γ-TiAl based alloys have attracted considerable research interest in the past few decades and have gained niche high temperature applications in aero-engines and automobiles. As high temperature structural materials, these alloys require stable microstructures. This thesis aims at addressing knowledge gaps in the understanding of microstructural stability in two technologically important γ-TiAl based alloys in different microstructures, viz. fully lamellar (FL) and duplex. Creep and exposure tests were complemented with a variety of microstructural characterization tools (SEM, EBSD, TEM, XRD). Density functional theory based calculations were also performed to further the understanding of stability of phases. In the first part of the thesis, microstructural stability of a FL microstructure was studied under creep and high temperature exposure conditions. An aim of these studies was to probe the effect of stress orientation with respect to lamellar plates on microstructural changes during primary creep. It was observed that retention of excess α2 resulted in an unstable microstructure and so under stress and temperature, excess α2 was lost. However, depending on stress orientation, the sequence of precipitates formed was different. In particular, for certain stress orientations, the formation of the non-equilibrium C14 phase was observed. The stress dependence of microstructural evolution was found to be stem from internal stresses due to lattice misfit and elastic moduli mismatch between α2 and γ. In the second part of this thesis, microstructural stability of a duplex alloy was probed, with an emphasis on understanding mechanisms that lead to tertiary creep. The as-extruded microstructure consisted of bands of equiaxed grains and lamellar grains. During creep, loss of lamellar grains was observed and this was attended by kinking of laths and formation of dynamically recrystallized equiaxed grains. Significant dislocation activity was seen in both lamellar and equiaxed grains at all stages of creep. Initially, dislocation activity leads to strengthening and primary creep behavior, but at later stages, it triggers dynamic recrystallization. Dynamic recrystallization was found to be the rate controlling creep mechanism. Accelerating creep behavior was due to strain localization during the constant load tensile test resulting from microstructural instabilities such as kinking.

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The subject of this master thesis is focused to the refining of the cast structure of gamma-TiAl–2Nb alloy using cyclic heat treatment and to the analysis of the grain refining mechanism. Structure evolution after applied cycles of heat treatment was characterized using light, laser and electron microscopy and using microhardness tests. Application of five heat treatment cycles during which two phase transformations (eutectoid and alpha-recrystallization reactions) repeatedly took place resulted in refining of the cast columnar structure having the mean grain size 512 microns to fully lamellar structure containing gamma and alpha2 phases having the mean grain size 229 microns. Lamellae thickness of gamma was not changed while the thickness of alpha2 phase decreased, up to 78 nm. Refining of alpha2 phase resulted in the increase of the microhardness by 20 %. The recrystallized cast structure obtained by cyclic heat treatment and the knowledge on the mechanisms of the refining the structure were compared with the literature data and were discussed in order to propose more efficient procedure for refining thermal treatment of cast TiAl alloys.