The use of foam-forming surfactants offers promise to improve sweep efficiency and mobility control for enhanced oil recovery (EOR). This thesis provides an in depth understanding of transport of surfactant and foam through porous media using a combination of laboratory experiments and numerical simulations. In particular, there are several issues in foam EOR processes that are examined. These include screening of surfactant adsorption onto representative rock surfaces, modeling of foam flow through porous media, and studying the effects of surface wettability and porous media heterogeneity. Surfactant adsorption onto rock surfaces is a main cause of foam chromatographic retardation as well as increased process cost. Successful foam application requires low surfactant adsorption on reservoir rock. The focus of this thesis is natural carbonate rock surfaces, such as dolomite. Surfactant adsorption was found to be highly dependent on electrostatic interactions between surfactants and rock surface. For example, the nonionic surfactant Tergitol 15-S-30 exhibits low adsorption on dolomite under alkaline conditions. In contrast, high adsorption of cationic surfactants was observed on some natural carbonate surfaces. XPS analysis reveals silicon and aluminum impurities exist in natural carbonates, but not in synthetic calcite. The high adsorption is due to the strong electrostatic interactions between the cationic surfactants and negative binding sites in silica and/or clay. There are a number of commercial foam simulators, but an approach to estimate foam modeling parameters from laboratory experiments is needed to simulate foam transport. A one-dimensional foam simulator is developed to simulate foam flow. Chromatographic retardation of surfactants caused by adsorption and by partition between phases is investigated. The parameters in the foam model are estimated with an approach utilizing both steady-state and transient experiments. By superimposing contour plots of the transition foam quality and the foam apparent viscosity, one can estimate the reference mobility reduction factor (fmmob) and the critical water saturation (fmdry) using the STARS foam model. The parameter epdry, which regulates the abruptness of the foam dry-out effect, can be estimated by a transient foam experiment in which 100% gas displaces surfactant solution at 100% water saturation. Micromodel experiments allow for pore-level visualization of foam transport. We have developed model porous media systems using polydimethylsiloxane. We developed a simple method to tune and pattern the wettability of polydimethylsiloxane (PDMS) to generate porous media models with specific structure and wettability. The effect of wettability on flow patterns is observed in gas-liquid flow. The use of foam to divert flow from high permeable to low permeable regions is demonstrated in a heterogeneous porous micromodel. Compared with 100% gas injection, surfactant-stabilized foam effectively improves the sweep of the aqueous fluid in both high and low permeability regions of the micromodel. The best performance of foam on fluid diversion is observed in the lamella-separated foam regime, where the presence of foam can enhance gas saturation in the low permeable region up to 45.1% at the time of gas breakthrough. In conclusion, this thesis provides new findings in surfactant adsorption onto mineral surfaces, in the methodology of estimating foam parameters for reservoir simulation, and in micromodel observations of foam flow through porous media. These findings will be useful to design foam flooding in EOR processes.

Computer simulation is an essential tool in the development process of childseats, particularly when it comes to ensuring the safety of child passengers.As awareness regarding child passenger safety continues to grow, the use ofsuitable materials in the development of child seats becomes increasinglycrucial. Numerical simulations play a vital role throughout the entiredevelopment phase, enabling accurate analysis and evaluation. Toeffectively reduce development costs and time, it is imperative to have amaterial model that accurately predicts the behavior of materials innumerical simulations. This enables optimized performance of child seatswhile maintaining safety standards. The objective of the thesis is to implement a standard procedure forextracting material data for numerical modelling of foam materials andvalidating it. In this study, material models available in LS-DYNA, such asMAT_083 and MAT_057 for foam materials, are utilized along withcompression test data to create the material model. The model is furtherenhanced by optimizing the material parameters to establish a correlationbetween the test and simulation results. The improved material model is thenvalidated by comparing it with the impact drop test results. However,THULE's current impact drop test equipment is not considered accurate orefficient, and addressing this issue is one of the main objectives of thisthesis. Within this thesis, the identified problems are thoroughly examined,and suitable solutions are proposed to ensure the accurate extraction ofmaterial data and its validation, particularly when introducing new foammaterials.

High expansion foam (Hi-Ex) is a firefighting technology that has been widely used for fire suppression in underground locations. Hi-ex foam can be applied remotely through boreholes from the surface reducing firefighter exposure to fires. Despite the experimental studies that have been carried out there are still some uncertainties about foam behavior in underground locations. For this reason, the main objective of this thesis was to estimate Hi-Ex foam flow behavior in different underground configurations using computational fluid dynamics (CFD) simulations. An experimental apparatus was built to study the foam rheology in order to determine the rheological model parameters to simulate foam as a continuous Non-Newtonian fluid. Furthermore, numerical and experimental results of Hi-Ex foam flowing in a pipe were compared with the objective of validating numerical results. Results of this study show that Hi-Ex foam with an expansion ratio between 1:250 and 1:1280 behaves as a shear thinning fluid represented by the power law model. Numerical simulations results were between 0.06% and 14% of experimental results for Reynolds numbers between 200 and 1700. Finally, numerical simulations of Hi-Ex foam in different mine entry slopes were carried out and compared with qualitative results of prior field work. This work generates some of the necessary numerical parameters for the simulation of Hi-Ex foam flow in mines. Furthermore, results of this work and the methodology used can allow for improved predictions of foam flow in in underground mine fires, while improving safety for mine workers / Master of Science