This thesis discusses optoelectronic devices at mm-wave frequencies, focusing on optoelectronic beamforming and non-mechanical beam steering based on an optically excited Fresnel zone plate plasma. The optically controlled zone plate, termed the photo-injected Fresnel zone plate antenna (piFZPA) within this work, is introduced and a comprehensive theoretical framework developed. The design and optimisation of Fresnel zone plates are detailed, which determine the inherent performance of the piFZPA. A range of zone plates were designed, fabricated, and characterised at 94 GHz with up to 46 dBi gain, -26 dB sidelobe levels, and 67% aperture efficiency being measured for a quarter-wave design. The control of (sub) mm-wave beams by optical modulation of the complex permittivity of a semiconductor substrate is discussed. The significance of the free-carrier plasma dynamics, the effective lifetime, surface recombination, and the limits of the substrate which are imposed by the spatial resolution of the free-carrier plasma are highlighted, with the optimisation of these parameters discussed. The passivation quality of high-resistivity silicon wafers were characterised using a mm-wave photoconductance decay method, which yielded lifetime improvements from τ[subscript(eff)] = 60 us up to τ[subscript(eff)] ≈ 4,000 us, resulting in lowered recombination velocities (S = 15 cm/s). W-band characterisations of the passivated wafers illustrate the significance of surface recombination, with measured attenuations of up to 24 dB. Novel theoretical models are developed throughout this thesis, which yield insight into the requirements of optoelectronic devices, and are shown to agree well with measured data. The theoretical framework developed details the requirements, limitations, suitability, and design of piFZPAs at any frequency. A range of transmission-type piFZPAs are demonstrated and characterised at 94 GHz, both on-axis and off-axis, based on a novel architecture, with up to 8% aperture efficiency. Finally, the hybridisation of the piFZPA technique and well established visible display technologies, which has been developed throughout this thesis, enable low-cost, simple, and highly flexible optoelectronic devices, highlighting this method as an attractive solution to adaptive beamforming and non-mechanical steering at mm-wave and submm-wave frequencies.

In this study nano-patterning was carried out using two different nano-optic devices namely- the NSOM and Fresnel zone plate. In the first study, NSOM was used to generate nano-patterns on selected semiconducting (Si and Ge) and metallic (Cr, Cu and Ag) targets under different laser pulse durations, laser energies and number of laser pulses. Based on the experimental results, femtosecond laser pulses, provided lower pattern generation thresholds on targets but higher damage thresholds to the NSOM probes at the wavelength (~400-410 nm) studied, compared with nanosecond laser pulses. Three different mechanisms were identified as the dominant processes for pattern generation under different conditions, namely nano-scale laser ablation, nano-scale thermal oxidation and nano-scale melting/recrystallization of the targets. Furthermore, the resulting nano-patterns also showed a significant dependence on the optical properties (i.e., absorption coefficient and surface reflectivity) of the target material. By comparing the obtained experimental results, it was concluded that the optical energy transport from the NSOM probe to the target dominates the pattern generation when femtosecond laser is applied to the NSOM system. When nanosecond laser is applied, both the thermal and optical energy transported from the NSOM probe to the targets attribute to the obtained morphology of nano-patterns on different targets under the experimental conditions studied. In the second study, a traditional Fresnel zone plate with a focus length of 3 micrometres was fabricated with a novel lift-off process in e-beam lithography. The fabrication process involved, using a HSQ/PMMA bi-layer in a negative tone lift-off process with a layer of conducting polyaniline for charge dissipation. HSQ was used as the high resolution negative resist for e-beam patterning and the PMMA under-layer was used to enable a HSQ lift-off process. The fabricated Fresnel zone plate was used to generate nano-patterns on a UV sensitive photoresist using nanosecond laser light with lamda~409nm. The smallest pattern sizes generated was close to the diffraction limit. Nano-pattern sizes generated on the photoresist were comparable with a numerically calculated intensity distribution at the focus spot of the designed Fresnel zone plate obtained from Scalar Diffraction Theory.

In this research, Fresnel zone plates were studied using an accurate, full-electromagnetic simulator based on the body-of-revolution finite-difference time-domain (BOR-FDTD) method. This tool was used to investigate zone plates for two different applications: zone plates used as antennas in communication systems and zone plates used as focusing elements in free-space, focused-beam measurement systems. Through detailed studies of zone plates for these applications, a number of general characteristics of the zone plate were given a more in-depth look than they have been given in the past. For the first application, parametric studies were performed for Soret, folded, and grooved-dielectric, phase-correcting zone plates for antenna applications. These studies were used to generate new design graphs, from which general observations are made about the effect of varying different parameters on the focusing ability of a zone plate. For the grooved-dielectric, phase-correcting zone plate, these studies show that a number of factors influence the focusing ability in ways that are unexpected, based on many of the simple techniques typically used to analyze zone plates. Each of these factors is evaluated individually. For the second application, a zone plate was designed to be used as a focusing element in a free-space, focused-beam measurement system. To determine the suitability of zone plates for this application, simulations and measurements of the electric field were used to compare this zone plate to a doubly-hyperbolic lens. A complete focused-beam system, using two zone plates as focusing elements, was used to measure the permittivity of different dielectric materials. These measurements are compared to results for a system that uses doubly-hyperbolic lenses and to published values. A technique for increasing the usable bandwidth of a zone plate in a focused-beam system was proposed and tested. Finally, as a topic for future research, the question is posed: Using the BOR-FDTD method, can a similar volume of material be shaped in a way that results in improved focusing performance compared to a traditional zone plate? Some insight into this open-ended question can be gained by examining preliminary results of the optimization of zone plates using of a genetic algorithm.