The annual biomass of fish caught from estuaries in South Africa is currently estimated at over 24,800 tons. These estuarine fishes are caught by over 73,000 fishers, most of them recreational. Annual income derived from South Africa’s total estuarine fishery was worth approximately R430,000,000 in 1997. There is increasing concern that unless our estuarine fisheries are effectively managed, we will not be able to sustain these benefits into the future. Two factors that contribute to inadequate management of the estuarine fisheries in South Africa are a lack of data on which to base management decisions, and the lack of indicators by which to assess trends towards sustainability. The main aims of this study were to provide a description of the Kowie estuary fishery, identify suitable indicators of sustainability for this fishery, and assess its sustainability. Boat-based and shore-based roving creel surveys were carried out on the Kowie estuary between July 2000 and June 2001; 1,091 interviews were conducted with linefishers, and 277 interviews with bait collectors. In the boat-based interviews, data were collected on fisher demographics, fishing site, fishing method, choice of bait, fishing duration and catch statistics. In the shore-based surveys, additional data were collected from shore-based linefishers and bait collectors on their perceptions, attitudes, and knowledge of fishery regulations. Total annual fishing effort on the Kowie estuary was estimated at 30,952 angler hours (SD=154); 84% of it recreational, and the rest subsistence. Most fishing occurred during December and January, and decreased during winter, especially June and July. The annual yield of fish from the estuary was estimated at 16,240 fish (SD=667) or 5.99 tons (SD=0.81). By number, recreational anglers caught 69% of the annual catch. Three species dominated the catch by number: Rhabdosargus holubi (62%), Pomadasys commersonnii (17%) and Argyrosomus japonicus (7%). By mass, the dominant species caught were Argyrosomus japonicus (60%) and Pomadasys commersonnii (19%). Overall catch rate on the estuary was 0.57 fish.ang.⁻¹h⁻¹ (SD=0.24), or 0.298 kg ang.⁻¹h⁻¹ (SD=0.31). Overall catch rate by number was highest in the subsistence sector at 1.13 fish.ang.⁻¹h⁻¹(SD=0.70), while the boat-based recreational sector recorded the highest overall catch rate by mass (0.427 kg.ang.⁻¹h⁻¹, SD=0.625). Argyrosomus japonicus had the highest overall catch rate by mass on the estuary (0.496 kg ang.⁻¹h⁻¹), and Rhabdosargus holubi the highest overall catch rate by number (1.233 fish.ang.⁻¹h⁻¹). Only 19% of the catch of R. holubi was above the minimum legal size, while the estimates for P. commersonnii and A. japonicus were 21% and 25%, respectively. The annual number of bait collecting outings on the estuary was estimated at 2,889, of which 75% were subsistence. The highest numbers of bait collecting outings were recorded in December and April. The Bay of Biscay was the most popular site for bait collecting. A total of five invertebrate species were collected from the estuary to be used as bait, of which the mud prawn Upogebia africana was the dominant species. Total annual number of mud prawns collected from the estuary was estimated at 260,648; of which 41% was collected by subsistence bait collectors. Thirteen indicators were selected to assess sustainability in three fishery sectors on the Kowie estuary: namely, the shore-based recreational linefishery, the subsistence linefishery and the subsistence bait fishery. Social sustainability was evaluated on the basis of the use fishery resources to fulfil Maslow's basic human needs of food and employment, safety and security, affiliation, self-esteem and selfactualisation. Indicators of ecosystem sustainability assessed the productivity, diversity, disturbance and degree of water quality in the estuary. Institutional sustainability was assessed on the basis that management systems in the fishery should be results-oriented, consent-based, truth-seeking and adaptable. Data on indicator performance was collected during the shore-based roving creel survey, and from published literature. Arbitrarily set reference points were used to assess indicator performance, which was graded on a scale from 1 (indicating minimum probability of sustainability) to 4 (indicating maximum probability of sustainability). Sustainability was illustrated with the aid of amoeba plots. Overall sustainability was low in all three fishery sectors investigated. Nine of the 13 indicators in the shore-based recreational fishery performed poorly, while 11 of 13 in the subsistence line fishery, and 10 of 13 in the subsistence bait fishery, performed poorly. In all three fishery sectors all four selected indicators of institutional sustainability performed poorly. The probability of social sustainability was higher in the shore-based recreational line fishery, where the performance of two of the five selected indicators was very good. The probability of ecological sustainability was lowest in the shore-based recreational linefishery, while in the subsistence linefishery only one selected indicator performed very well. Recommendations made towards assessing sustainability in small-scale estuarine fisheries include the formulation of national policy for assessing sustainability in fisheries, the involvement of fishers in the assessment process, use of fisher perceptions where data gaps exist, and the use of research results to guide future management decisions. Management changes recommended for the Kowie estuary fishery include the formulation of an effective and integrated management plan, identification of the key stakeholders in the fishery, inclusion of fishers in management, the protection of the estuary’s Zostera capensis beds, and the establishment of a programme to increase research and monitoring in the fishery.

Between 1988 and 2014, otter trawls, seine nets, and plankton nets were deployed along the salinity gradients of 18 estuaries by the University of South Florida and the Florida Fish and Wildlife Research Institute (FWRI, a research branch of the Florida Fish and Wildlife Conservation Commission). The purpose of these surveys was to document the responses of aquatic estuarine biota to variation in the quantity and quality of freshwater inflows that were being managed by the Southwest Florida Water Management District (SWFWMD). In the present analyses, four community types collected by these gears were compared with a diversity of habitat factors to identify the factors with the greatest influence on beta diversity, and also to identify the factors that were most influential to important prey species and economically important species. The four community types were (1) plankton-net invertebrates, (2) plankton-net ichthyoplankton, (3) seine nekton, and (4) trawl nekton. The habitat factors were (1) vertical profiles of salinity, dissolved oxygen, pH, and water temperature taken at the time of the biological collections, (2) various characterizations of local habitat associated with seine and trawl deployments, (3) chlorophyll a, color, and turbidity data obtained from the STORET database (US Environmental Protection Agency), and (4) data that characterize the effects of freshwater inflow on different estuarine zones, including factors for freshwater inflow, freshwater turnover time, and temporal instability in freshwater inflow (flashiness). Only 13 of the 18 estuaries had data that were comprehensive enough to allow habitat-factor analysis. An existing study had performed distance-based redundancy analysis (dbRDA) and principle component analysis (PCA) for these data within 78 estuarine survey zones that were composited together (i.e., regardless of estuary of origin). Based on that study’s findings, the communities of primarily spring-fed and primarily surface-fed estuaries were analyzed separately in the present study. Analysis was also performed with the habitat factors grouped into three categories (water management, restoration, and water quality) based on their ability to be directly modified by different management sectors. For an analysis of beta diversity interactions with habitat factors, dbRDA (called distance-based linear modeling (DistLM) in the PRIMER software) was performed using PRIMER 7 software (Quest Research Limited, Auckland, NZ). The dbRDA indicated pH, salinity, and distance to the Gulf of Mexico (distance-to-GOM) usually explained the most variation in the biotic data. These results were compared with partial dbRDA using the Akaike Information Criterion (AIC) as the model selection criterion with distance-to-GOM held as a covariate to reduce the effect of differences in the connectivity of marine-derived organisms to the different estuaries; distance-to-GOM explained between 8.46% and 32.4% of the variation in beta diversity. Even with the variation from distance-to-GOM removed, salinity was still selected as most influential factor, explaining up to an additional 23.7% of the variation in beta diversity. Factors associated with the water-management sector were most influential (primarily salinity), followed by factors associated with the restoration sector (primarily factors that describe shoreline type and bottom type). For the analysis of individual species, canonical analysis of principal coordinates (CAP) was performed to test for significant difference in community structure between groups of sites that represented high and low levels of each factor. For those communities that were significantly different, an indicator value (IndVal) was calculated for each species for high and low levels of each factor. Among species with significant IndVal for high or low levels of at least one factor, emphasis was given to important prey species (polychaetes, copepods, mysids, shrimps, bay anchovy juveniles, and gammaridean amphipods) and to species of economic importance, including adults, larvae and juveniles of commercial and recreational fishes, pink shrimp, and blue crab. Shrimps, copepods and mysids were all associated with estuarine zones that had low percentages of wooded or lawn-type shoreline, a factor that may serve as a proxy for flood conditions, as lawns or trees were usually only sampled with seines at high water elevations and in the freshwater reaches of the estuaries. Many copepod and shrimp species were strongly associated with high flushing times, which suggests that if flushing times were too short in an estuarine zone, then these species or their prey would be flushed out. Multiple regression analysis was performed on each of the selected indicator species, using AIC as a selection criterion and distance-to-GOM as a covariate. As might be expected, the apparent influences of different habitat factors varied from species to species, but there were some general patterns. For prey species in both spring-fed and surface-fed estuaries, pH and flushing time explained a significant amount of variation. In surface-fed estuaries, the presence of oysters on the bottom also had a positive effect for many prey species. For economically important species, depth was important in both spring-fed and surface-fed estuaries. This suggested the importance of maintaining large, shallow areas, particularly in surface-fed estuaries. Another important factor in spring-fed estuaries was the percent coverage of the bottom with sand; however, a mixture of positive and negative coefficients on this factor suggested the importance of substrate variety. In surface-fed estuaries, flashiness also often explained substantial variation for many economically important species, usually with positive coefficients, possibly due to the importance of alternation between nutrient-loading and high-primary-productivity periods. When comparing the three management sectors, the restoration sector was the most explanatory. Several factors were averaged over entire estuaries due to data scarcity or due to the nature of the factors themselves. Specifically, the STORET data for chlorophyll, color, and turbidity was inconsistently distributed with in the survey areas and was not collected at the same time as the biological samples. Moreover, certain water-management factors such as freshwater-inflow rate and flashiness are inherently less dimensional than other factors, and could only be represented by a single observation (i.e., no spatial variation) at any point in time. Due to concern that reduced spatiotemporal concurrence/dimensionality was masking the influence of habitat factors, the community analysis was repeated after representing each estuary with a single value for each habitat factor. We found that far fewer factors were selected in this analysis; salinity was only factor selected from the water-management factors. Overall, the factor that explained the most variation most often was the presence of emergent vegetation on the shoreline. This factor is a good proxy for urban development (more developed areas have lower levels of emergent vegetation on the shoreline). Unlike the previous analysis, the restoration sector overwhelmingly had the highest R2 values compared with other management sectors. In general, these results indicate the seeming importance of salinity in the previous analysis was likely because it had a higher resolution compared with many other factors, and that the lack of resolution homogeneity did influence the results. Of the habitat factors determined to be most influential with the analysis of communities and individual species (salinity, pH, emergent vegetation and lawn-and-trees shoreline types, oyster and sand bottom types, depth, flashiness, and flushing time) most were part of an estuarine gradient with high values at one end of the estuary with a gradual shift to low values at the other end. Since many of the analyzed species also showed a gradient distribution across the estuary, the abundance and community patterns could be explained by any of the habitat factors with that same gradient pattern. Therefore, there is a certain limitation to determining which factors are most influential in estuaries using this type of regression-based analysis. Three selected factors that do not have a strong estuarine gradient pattern are the sand bottom type, depth, and flashiness. In particular, flashiness has a single value for each estuary so it is incapable of following the estuarine gradient. This suggests that flashiness has an important process-based role that merits further investigation of its effect on estuarine species.

The isotopic composition of the organic components of an animal's body, with respect to carbon and nitrogen, reflect the weighted average of the isotopic compositions of the animal's food sources, with a certain degree of enrichment in the heavier isotopes. Thus, by comparing the isotopic compositions of the animal and all the potential food sources, it is possible to ascertain the relative proportions of each availible food source in its diet, if the various food sources are sufficiently isotopically distinct. This approach is particularly usefull in estuarine communities where food-webs tend to be complex and where there are several sources of primary productivity. In this study it was used on two types of claw in an arctic and a temperate estuarine tidal flat in order to assess the importance of terrestrially fixed organic matter to each community. The results indicated that while marine and terrestrial organics were important food sources in the arctic tidal flat, the clams in the temperate site depended mostly on marine organics. / Thesis / Bachelor of Science (BSc)

No description available.

xvii, 175 leaves : ill. ; 29 cm Notes Typescript Thesis (Ph. D.)--University of Oregon, 2002 Includes vita and abstract Includes bibliographical references (leaves 150-175) Another copy on microfilm is located in Archives

This research involved the study of sediment cores from Loch Etive, Loch Long, Loch Goil and Loch Fyne with the aims of investigating the geochemistry of natural, and manmade radionuclides and heavy metals within the sea loch environment. The main aims of the research were to determine accumulation rates and the extent of mixing within these sediments and to assess the fluxes, sources and temporal variations in input of pollutant heavy metals to these environments. In recent years it has been suggested that Pb is mobile in sea loch sediments which questions the validity of applying ²¹⁰Pb dating in this environment. This has important implications with respect to interpreting sediment cores to assess temporal trends of pollutant inputs and investigating the rates of physical and biogeochemical processes that are taking place in the coastal environment. Hence, one of the aims of this research was to determine whether Pb was mobile in these sediments. The ²⁰⁶Pb/²⁰⁷Pb isotope ratio can potentially be used to determine the extent of pollutant Pb input from leaded petrol to the environment and a further objective of the work was to investigate the isotopic signature of pollutant Pb in the sediment. Concentration of ²¹⁰Pb, ²²⁶Ra, ²²⁸Ra, ²²⁸Th, ²³⁸U, ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am in the sediments were analysed using gamm a spectroscopy and the heavy metals, Pb, Zn and Cu were determined using X-ray Fluorescence. Stable Pb isotope ratios were determined using Inductively coupled plasma Mass spectrometry. The results obtained indicated that Pb is not subject to diagenetic mobility in these sediments and that ²¹⁰Pb profiles can be used to determine sedimentation rates for most of the sediment cores. lt was not possible to determine accumulation rates for the two cores from Loch Fyne by ²¹⁰Pb dating, and in this case the sedimentation rate was assessed by correlating the maximum concentration of ¹³⁷Cs in the sediments with the maximum ¹³⁷Cs discharge from Sellafield, BNFL's reprocessing plant located on the Cumbrian coast. The flux of ²¹⁰Pb to the lochs varied significantly suggesting that there has been sediment focusing of fine and/or organic rich material to the deeper sites, resulting in an enhanced flux of ²¹⁰Pb to these sediments. Sellafield waste radionuclides also provided useful chronologies by relating sediment maximum concentrations to maxima in the discharges. ¹³⁷Cs was observed to be subject to diffusive movement, invalidating the use of its total depth of penetration as a chronological indicator. The temporal trends of pollutant metal input agreed well with known historical trends and the Pb isotope profiles indicated that the onset of deposition from pollutant Pb from petrol occurred in the late 1920's. The maximum input of Pb from petrol peaked in the early 1980's and since then there has been a decrease in this input. The two sea lochs which were closest to the industrial centre of Glasgow exhibited a large anthropogenic pollutant input, confirming that these sediments have been highly perturbed by human activities, either directly as a result of sludge dumping or due to changes in land use (eg. road construction, deforestation, etc.) in the catchment. All the sea lochs reflected a change in the supply of material to the sediments over the last eighty years, indicating that increased anthropogenic activity has had an effect on these environments.

The New River Estuary is a large mesotidal estuary connected to Foveaux Strait by way of an inlet, and has two principle rivers (the Oreti and the Waihopai) flowing into it. The purposes of this study have been to describe the sediment distribution within the estuary; investigate the sediment source-sink relationships.; to calculate whether on a net basis sediment is being deposited in or eroded from the New River Estuary, and to investigate some of the influences on the sediment dynamics of this estuary. Textural analysis of the sediment indicated that there are three sedimentary environments within the estuary, and each is distinguishable due to the relative mix of fine sand. It was shown that Foveaux Strait is a dominant source of medium-fine sand. The Oreti River and the channels of the main estuary body are also important sources of these sediments. Medium-fine sand is transferred into the estuary and very fine sand is transferred out of the estuary and onto the continental shelf. Aerial photographs indicated that estuarine morphology was stable over a 31 year period (from 1947 to 1978). However a network of scour rods indicated that the intertidal sediment surface was spatially and temporally dynamic. It was calculated that on a net basis sediment was deposited in the estuary over a five month period. An important influence on the sedimentation of the New River Estuary has been the reduction of the tidal com partment by 25%, due to the reclamation of 12.2 km2.

This study investigates the interactions between dissolved trace metals and plastic debris under controlled laboratory conditions by using polyethylene pellets as a model plastic particle. Specifically, the study compared virgin pellets sourced from a local moulding plant with those collected from local beaches and subjected to aging, attrition and deposition of extraneous material. Pellets collected from the coastline of Southwest England were mainly polyethylene according to Fourier transform infra-red spectroscopy (FTIR), although occasional polypropylene pellets were present. Additionally, FTIR was used to identify the extent of degradation of pellets according to a photo-oxidation index derived from the relative magnitudes of specific absorbance peaks, and suggests pellet colour may give an indication of polymer degradation. Acid extractions of pellets collected from the coastline of Southwest England yielded metal concentrations ranging from low ng g-1 for metals such as Cd, Ni and Cr, to 7.7, 10.3 and 290 g g-1 for Cu Pb and Zn, respectively, while Al, Fe and Mn were present on beached pellets at concentrations of up to 171, 314 and 308 g g-1, respectively. Metal concentrations exhibited a high degree of inter- and intra-site variability. Correlation of metal concentrations with the photo-oxidation index indicates that pellet age is not a reliable indicator of metal concentrations. Batch experiments where metals (Cd, Co, Cr, Cu, Ni, Pb, Zn) were added to suspensions of pellets in seawater and estuarine water were performed in order to understand the extent and rates of trace metal adsorption to pellets. Langmuir modelling of adsorption isotherms in seawater indicated a range of maximum values for the accumulation of trace metals on beached pellets from 10 ng g-1 to 720 ng g-1 for Cd and Pb, respectively, in seawater spiked with 5 g L-1 of each trace metal. Langmuir constants for these relationships ranged from 0.140 (Cd) to 2.67 (Ni) mL g-1. Differences between trace metal affinities for pellets collected from the environment (beached) and those obtained directly from a plastics processing facility (virgin) were also identified. Adsorption maxima for virgin pellets ranged from < 1 ng g-1 (Cd) to 300 ng g-1 (Cr) with corresponding, respective Langmuir constants of 0.413 and 0.127 mL g-1. Adsorption of trace metals to beached pellets exceeds that to virgin pellets owing to the development of viable surface sites by photo-oxidation, biofouling and deposition of fine sediment particles on the former during exposure to environmental conditions. Adsorption kinetics were modelled successfully using a pseudo first-order reversible model. Chemical response times derived from kinetic constants ranged from 1.5 – 12 h for beached pellets and 0.2 to 4.5 h for virgin pellets, and were generally lower in seawater than in river water. Applying a similar batch approach to a system simulating an estuarine salinity gradient, the controlling effects of ionic strength and pH on the adsorption of trace metals to pellets were identified. Partitioning of Cd, Co and Ni exhibited inverse relationships with salinity, with partition coefficients (KD) decreasing from values of the order 101 to 10-1 or 10-2 mL g-1 (for beached pellets) as salinity is increased from < 0.05 to 33. Chromium exhibited contrasting behaviour within the estuarine gradient, with partitioning increasing with salinity, while Pb appears to be independent of salinity within this system. Chemical modelling was used to explain the results in context of changes in trace metal speciation which occur through the estuarine gradient. The bioaccessibility of metals on beached pellets to avian species was determined using an in vitro approach. Metal bioaccessibility in a simulated avian gastric environment comprising 10 g L-1 pepsin, 0.1 M NaCl and HCl at pH 2.8 indicated metals on pellets are labile (bioaccessibility ranges from < 10 % (Cr) to > 80 % (Mn)) and may be released readily within the digestive tract. Dissolution kinetics were modelled using the Noyes-Whitney equation, from which rate constants were determined in the range 3.1 x10-4 (Cr) to 8.7 x10-1 %-1 h-1 (Mn). This study has shown, for the first time, that plastic pellets have the potential to accumulate and transport trace metals in the marine environment. Furthermore, metal accumulation on plastic pellets is controlled by estuarine master variables such that conditions which favour or limit adsorption can be defined. Pellets present a previously unreported vector for the transport of metals in the environment, and have the potential to convey metals to organisms upon ingestion. The findings of this thesis have implications for interactions between metals and plastics more generally in the marine environment.

Wetlands are some of the most diverse and productive ecosystems on earth. Water-level fluctuations determine the ecological function of shallow lakes and wetlands. Currently, anthropogenic modification to water-level fluctuations is the leading source of ecological degradation in lake and wetland ecosystems worldwide. I used wading birds nesting in Lake Okeechobee, as a model system to address the challenges of environmental restoration within an ecosystem greatly impacted by anthropogenic activities. Specifically, I 1) identified environmental factors most important for predicting the number of wading bird nests, 2) tested the assumptions of both the match-mismatch and the threshold hypothesis by modeling the relationship between nesting success and prey density with foraging habitat availability, and 3) measured the stress response of Great (Ardea alba) and Snowy Egrets (Egretta thula) to hydrologically-mediated changes in food availability. Collectively, the results suggest that the number of nests was greatest when area of nesting substrate was high and water-levels were moderate (3.9 - 4.4 m). Nest numbers dropped when either nesting substrate or foraging habitat was limited. My investigation into the predictions of the match-mismatch and threshold hypotheses found that indeed, prey density can reduce or intensify the effects of a mismatch event. The interaction of prey density and foraging habitat availability was significant and positive in both models. Saturation thresholds existed for both fledging success (147 prey (m^2)^-1) and total productivity (189 prey (m^2)^-1), above which high concentrations of prey could sustain nesting when foraging habitat availability was low. Finally, my studies of the stress response support the hypothesis that hydrologic factors associated with prey availability play an important role in regulating nesting patterns, although the level of food limitation the birds experience at the lake was not as severe as expected. Model selection identified foraging habitat availability as most influential to the nestling Great Egret stress response, whereas foraging habitat availability and prey density both influenced nestling Snowy Egret stress response. Moreover, the Snowy Egret stress response was more sensitive to changes in prey availability than was the Great Egret stress response. Temperature and foraging conditions influenced yolk corticosterone concentrations for both egret species. / Includes bibliography. / Dissertation (Ph.D.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection

Entrainment velocity, salt flux and the turbulent diffusivity of salt are estimated in the outflow of a small, radially spreading buoyant outflow, just outside of the Teign Estuary mouth, as a means to compare mixing dynamics between very small and larger-scale estuarine and river plumes, and build on a scant knowledge base regarding the former. The analysis was made using a control volume approach, based on the conservation of momentum, volume and salt, from a Lagrangian perspective. Drifting buoys were used to accomplish this. The analysis was based on that employed by McCabe et al. (2008), with some modifications to fit a small-scale outflow, namely: repeat deployments, shorter drifter tracks, and deployment-specific criteria used for choosing the plume base, a step in the analysis used to calculate vertical entrainment, flux and diffusivity. In addition, temperature was used as a proxy for salinity, and this is evaluated in the results. Overall results were compared to a similar study, which was conducted in the Columbia River plume, a system much larger in scale to the Teign. Drifter experiments were conducted on multiple days, under different conditions (i.e. wind, tides, river flow), and those results are discussed briefly, but the focus is on one specific day, April 3, 2014, where conditions most closely matched those of the comparison study, and those results are compared between the two systems. Entrainment velocity was measured along the drifter tracks, in the near-field plume, where shear-induced mixing dominates. Drifter track subsections were chosen so as to avoid source or frontal dynamics, the plume base was chosen for individual deployments as the plume dynamics could change relatively quickly, and repeat deployments were conducted as a way to look at near-field plume evolution over the course of the ebb (and with a smaller plume, time allowed for this) . On April 3, the mean value for entrainment velocity for the four deployments chosen in the Teign outflow was 4.3 x 10-4 ms-1. The mean cast value was slightly higher at 7.6 x 10-4 ms-1, as casts values were typically measured at the beginning of the drifter tracks. Entrainment values at the cast sites were calculated in the same way as the track values, taking plume thickness from hydrographic casts, as a means to evaluate accuracy of track values, which are based on a modelled plume thickness. A rough estimate for the mean entrainment velocity for one pair of drifters used in the Columbia River was 9 x 10-4 ms-1, approximately double that of the Teign, but within the same order of magnitude. Salt flux values ranged from 0-5 x 10-2 psu ms-1 and from 0-3 x 10-2 psu ms-1 for the Teign and the Columbia, respectively, and diffusivities ranged from 0.5-5.8 x 10-2 m2s-1 and from 0.2-9.6 x 10-3 m2s-1. With a similar range of entrainment and salt flux values, and almost an order of magnitude difference between diffusivity values, it was determined that weaker density gradients in the Teign are responsible for the latter, and that this increased level of mixing results in a larger horizontal horizontal salinity gradient, which balances out the terms in the entrainment equation that are related solely to the physical size of the system (i.e. plume thickness, velocity and the vertical salinity gradient). This higher level of mixing of a smaller physical entity, supports the view that smaller plumes mix more thoroughly over a shorter timescale, resulting in a larger impact to the local environment into which they flow.