La fluorescence en temps résolu est une méthode d'analyse spectrophotométrique avancée permettant la sélection des photons émis par luminescence sur un critère temporel. Il est ainsi possible, et cela même dans des milieux complexes et pollués issu de l'industrie, de faire émerger sélectivement le signal d'espèces luminescentes présentant des durées de vie de luminescence relativement grandes.Ce type d'analyse spectrale est particulièrement adapté à la détection de trace d'éléments lanthanides. Chacun des éléments de la série présente en effet des propriétés luminescentes uniques bien que largement fonction de la nature des ligands qui les entourent. Les travaux de thèse présentés dans ce manuscrit utilisent avantageusement la constatation précédente. Deux technologies ont étés mise sur pied et/ou optimisées pour permettre un transfert vers des domaines industriels aux cahiers des charges bien définis.Ainsi dans le domaine de la lutte anti-contrefaçon l'ajout de marqueurs luminescents à temps résolu à base de lanthanide rend possible la surveillance de l'origine et du devenir de divers produits industriels.Dans le domaine pétrolier l'analyse des effluents à l'aide de sondes luminescentes à base de lanthanide permet de quantifier le taux résiduel de plusieurs classes d'additifs chimiques et permet d'optimiser la sécurité, la rentabilité et l'impact écologique du processus d'extraction.Dernièrement un prototype de spectrofluorimètre résolu en temps adapté à un usage industriel a été mis au point pour permettre un transfert technologique du laboratoire vers le milieu industriel / Time-resolved fluorescence is an advanced spectrophotometric analysis method which allows the selection of emitted luminescent photons on a time-based parameters. It is possible to extract the signal of long-lived luminescent species even in complex and polluted matrix from the industry. This type of analysis is especially fitted for the detection of lanthanide ions. During this thesis two technologies based on time-resolved analysis were designed to answer specific industrial problematics. The first one yields the residual concentration of chemical additives used during oil and gas extraction. The second one aims at protecting crude oils and refined fuels from counterfeiting. They both rely on the use of lanthanide complex and the measurement of their luminescent properties. A prototype of time-resolved spectrofluorimeter was also built to transfer the technologies from the laboratory to the industrial world

Esta dissertação apresenta um estudo ergonômico sobre o trabalho de operadores de processo de plataformas marítimas de produção de petróleo. As primeiras investigações sobre as atuais práticas e produtos finais de projetos de sistemas produtivos de grande porte resultaram em indícios de um ambiente de produção com aspectos operacionais não equilibrados e desintegrados. A partir destes indícios, foi realizada uma revisão bibliográfica que destacou as considerações e limitações de aspectos relacionados à Ergonomia em assuntos como gestão de projetos, projetos de engenharia, de sistemas produtivos e de arranjo físico. A revisão relativa à Ergonomia destacou seus conceitos básicos, a Ergonomia de Concepção e estudos relacionados ao trabalho de operadores de produção contínua, tendo o objetivo de indicar possibilidades de atuações desta ciência em projetos de plantas produtivas. Desta forma, a pesquisa de campo desenvolvida procurou destacar aspectos operacionais como dificuldades e constrangimentos enfrentados pelos operadores. Tais aspectos foram investigados com o objetivo de ressaltar os desequilíbrios presentes nesta situação de trabalho e as estratégias desenvolvidas por estes operadores para manterem o funcionamento satisfatório da unidade produtiva, atendendo aos objetivos da organização empresarial em que se inserem. / This work presents the ergonomics study based on offshore oil production platforms, in operation works for the process plant. The first investigations resulted on indications of disintegrated and unbalanced operational aspects into the production environment. From those evidences, the bibliographical revision indicated the considerations and limits of aspects related to Ergonomics in subjects as design management, engineering design, productive systems and layout design. The revision of Ergonomics included basic concepts, Ergonomics of Conception, and studies related to the operator works of continuous production process, having the aim of indicating participation possibilities of this science in production plants design. In such a way, the developed research tried to raise operational aspects as difficulties and constraints daily faced by operators. Such aspects were investigated intending to stand out the disequilibriums in this situation of work and strategies developed by these operators to keep satisfactory performance of a productive unit, taking care of company goals where they are inserted.