The concept of employing engineering thermoplastics as toughness modifiers for Bismaleimide resins was utilized to improve the fracture toughness properties of these important materials, which have applications as matrix resins for high performance composites. Modifier molecular weight, end group functionality, backbone structure and weight percent incorporation were all studied with respect to their influence on K_lc, fracture toughness properties. Increases in fracture toughness were created with thermoplastic oligomers without sacrificing high temperature properties and desirable hot-melt processing conditions. Investigations were also made to study the morphological features that develop within these modified thermosets and their resistance to specific environments. In addition, unidirectional carbon fiber composites were prepared and their mode I and II strain energy release rates measured. Respectable increases in the interlaminar fracture toughness were obtained, 15 and 20 percent by weight loadings of maleimide terminated polysulfone modifiers yielded G_lc values of 489±25 and 734±10 J/m² respectively, a substantial improvement over the control value of 359±17 J/m². Laminates were prepared using carbon fibers that had been investigated in terms of their surface energies using Inverse Gas Chromatography. It was illustrated how this technique could distinguish between the acid-base properties of fibers possessing different degrees of proprietary surface treatments. Fiber composites containing both contrasting and subtle changes at the fiber-matrix interphase were prepared and their mechanical properties evaluated using a variety of test methods. Dramatic increases in laminate properties were measured for composites possessing contrasting interphases. Furthermore, the mode II fracture toughness test was sensitive to interphase differences; however, the mode I fracture toughness test was not. Specimens subjected to the new Continuous Ball Indentation test method (meso-indentation) were compared with single fiber micro-indentation test results. Differences were detected in composites prepared using untreated and surface treated fibers. The new method was also sensitive to changes in matrix ductility. Certain anomalies that were noted to be surprising from micro-indentation measurements were not present in the meso-indentation test results. These observations brought to light certain limitations found within the micro-indentation test, but further supported the new test method as a potential technique for fiber-matrix interphase evaluation. / Ph. D.

A detailed study of the feasibility of anchoring fiber reinforced plastic wires for civil engineering applications is presented. An experimental investigation using tensile testing machines is performed, testing anchorages of 1, 7 and 19 wires. Conventional strain gage and acoustic emission measurement techniques are used. The tests are essential in determining the failure load and failure mode. However, the experimental data alone do not provide enough information about the behavior of the anchorage to be used exclusively in the design process. The results are used to modify the design of the anchorage system. It is shown that for a successful anchorage system the choice of material for the load transfer medium is crucial. A solution is presented to overcome the high stress concentration at the load entry area of the wire into the anchor. A finite element analysis of the anchors for 1 and for 19 wires is used to assess the stress and strain fields inside the anchor, to validate the analytical model, and to determine locations of possible high stress concentrations. Three-dimensional and one-dimensional models, that utilize axisymmetry, are evaluated. The results of the numerical analysis are used to demonstrate the improvement as a result of a change in material choice or design of the anchor. It is shown that the modification of the load transfer medium results in a decrease of 30 % of the average stress level. In the analytical investigation, several common models are introduced that describe the fiber pullout behavior. Based on a recent treatment by C. H. Hsueh, a model is developed that describes the anchorage of a wire in a conical shaped socket using orthotropic materials. This model includes boundary conditions that are similar to the ones observed in the experiments. A parametric study is performed to obtain information on the ideal geometry of the anchor system. The results and predictions of the applied techniques, i. e. analytical description, finite element method and experimental investigation, are compared and contrasted. Based on the analytical, numerical and experimental results, recommendations for improving the design of the anchor system are made. Subsequently, a modified anchor system is proposed that utilizes the properties of a load transfer medium that has a variable stiffness. The inclusion of a pure resin collar and supporting wires is suggested. For a successful completion of this project, ideas are proposed and suggestions made for future work. / Ph. D.

The American Concrete Institute (ACI) has developed guidelines for the design of fiber reinforced polymer (FRP) reinforced concrete structures. Current guidelines require the application of environmental and flexural strength reduction factors, which have minimal experimental validation. Our goal in this research is the development of a Monte Carlo simulation to assess the durability of glass fiber reinforced polymer (GFRP) reinforced concrete designed for flexure. The results of this simulation can be used to determine appropriate flexural strength reduction factors. Prior to conducting the simulation, long-term GFRP tensile strength values needed to be ascertained. Existing FRP tensile strength models are limited to short-term predictions. This study successfully developed a power law based-FRP tensile strength retention model using currently available tensile strength data for GFRP exposed to variable temperatures and relative humidity. GFRP tensile strength retention results are projected at 0, 1, 3, 10, 30, and 60-year intervals. The Monte Carlo simulation technique is then used to assess the influence beam geometry, concrete strength, fractions of balanced reinforcement ratio, reinforcing bar tensile strength, and environmental reduction factors on the flexural capacity of GFRP reinforced concrete beams. Reliability analysis was successfully used to determine an environmental reduction factor of 0.5 for concrete exposed to earth and weather. For simulations with higher GFRP bar tensile strength as well as larger beam geometry and fractions of the balanced reinforcement ratio, larger moment capacities were produced. A strength reduction factor of approximately 0.8 is calculated for all fractions of balanced reinforcement ratio. The inclusion of more long-term moisture data for GFRP is necessary to develop a more cohesive tensile strength retention model. It is also recommended that longer life cycles of the GFRP reinforced concrete beams be simulated. This research was conducted thanks to support from the National Science Foundation Division of Graduate Education's Interdisciplinary Graduate Education Research and Traineeship (Award # DGE-0114342) Note: The opinions expressed herein are the views of the authors and should not be interpreted as the views of the National Science Foundation. / Master of Science

Lewis acid/base interactions were shown to play an important role in the optimization of the interfacial adhesion of reinforcing carbon fibers to thermoplastic polymer matrices. Inverse gas chromatography (IGC) and x-ray photoelectron spectroscopy (XPS) were used to characterize the acid/base nature of the carbon fiber surfaces. Capillary column IGC (CIGC) was used to determine the acid/base nature of thermoplastic polymer surfaces. To quantify the non-dispersive (acid/base) interactions, the dispersive component had to be factored out by separate experiments. The carbon fibers (both surface pretreated and untreated) were found to be predominantly acidic while the polymer matrices (polysulfone, polycarbonate, and polyetherimide) exhibited basic properties. Single fiber fracture tests showed that increased acidity in the fiber surfaces (as a result of surface pretreatment) resulted in a significant improvement in the interfacial adhesion to the basic polymers. The acid/base interactions, however, were not solely responsible for the most favorable adhesion. The dispersive component and thus, the carbon fiber structure also played a role. / Master of Science

yes / ACI Committee 544’s repeated drop-weight impact test for concrete is often criticized for large variations within the results. This paper identifies the sources of these large variations and accordingly suggests modifications to the ACI test. The proposed modifications were evaluated and compared to the current ACI test by conducting impact resistance tests on 40 specimens from two batches of polypropylene fiber-reinforced concrete (PPFRC). The results obtained from both methods were statistically analyzed and compared. The variations in the results were investigated within the same batch and between different batches of concrete. The impact resistance of PPFRC specimens tested with the current ACI test exhibited large coefficients of variation (COV) of 58.6% and 50.2% for the first-crack and the ultimate impact resistance, respectively. The corresponding COV for PPFRC specimens tested according to the modified technique were 39.4% and 35.2%, indicating that the reliability of the results was significantly improved. It has been shown that, using the current ACI test, the minimum number of replications needed per each concrete mixture to obtain an error below 10% was 41 compared to 20 specimens for the modified test. Although such a large number of specimens is not good enough for practical and economical reasons, the reduction presents a good step on the development of a standard impact test.

A model for the dynamic response of a laminated composite arch is developed from classical shell theory. The problem is reduced from a shell to an arch by making an assumption that the variation of the field of variables in the direction of the width of the arch is small compared to those in other directions. Standard separation of variables is used to change from a system of partial differential equations to that of ordinary differential equations. Several methods of solution are explored, namely the Laplace transformation, the method of particular solutions, and the eigensolution. The eigensolution is chosen as the the most efficient in terms of computer time and is the easiest to modify. The free vibration of the arch is explored and the natural frequencies of the system are determined. The response of the arch to general forcing functions is also considered, by the use of the Fourier transformation technique. Damping through material viscoelasticity and use of the model in evaluation of experimental data are also discussed. / Master of Science / incomplete_metadata

Adjacent voided slab bridges (AVSB) are economical systems for short spans. They provide the advantages of having low clearances due to their small section depths, accelerated construction times, and high torsional stiffness. The current longitudinal connection detail, a partial depth grouted shear key, has been known to fail in many of these bridges. The failure leads to reflective cracking in the wearing surface which allows chloride laden water to seep down through the joint, where it corrodes the reinforcement and prestressing strand. Ultimately, the failed keys lead to costly repairs and bridge replacements sooner than their proposed lifespan. This research project aimed to develop a more durable longitudinal connection detail by using sub-assemblages to test five alternate connections. The objective was to find a connection that abated all cracking in the shear key, thus removing the need for transverse post-tensioning. The tested connections employed alternate connection shapes and two different mix designs of fiber reinforced high strength concretes. The results showed that each tested connection outperformed the current detail. The findings of this research indicate that the longitudinal connection detail of adjacent member voided slab bridges should be modified. The modified version should be a blockout with lap splice connection detail utilizing a nonproprietary fiber reinforced high strength concrete. / Master of Science

The random discontinuous fiber composite has uniform properties in all directions. The wetlay process is an efficient method to manufacture random discontinuous thermoplastic preform sheets that can be molded into random composite plaques in the hot-press. Investigations were done on the molding parameters that included the set-point mold pressure, set-point mold temperature and cooling methods. The fibers used in the study included glass and carbon fiber. Polypropylene (PP) and Polyethylene Terephthalate (PET) were used as the matrix. Glass/PP and Glass/PET plaques that had fiber volume fractions ranging from 0.05 to 0.50 at an increment of 0.05 were molded. Both tensile and flexural tests were conducted. The test results showed a common pattern, i.e., the modulus and strength of the composite increased with the fiber volume fraction to a maximum and then started to descend. The test results were analyzed to find out the optimal fiber volume fraction that yielded the maximum modulus or strength. Carbon/PET composites plaques were also molded to compare their properties with Glass/PET composite at similar fiber volume fractions. Micrographs were taken of selected specimens to examine the internal structure of the material. Existing micromechanics models that predict the tensile modulus or strength of random fiber composites were examined. Predictions from some of the models were compared with test data. / Master of Science

Within this research, factors affecting the orientation of injection molded long fiber composites in an end-gated plaque were investigated. Matrix viscosity was found to have a small effect on fiber orientation. The impact matrix viscosity had on orientation was dependent on fiber loading. At lower fiber loadings, the higher viscosity material had a more asymmetric orientation profile throughout the samples and less of a shell-core-shell orientation. At higher fiber loadings, there were few differences in orientation due to matrix viscosity. Fiber concentration was found to have a larger influence on fiber orientation than matrix viscosity. Increased fiber concentration led to a lower degree of flow alignment and a broader core region at all locations examined, following the trend previously reported for short fiber composites. The orientations of three different fiber length distributions of glass fiber (GF) were compared. The longer fibers in the fiber length distribution were shown to have a disproportionate effect on orientation, with weight average aspect ratio being better than number average aspect ratio at indicating if the GF and CF samples orientated comparably. To improve properties transverse to the main flow direction, the super critical carbon dioxide aided deagglomeration of multi-walled carbon nanotubes (CNTs) was used to create injection molded multiscale composites with CNT, CF, and polypropylene. The addition of CNTs greatly improved the tensile and electrical properties of the composites compared to those without CNTs. The degree of improvement from adding CNTs was found to be dependent on CF concentration, indicating that the CNTs were most likely interacting with the CF and not the polymer. A CNT concentration of 1 wt% with a tenfold degree of expansion at 40 wt% CF proved to be optimum. A large improvement in the tensile properties transverse to the flow direction was found implying that the CNTs were not highly flow aligned. Tensile and electrical properties began to fall off at higher CNT loadings and degrees of expansion indicating the importance of obtaining a good dispersion of CNTs in the part. / Ph. D.

Linear viscoelasticity theory is used to analyze the dynamic stability of composite, viscoelastic flat plates subjected to in-plane, biaxial edge loads. In deriving the associated governing equations, a hereditary constitutive law is assumed. In addition, having in view that composite-type structures exhibit weak rigidity in transverse shear, the associated governing equations account for the transverse shear deformations, as well as the transverse normal stress effect. The integro-differential equations governing the stability are solved for simply-supported boundary conditions by using the Laplace transform technique, thus yielding the characteristic equation of the system. In order to predict the effective time-dependent properties of the orthotropic plate, an elastic behavior is assumed for tile fiber, whereas the matrix is considered as linearly viscoelastic. In order to evaluate the nine independent properties of the orthotropic viscoelastic material in terms of its isotropic constituents, the micromechanical relations developed by Aboudi [24] are considered in conjunction with the correspondence principle for linear viscoelasticity. The stability behavior analyzed here concerns the determination of the critical in-plane normal edge loads yielding asymptotic stability of the plate. The problem is studied as an eigenvalue problem. The general dynamic stability solutions are compared with their quasi-static counterparts. Comparisons of the various solutions obtained in the framework of the Third Order Transverse Shear Deformation Theory (TTSD) are made with its first order counterpart. Several special cases are considered and pertinent numerical results are compared with the very few ones available in the field literature. / Master of Science