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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Ethanol amine functionalized electrospun nanofibers membrane for the treatment of dyes polluted wastewater

AlAbduljabbar, Fahad A., Haider, S., Alghyamah, A., Haider, A., Khan, R., Almasry, W.A., Patel, Rajnikant, Mujtaba, Iqbal M., Ali, F.A.A. 25 March 2022 (has links)
Yes / This study investigated adsorption kinetics, adsorption equilibrium, and adsorption isotherm of three dyes [i.e., methylene blue (MB), rhodamine-B (RB), and safranin T (ST)] onto polyacrylonitrile (PAN) and ethanolamine (EA) grafted PAN nanofibers (NFs) membranes (EA-g-PAN). The membranes were characterized by field emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FT-IR) spectroscopy, and Brunauer–Emmet–Teller (BET). FE-SEM showed a smooth morphology for the NFs before and after grafting, while FT-IR confirmed EA grafting into the nitrile group of PAN. The grafting percentage with no change in the physical nature of the membrane was 12.18%. The nitrogen adsorption–desorption isotherms for PAN and EA-g-PAN NFs membranes were similar and classified as a Type IV according to the International Union of Pure and Applied Chemistry. The surface area, pore-volume, and pore size of the EA-g-PAN increased to 21.36 m2 g−1, 0.16 cm3 g−1, and 304.93 Å, respectively. The pores were cylindrical mesopores with bimodal openings, which means that pores were open at both ends. The adsorption of the MB, RB, and ST dyes onto the PAN and EA-g-PAN NFs membranes leveled off at ~ 60 min. The adsorption kinetics showed good fitting to pseudo-second-order kinetic model and multi-step diffusion process. The order of the dye adsorption was PAN / the Deanship of Scientific Research, King Saud University [RG-1440-060]

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