis techniques in order to familiarize fire debris analysts with the chromatographic and mass spectral features of these products. General information about different types of green commercial products, their chromatographic and mass spectral characteristics, and their interpretation will be summarized. Analytical methods were developed for the analysis of environmentally friendly products and included considerations of gas chromatography oven temperature and ramp rate, hold times, and flow rate, as well as the scan rate and range of the mass spectrometer. Analyses involving common substrates were performed, including spiking green products onto various substrates with subsequent analysis and comparison of burned and unburned samples. Part 2: Application of fast GC/MS analysis for the identification of ignitable liquids in fire debris samples. Fire debris samples that contain ignitable liquid residues undergo a two-step process of extraction, most commonly via passive adsorption elution (PAE) onto an activated carbon strip, and instrumental analysis by gas chromatography/mass spectrometry. Upon completion of PAE, adsorbed compounds are eluted from the adsorbent with a suitable solvent and analyzed using (GC/MS) for the potential identification of ignitable liquid residues. A thorough evaluation of the literature revealed the average run time for gas chromatography of fire debris samples that contain hydrocarbon or petroleum based ignitable liquids to be 30 minutes. Additionally, a blank sample is run before an evidentiary sample to ensure solvent purity and to ensure any chromatographic carry over has not occurred between subsequent injections. The average run time, along with case volume, extraction times and case reviews contributes significantly to the backlog of samples to be analyzed in most crime laboratories around the country. Fast-GC/MS would significantly reduce analysis time, lower operating costs and would use less consumables. Based on a process known as pattern recognition, an initial goal of a fire debris analyst is to identify a pattern that is consistent with an ignitable liquid class. The standard method followed by most fire debris analysts use or base standard operating procedures (SOPs) on the American Society of Testing and Materials (ASTM) E1618, which defines the classes of commercial ignitable liquids based on chemical composition and boiling point range (or volatility). This study was conducted to optimize current methods of ignitable liquid detection and to optimize fast-GC/MS conditions for the identification of ignitable liquids in fire debris samples. Additionally, this study was conducted to determine if fast-GC/MS can reduce chromatographic separation times without sacrificing peak resolution and subsequently allow for ignitable liquid discrimination. Method development included considerations of flow rate, initial GC oven temperature, ramp rate, and mid and end temperature hold times. Fast-GC/MS conditions were tested on neat ignitable liquids from all nine ASTM E1618 classes. Optimizing fast-GC/MS method parameters led to an increase in sample throughput in comparison to traditional GC/MS methods. As a result, the GC/MS identification of ignitable liquids and their residues was performed in a quarter of the amount of time when compared to traditional methods.

Tourism is promoted by the governments of many developing countries because it offers the potential for creating jobs, thus generating income for the country and revenue for the government. However, the tourism industry can also be viewed as a destructive force, associated with negative externalities such as the loss of natural landscapes, congestion, and environmental and cultural degradation. These problems are more likely to be exacerbated where there is a lack of well-designed planning and effective management of tourism development. An essential component of any management of tourism is the ability to engage with, and get a positive response from, the tourism industry. There are a wide range of enterprises involved in providing tourist products and experiences, and in many nations, both developing and developed, a large number of these businesses are small and medium in size and tend to operate at a local scale. The informal nature of tourism enterprises in the developing world can make it difficult to spread awareness of tourism policy and to measure moves towards more sustainable performance on the part of the industry. Using the case study of tourism in the city of Hue, this thesis argues that it is essential to understand both what tourism enterprises know about sustainable tourism practice and policy and also how they respond to its adoption, if we are to more fully understand tourism and its links to sustainable economic development. Located on the central northern coast of Vietnam, Hue is well known for its cultural resources and natural beauty, and the province has become a major tourism centre in Vietnam. The city of Hue itself is recognized as having international heritage value and was listed as a world cultural heritage site by UNESCO in 1993. During the last decade, tourism revenues have increased by nearly 35% per annum, and Hue has made great efforts to both stimulate and cater for increasing demand for its tourism products and services. The Vietnamese government has introduced a number of policies designed to enhance environmental quality generally and, more specifically, to improve the sustainability of enterprises in the tourism sector. This thesis examines the degree to which tourism enterprises in the city of Hue are aware of the broad concept of sustainable tourism and of the specific legislation designed to influence the sustainability of their businesses. I examine the structure and make-up of the industry and then analyse whether characteristics such as size, ownership type and sectoral focus play a role in influencing awareness of, and response to, government policy. The research triangulates data-gathering methods: secondary data, literature reviews, semi-structured interviews and an enterprise survey are all used to gain insights into the core research questions. Each method feeds into and is strengthened by the others, and their combination (including 50 interviews and 180 survey responses) provides a robust data set to work from. The findings reveal that many of the firms operating in the Hue tourism industry are characterized by weak institutional practices, low financial capacity, poor facilities and a lack of broader awareness of policies that influence sustainable tourism practice. The tourism industry’s awareness of general sustainable development issues is low, and much business practice focuses on short-term rather than long-term perspectives. This limits the use of environmentally friendly practices by firms, especially small- and medium-scale enterprises (SMEs), in their daily business activities. The study reveals that there is no significant variation in the adoption of sustainable tourism practices according to the size of enterprises, especially if the practices in question are simple and can be introduced with cost savings. However, as the cost and complexity of introducing environmental measures increases, we see a greater ability on the part of larger enterprises to adopt such actions – partly because they are in a stronger position to bear the short-terms costs of implementing such approaches. There are a wide range of factors that constrain the Hue tourism industry from adopting more sustainable tourism practices. Internal constraints such as limited financial and human resources are combined with external constraints such as increasing cost-based competition, the lack of enforcement of government policies, and limited awareness of sustainable tourism pracitces. All of these factors play a crucial role in shaping the actions of enterprises in relation to sustainable tourism practices and policies. The results of this study also point to the fact that government sustainable tourism initiatives that rely on ‘command-and-control’ approaches will have limited effect; instead, a variety of institutional economic instruments offer greater potential to overcome deficiencies in the ability of the market to drive tourism enterprises towards more sustainable business practices. The thesis also argues that it is important to develop approaches that can cope with the special challenges attached to management of sustainable tourism development in destinations that are dominated by SMEs. The thesis contributes to the growing body of theory and literature in sustainable tourism development and tourism-enterprise behaviour. It also makes an important contribution to our understanding of tourism enterprises in the developing world. In particular, the findings add an important layer of understanding to those attempting to develop a more sustainable tourism industry in Vietnam. Specifically, it provides policy-makers with important insights into the ways in which different types of tourism enterprises respond to initiatives that relate to improved business sustainability.

Cadmium (Cd) is a priority pollutant in ecosystems worldwide. It is highly toxic to aquatic organisms including fish at fairly low concentrations. Numerous studies have investigated the influence of Cd exposure on fish, but few of them have considered how environmentally relevant levels of Cd affect reproduction, particularly reproductive behaviour. To assess the toxicity of Cd on fish reproduction, breeding fathead minnows (Pimephales promelas) were exposed to water-borne Cd for 21 days at four different concentrations (0, 1, 2.5 and 5 µg/L, respectively) based on a standard short-term reproductive assay and reproductive performance as well as behaviour were examined during or at the end of the exposure period. The results showed that Cd accumulated in a dose-dependent manner in the livers and ovaries of female fish. Brood size and mean egg production were significantly reduced in Cd-exposure treatment groups. When fertilized eggs were incubated in the water containing 2.5 µg/L or higher Cd, there was delayed hatching, but at the same time there was greater synchronous hatching after hatching started. Hatching success of Cd-exposed eggs also declined compared to the control. No significant difference was observed among treatments in adult fish survival, the number of breeding attempts, fertilization success, egg size, plasma β-estradiol levels of female, larval deformities, reproductive behaviour, gonadosomatic index or liver somatic index. The results of this study demonstrate that Cd is able to impair reproduction of fathead minnow at the concentration as low as 0.64 µg/L. It is harmful to both breeding fish and their offspring. The traditional endpoints used in standard reproduction assay (e.g. egg production and brood size) are probably more sensitive than behavioural endpoints, but the traditional method of interpreting reproductive impairment may underestimate toxic effects. The findings of this study have important implications for understanding the effects of chronic Cd exposure in metal-impacted feral fish populations. It can be applied to the protection or restoration of fish populations in Cd contaminated aquatic systems.

Excess water production is a major economic and environmental problem for the oil and gas industry. The cost of processing excess water runs into billions of dollars. Polymer gel technology has been successfully used in controlling water influx without damaging hydrocarbon production in conventional naturally fractured or hydraulically fractured reservoirs. However, there has been no systematic investigation on effectiveness and placement conditions of polymer gels for shutting off water flow from fractures with narrow apertures in shale and tight gas reservoirs. The existing polymer gels, like those based on Chromium(III) Acetate, as a crosslinker will exert very high extrusion pressure to effectively penetrate the narrow aperture fractures present in shale and tight gas reservoirs. This gives rise to a need for a new polymer gel system that can be used for selectively shutting off water flow from narrow aperture fractures in shale and tight gas reservoirs. The new gel system will have a longer gelation time than the existing polymer gels; this ensures minimum crosslinking of the gel by the time it reaches bottom hole. The gelant solution will be pumped at low pressure so that, it penetrates only pre-existing fractures in the formation with ease. This study for the first time focuses on developing an environmentally benign polymer gel system based on high molecular weight HPAM, as a base polymer and a commercial grade PEI as an organic crosslinker. Gel samples of different concentration ratios of the polymer and crosslinker were prepared and classified under Sydansk code of gel strength to find optimum concentration ratios that gave good gels. The gel system was characterized using Brookfield DV-III Ultra Rheometer and Fann-35 Viscometer.

The impact people and organizations have on the environment has been on the agenda in media for decades now. Still, very little research has been conducted in looking at what impact organizational culture can have when organizations attempt to become more environmentally friendly. For most organizations the environmental work is not part of their core business but rather something they work on at the side, if at all. Due to this, when an organization decides to implement an environmental vision and goals the employees may not adapt to it. This leads to the research question: How can an organizational culture be changed towards becoming environmentally friendly?To gain insight in the topic we researched general organizational cultural change theories which we used as a foundation for the deep, semi-structured interviews we conducted with five organizations that have worked towards becoming environmentally friendly for some time, and all consider themselves successful in having an environmentally friendly organizational culture. The respondents are very different from each other in regards to both industry and size, and some of them are Swedish while others are international. We chose maximum variation sampling as it would help us identify common methods organizations us across their variations.We found that to a large extent the same methods that are used for changing general organizational culture also can be used when changing the organizational culture towards becoming more environmentally friendly but that there are many adjustments to be made in which parts of the theories are most important. There is nonetheless a noticeable difference in the importance the different methods have and what the respondents emphasized as crucial. We found that the main drivers of motivation are communication and the importance of involving all employees in the environmental work. There is also a need to recognize and encourage employees for their work. All in all, however, the one method that stands above all other is what one of our respondents concluded with “The most important thing to do to create environmental change is to inform, inform and inform the employees”. The respondents highlighted the importance of making all employees feel like they are included in the process. That they understand the need for change is also something that seems crucial to getting people onboard. We also found that a lot of emphasis needs to be put on evaluation. Existing theory was however very weak in this area. We found tendencies of the organizations going through an environmental cultural life cycle where they start off the project, but maintain it poorly and hence every so often have to start over and therefore more focus therefore needs to be put into maintaining the cultural changes and not ever believe that the work is done. The work doesn’t end, but the environmental work and adaption is an ongoing process, even though the mindset of working environmentally can be permanently changed and built into the culture of employees.

Clay stabilizers are means to prevent fines migration and clay swelling, which are caused by the contact of formation with low salinity or high pH brines at high temperature. Previous clay stabilizers including: Al and Zr compounds and cationic polymers have several drawbacks. Al and Zr compounds can be removed by acids. Cationic polymers can cause formation damage in some cases. Quaternary amine-based chemicals have been used for many years as clay stabilizer, however, environmental profile of some has limited their use. There is a need to develop new clay stabilizers that can work following acid treatment and are environmentally acceptable. Laboratory studies were conducted on newly developed Al/Zr-based compound (Stabilizer A) to determine the optimum conditions for field application. Zeta potential was used to determine surface charge of different types of clays; and to optimize clay stabilizer concentration. Coreflood experiments were conducted on Berea and Bandera sandstone cores to assess the effectiveness of the new compound at high temperature, and determine the impact of acids on its performance. Also the effectiveness of this stabilizer was investigated at high pH medium and in low permeability cores. Inductively Coupled Plasma was used to measure the concentrations of e key cations in the core flood effluent. Three different commercial clay stabilizers (zirconium oxychloride, choline chloride and tetramethyl ammonium chloride) were also tested to validate the new chemical. The new clay stabilizer was very effective in mitigating fines migration. Zeta potential indicated that the isoelectric point at which complete shields of surface charge of clay particles was achieved at a stabilizer concentration of 0.2 wt%. Coreflood tests showed that this new chemical was effective, and unlike previous Al-based and Zr-based stabilizers (hydroxy aluminum and zirconium oxychloride solutions), it did not dissolve in acids and worked very well up to 300oF. Stabilizer A proved to be better than the three commercial stabilizers. Stabilizer A worked effectively at the high pH and no reduction in permeability was noticed after NaOH injection, unlike the other stabilizers. In addition, Stabilizer A is an inorganic-based fluid, environmentally friendly, in contrast to Quaternary amine chemicals.

The development of Environmentally Adapted Lubricants (EALs) and their use has been gaining momentum over the last decade. It has been shown that raw EALs degrade in the environment in about one tenth the time of an equivalent mineral based lubricant. Estimates and findings such as these serve to highlight the potential benefits of the EAL products, it is also important however to investigate the by-products of their use to ensure that the benefits are not cancelled by an increase of, for instance, combustion by-products. This thesis compares the emissions from a two-stroke outboard engine when using an EAL and an equivalent mineral lubricant, where the primary objective of the study is to characterise and quantify the pollutants that remain within the water column after combustion. To accomplish this, tests were conducted both in the laboratory (freshwater) and in the field (seawater) for a range of throttle settings. A 1.9kW two-stroke outboard engine was set-up in a test tank and water samples were taken from the tank after the engine had been run for a period at each of the throttle settings. The tests were repeated for a 5.9kW four-stroke engine, however, the experiments were only conducted in the laboratory (freshwater) and using only a standard mineral lubricant. Statistical analyses of the results were conducted using a Principal Components Analysis (PCA). A simple dilution model was used to estimate the initial outboard engine emission concentrations, which was extended to determine the concentrations at distances of 1, 10 and 100 metres from the source. An investigation of the Total Toxicity Equivalence of the PAH pollutant concentrations (TEQPAH) was conducted using Toxicity Equivalent Factors (TEFs). Results for both types of engine and in both fresh and seawater showed that even the initial concentrations at the source, in almost all instances, were well below the ANZECC water quality guidelines trigger levels. At a distance of 1 metre from the source all concentrations were well below, and therefore, the Total Toxicity Equivalents of the PAHs were found to be even lower. It is concluded that the emissions from a single outboard engine when using either an EAL or a mineral based lubricant are similar. However, the use of EALs has further reaching advantages in that spilt raw lubricants will degrade in the environment up to 10 times faster than a mineral lubricant. Also EALs are less toxic to aquatic and marine organisms and therefore the benefits of using them has to be viewed from a wider perspective. The results in this thesis for a single outboard engine now form the basis for a more detailed environmental assessment of their impacts.

Tourism is promoted by the governments of many developing countries because it offers the potential for creating jobs, thus generating income for the country and revenue for the government. However, the tourism industry can also be viewed as a destructive force, associated with negative externalities such as the loss of natural landscapes, congestion, and environmental and cultural degradation. These problems are more likely to be exacerbated where there is a lack of well-designed planning and effective management of tourism development. An essential component of any management of tourism is the ability to engage with, and get a positive response from, the tourism industry. There are a wide range of enterprises involved in providing tourist products and experiences, and in many nations, both developing and developed, a large number of these businesses are small and medium in size and tend to operate at a local scale. The informal nature of tourism enterprises in the developing world can make it difficult to spread awareness of tourism policy and to measure moves towards more sustainable performance on the part of the industry. Using the case study of tourism in the city of Hue, this thesis argues that it is essential to understand both what tourism enterprises know about sustainable tourism practice and policy and also how they respond to its adoption, if we are to more fully understand tourism and its links to sustainable economic development. Located on the central northern coast of Vietnam, Hue is well known for its cultural resources and natural beauty, and the province has become a major tourism centre in Vietnam. The city of Hue itself is recognized as having international heritage value and was listed as a world cultural heritage site by UNESCO in 1993. During the last decade, tourism revenues have increased by nearly 35% per annum, and Hue has made great efforts to both stimulate and cater for increasing demand for its tourism products and services. The Vietnamese government has introduced a number of policies designed to enhance environmental quality generally and, more specifically, to improve the sustainability of enterprises in the tourism sector. This thesis examines the degree to which tourism enterprises in the city of Hue are aware of the broad concept of sustainable tourism and of the specific legislation designed to influence the sustainability of their businesses. I examine the structure and make-up of the industry and then analyse whether characteristics such as size, ownership type and sectoral focus play a role in influencing awareness of, and response to, government policy. The research triangulates data-gathering methods: secondary data, literature reviews, semi-structured interviews and an enterprise survey are all used to gain insights into the core research questions. Each method feeds into and is strengthened by the others, and their combination (including 50 interviews and 180 survey responses) provides a robust data set to work from. The findings reveal that many of the firms operating in the Hue tourism industry are characterized by weak institutional practices, low financial capacity, poor facilities and a lack of broader awareness of policies that influence sustainable tourism practice. The tourism industry’s awareness of general sustainable development issues is low, and much business practice focuses on short-term rather than long-term perspectives. This limits the use of environmentally friendly practices by firms, especially small- and medium-scale enterprises (SMEs), in their daily business activities. The study reveals that there is no significant variation in the adoption of sustainable tourism practices according to the size of enterprises, especially if the practices in question are simple and can be introduced with cost savings. However, as the cost and complexity of introducing environmental measures increases, we see a greater ability on the part of larger enterprises to adopt such actions – partly because they are in a stronger position to bear the short-terms costs of implementing such approaches. There are a wide range of factors that constrain the Hue tourism industry from adopting more sustainable tourism practices. Internal constraints such as limited financial and human resources are combined with external constraints such as increasing cost-based competition, the lack of enforcement of government policies, and limited awareness of sustainable tourism pracitces. All of these factors play a crucial role in shaping the actions of enterprises in relation to sustainable tourism practices and policies. The results of this study also point to the fact that government sustainable tourism initiatives that rely on ‘command-and-control’ approaches will have limited effect; instead, a variety of institutional economic instruments offer greater potential to overcome deficiencies in the ability of the market to drive tourism enterprises towards more sustainable business practices. The thesis also argues that it is important to develop approaches that can cope with the special challenges attached to management of sustainable tourism development in destinations that are dominated by SMEs. The thesis contributes to the growing body of theory and literature in sustainable tourism development and tourism-enterprise behaviour. It also makes an important contribution to our understanding of tourism enterprises in the developing world. In particular, the findings add an important layer of understanding to those attempting to develop a more sustainable tourism industry in Vietnam. Specifically, it provides policy-makers with important insights into the ways in which different types of tourism enterprises respond to initiatives that relate to improved business sustainability.

Today, many small and medium enterprises (SMEs) either go out of business or see their growth being stalled due to poor activity management and organization, which is why they are often unprepared to engage against large companies leading their competitive markets. This study aims to develop a comprehensive management model, exclusively designed for SMEs in the jewellery sector, which may encompass all areas that create value and make them competitive. The development of this comprehensive management model was deployed in 21 steps classified into three tiers based on three major philosophies. This study uses lean manufacturing to identify activities that add value and reduce waste, and lean green was used to provide the environmental care and culture approach required for a friendly and fair workplace environment. The selected scenario is a jewelry workshop, wherein techniques and tools were completely applied and yielded a 20% increase in operating performance and a 15% increase in annual return.

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