M.Sc. / Water quality management is the effort of the community to control the physical, chemical and biological qualities of water. Water quality is mainly controlled by the activities of the community and the hydrological cycle. Usually an effort is made to control only one of the two causes, namely the activities of the community. The Sasolburg industrial complex is the largest of its kind in the Free State and consists mainly of chemical industries. A large proportion of the effluent is returned to the Vaal River via the Sasol sewerage works while some industries have permission to send their effluent to the Taaibosspruit, east of Sasolburg. The most industries let their storm water flow into the Taaibosspruit The option of the location of a monitoring point should determine whether the collected data is representative of the water quality and whether it is useful to observe trends in the water quality. The reliability of the data on water quality is strongly dependent on inter alia, the frequency of monitoring, which is determined by the availibility of staff and funding. By investigating the present monitoring sytem by Rand Water, the Department of Water Affairs and Forestry and the industries through this study it had to be determined whether the functioning of the monitoring network was optimal.Deficiencies like: unmonitored and unauthorised streams; badly contaminated areas which pollute the storm water and; the absence of retention facilities for contamninated storm water were found. Recommendations like: extra monitoring points; retention facilities for storm water and; biomonitoring for combined streams were made. Of great importance is the recommendation for the establishment of a local water quality management body to control the water quality of the water sources in the region.

The results from this study show how different precursors affect halonitromethane (HNM) formation as well as how different free chlorine doses can affect HNM speciation. This study shows that the low pressure ultraviolet (LPUV) and free chlorine concurrent exposure can enhance HNM formation. In addition, most previous studies in the literature showed trichloronitromethane (TCNM) forming in greater quantities followed by monochloronitromethane (MCNM) and dichloronitromethane (DCNM). However, the results of this study show that, in deionized (DI) water matrices, MCNM forms in greater quantities at chlorine to nitrogen (Cl:N) ratios less than 3, while TCNM forms in greater quantities at Cl:N ratios greater than 3. Even so, the increase in TCNM formation did not increase linearly as the Cl:N ratio increased; there was a decreased rate of return when Cl:N ratios were greater than 3. The type of nitrogenous precursors can affect the amount of HNMs formed, with glycine forming a higher amount of total HNMs compared to methylamine (MA) and dimethylamine (DMA). The source of water can also affect which HNM species is formed in greater concentrations. The limited number of real water samples showed that the river waters have higher than normal total organic carbon (TOC) and dissolved organic nitrogen (DON), which are associated with greater nitrogenous precursors and higher HNM formation. Each water source can have different nitrogenous precursors; river waters may have more algal organic matter while wastewater would have higher organic matter and synthetic chemicals. In addition, source waters can have different constituents, such as varying dissolved oxygen (DO) levels and inorganic ions, which might inhibit HNM formation or affect specification.

Master of Science / Food Science Institute / Karen Schmidt / Flour is essential to bread production as it provides structure, texture, and flavor. The most common, wheat flour, is unique compared to other cereal flours as it forms gluten that is capable of forming viscoelastic dough, which retains gas produced during fermentation and helps create cohesive dough, all of which are critical to bread development. However, a certain percentage of the population has a rare autoimmune disorder, celiac disease, which is triggered by gluten. A gluten-free diet is the only remedy for celiac disease. Traditionally, in gluten-free breads, hydrocolloids, or gums have been used to mimic the behavior of gluten. However, the lack of a protein structure in breads made with hydrocolloids leads to an almost batter-like viscosity. Therefore, research has focused on gluten-free alternatives, particularly non-wheat cereal proteins that can be altered to mimic gluten’s dough forming properties. For example, zein has an average molecular weight and larger peptides than gluten, which contribute to its hydrophobic behavior. In fact, zein from maize flour is an ideal alternative as it can be manipulated to behave like gluten under certain conditions. The main difference between gluten and zein is that zein does not exhibit a large disulfide-linked polymer. Zein is also more hydrophobic than gluten. However, zein has been found to exhibit viscoelastic properties similar to gluten’s at temperatures higher than its glass transition. Other research has found the secondary structure of zein, in particular the β-sheet structure, increases at temperatures above its glass transition. This suggests that temperature and shear are not the only factors necessary to form and maintain the viscoelastic properties of zein; apparently, the β-sheet structures also affect viscoelasticity. Finally, differences such as maize variety and particle size also affect the properties of zein in bakery applications.

The research study focused on assessing the usage of accounting systems by Small Medium Micro Enterprises (SMMEs). The location of the study was SMMEs in Maluti-a-Phofung Local Municipality (MAP LM) in the Eastern part of the Free State province. The objective of the study was to investigate the usage of accounting systems by SMMEs around MAP ML. The research approach that premised the study was a quantitative methodology, which involved distribution of questionnaires as part of field work to SMMEs in MAP LM area. The questionnaires were analysed through a statistical approach, and further linked back to the problem statement posed to the research study. The area of focus in the SMMEs was the usage of Computerised Accounting Systems which was selected because of its huge impact in the operation of most businesses. Computerised Accounting System forms the core of the business sustainability; it ensures that management is always abreast with information. Various literatures were reviewed regarding the usage of Accounting Systems and computerised accounting systems for SMMEs. The results provided an interesting outcome to conclude that the accounting systems being used by the SMEs around the MAP area poses less challenges to the operation of the businesses. It can also be concluded from the study that SMMEs around the MAP LM area are using accounting systems that collect and process data accurately and communicate information to the decision makers with no challenges. / MBA, North-West University, Potchefstroom Campus, 2015

The research study focused on assessing the usage of accounting systems by Small Medium Micro Enterprises (SMMEs). The location of the study was SMMEs in Maluti-a-Phofung Local Municipality (MAP LM) in the Eastern part of the Free State province. The objective of the study was to investigate the usage of accounting systems by SMMEs around MAP ML. The research approach that premised the study was a quantitative methodology, which involved distribution of questionnaires as part of field work to SMMEs in MAP LM area. The questionnaires were analysed through a statistical approach, and further linked back to the problem statement posed to the research study. The area of focus in the SMMEs was the usage of Computerised Accounting Systems which was selected because of its huge impact in the operation of most businesses. Computerised Accounting System forms the core of the business sustainability; it ensures that management is always abreast with information. Various literatures were reviewed regarding the usage of Accounting Systems and computerised accounting systems for SMMEs. The results provided an interesting outcome to conclude that the accounting systems being used by the SMEs around the MAP area poses less challenges to the operation of the businesses. It can also be concluded from the study that SMMEs around the MAP LM area are using accounting systems that collect and process data accurately and communicate information to the decision makers with no challenges. / MBA, North-West University, Potchefstroom Campus, 2015

Thesis (M. Ed.) - Central University of Technology, Free State, 2007

No abstract available / Educational Studies / M.Ed. (Didactics)

Non-thermal plasmas are considered to be very promising for the initiation of chemical reactions and a vast amount of experimental work has been dedicated to plasma assisted hydrocarbon conversion processes, which are reviewed in the fourth chapter of the thesis. However, current knowledge and experimental data available in the literature on plasma assisted liquid hydrocarbon cracking and gaseous hydrocarbon decomposition is very limited. The experimental methodology is introduced in the chapter that follows the literature review. It includes the scope and objectives section reflecting the information presented in the literature review and the rationale of this work. This is followed by a thorough description of the design and construction of the experimental plasma reformer and the precise experimental procedures, the set-up of hydrocarbon characterization equipment and the development of analytical methods. The methodology of uncertainty analysis is also described. In this work we performed experiments in attempt the cracking of liquid hexadecane into smaller liquid hydrocarbons, which was not successful. The conditions tested and the problems encountered are described in detail. In this project we performed a parametric study for methane and propane decomposition under a corona discharge for COx free hydrogen generation. For methane and propane a series of experiments were performed for a positive corona discharge at a fixed inter-electrode distance (15 mm) to study the effects of discharge power (range of 14 - 20 W and 19 – 35 W respectively) and residence time (60 - 240 s and 60 – 303 s respectively). A second series of experiments studied the effect of inter-electrode distance on hydrogen production, with distances of 15, 20, 25, 30 and 35 mm tested. The analysis of the results shows that both discharge power and residence time, have a positive influence on gaseous hydrocarbon conversion, hydrogen selectivity and energy conversion efficiency for methane and propane decomposition. Longer discharge gaps favour hydrogen production for methane and propane decomposition. A final series of experiments on corona polarity showed that a positive discharge was preferable for methane decomposition.

No description available.

No description available.