This research evaluated the use of geosynthetic clay liners (GCLs) as a potential barrier material to the migration of metals that are leached from mine waste. This thesis consists of two parts. In the first part, micro analytical methods including µXRD with synchrotron-generated µXRF elemental mapping and synchrotron-based µXRD (S-µXRD) were used to characterize the GCL bentonite and distinguish how mechanisms of metal attenuation could be identified. These analytical methods were of particular use for the clay material as they offer non-destructive, in situ investigation of various soil characteristics with microspatial resolution. The combination of the analytical methods allowed for identification of minerals such as gypsum and pyrite, not accessible by conventional methods. In particular, distinguishing accessory crystalline phases present in the “starting material” bentonite from those formed as a result of interaction with metal-bearing leachates is critical, as the development of metal-attenuating crystalline phases can have a significant long-term impact on metal mobility. In the second part of the thesis, the migration behaviour of metals (As, Al, Cd, Cu, Fe, Mn, Ni, Sr, and Zn) was investigated by means of diffusion tests and permeation experiments using four metal-containing waters: acidic rock drainage (ARD), lime-treated ARD, water from gold mine tailings, and landfill leachate with metal loading. Effective diffusion coefficients of the metals were calculated by modelling laboratory diffusion and sorption data. Water pre-hydrated GCLs were permeated with 15-21 pore volumes (PVs) of solution and their interaction with these solutions was examined in terms of both the hydraulic conductivity and the change in the geochemical characteristics of the permeant over time. The greatest increase in hydraulic conductivity occurred for the acidic rock drainage, where it increased from 1.6x10-11 m/s to 1.3x10-10 m/s following 21 PVs of permeation; still a very low value when compared to regulatory standards for clay barrier materials. Observed delayed breakthrough curves were indicative of the GCL’s strong attenuation capacity for a number of metals. An understanding of mechanisms of metal retention at both the micro and macro-scale levels will facilitate effective pollution prevention using GCLs. / Thesis (Ph.D, Civil Engineering) -- Queen's University, 2009-04-26 18:46:23.02

A laboratory test program was conducted to investigate the effects of temperature, solution strength, and applied stress over increasing conditioning durations on cation exchange processes in sodium bentonite (Na-B) geosynthetic clay liners (GCLs). The test program was intended to determine if the variables of temperature, solution strength, and applied stress had beneficial or detrimental effects on the engineering behavior of Na-B GCLs in municipal solid waste (MSW) landfills and laboratory testing applications. Needlepunched-reinforced, double non-woven Na-B GCL specimens were conditioned in fluids of increasing ionic strength (DI water, 2 mM CaCl2, 50 mM CaCl2, and 200 mM CaCl2 representing control, pore water, mild MSW leachate, and harsh MSW leachate, respectively), temperatures of 5 degrees C, 20 degrees C, 40 degrees C, and 60 degrees C, and overburden stresses (30 kPa and 500 kPa representing stresses experienced by cover and bottom liner systems, respectively) which are all representative of geoenvironmental conditions observed in MSW landfill barrier systems. Cation exchange in the bentonite component of all conditioned Na-B GCL specimens was quantified by measuring the bound cation (BC) complexes and cation exchange capacities (CEC) of the specimens using inductively coupled plasma-optical emission spectroscopy (ICP-OES) analysis and by conducting index tests to determine the dimensional characteristics, swell index, and gravimetric moisture content of the specimens. For zero stress conditions, periodic measurements of electrical conductivity, total dissolved solids, sodium and calcium cation concentration, and temperature of the conditioning fluids were recorded to supplement bound cation complex data. For applied stress conditions, electrical conductivity, total dissolved solids, and temperature of the conditioning fluid were recorded. For zero stress conditions, 152 mm x 152 mm Na-B GCL specimens were conditioned in all conditioning fluids and temperatures over increasing time durations ranging from 4 hours to 32 days. For applied stress conditions, 60-mm-diameter Na-B GCL specimens were conditioned in 50 mM CaCl2 conditioning fluid at all temperatures for 4 to 16 days under the applied overburden stresses of 30 kPa and 500 kPa. Temperature, solution strength, and applied stress were all observed to affect cation exchange in the bentonite component of Na-B GCLs. Cation exchange processes were observed to increase with increasing temperature, increasing solution strength, and decreasing applied overburden stress. The majority of cation exchange processes were observed to occur within 8 to 10 days for specimens conditioned under zero stress. Cation exchange processes were observed to have a higher sensitivity to changes in solution strength (up to 625% increase in the change of Na+ BC from DI water to 200 mM CaCl2) compared to changes in temperature (up to 52% increase in the change of Na+ BC from 5 degrees C to 60 degrees C) in zero stress conditions. Changes in the bound cations of the Na-B GCL specimens over time were not reflected in the periodic electrical conductivity measurements taken of the high strength conditioning fluids. The results of this study can be used for quality assurance evaluations of in-service GCLs using thresholds developed for index properties. From the numerical thresholds determined in this study, hydrated Na-B GCL specimens sampled from the field conditioned under zero stress that exhibit swell indices greater than or equal to approximately 70% of the swell index reported by the manufacturer and gravimetric moisture contents of greater than or equal to approximately 200% will likely exhibit adequate hydraulic barrier performance. Hydrated Na-B GCL specimens sampled from the field conditioned under zero stress that exhibit swell indices of less than or equal to approximately 20% of the swell index reported by the manufacturer and gravimetric moisture contents of less than or equal to approximately 100% will likely exhibit inadequate hydraulic barrier performance. The Na-B GCL component of cover liner systems may be susceptible to high rates of cation exchange due to experiencing low overburden stress and elevated temperatures compared to typical earth temperatures. The Na-B GCL component of bottom liner systems may exhibit low rates of cation exchange due to experiencing high overburden stress and cooler temperatures.

Landfill facilities are required to have a barrier system that will limit escape of contaminants to groundwater and surface water for the contaminating lifespan of landfill. Heat generated by the biodegradation of waste and chemical reactions in landfills reduces the service-life of geomembranes by accelerating the ageing process of high-density polyethylene. It may also lead to the desiccation of clay components of the liners. Four considerations with respect to the evaluation of the potential effects of liner temperature on the service-life of liners and the potential control of liner temperature are examined. For the first time, the likely temperature and service-life of a secondary geomembrane in a double composite lining system is predicted. It is shown that, in some cases, the temperature is likely to be high enough to substantially reduce the service-life of the secondary geomembrane. The possible effectiveness of using tire chips as passive thermal insulation between the primary and secondary liners, as well as traditional soil materials, is then explored. For the barrier system and contaminant examined, the results show that tire chips could potentially lower the temperature of the secondary geomembrane sufficiently to significantly extend its service-life. However, the use of tire chips brings about other practical issues, which are also discussed in this study. An active alternative method of controlling the increase in the landfill liner temperature is then examined. This approach, which is inspired by geothermal heat pumps, involves an array of cooling pipes beneath the waste. Numerical modelling showed that the hypotetical introduction of the cooling pipes resulted in a reasonable decrease in liner temperature. It is suggested that the proposed technique warrants further consideration. Finally the conditions that may lead to the desiccation of geosynthetic clay liners used in composite liners due to waste generated heat are examined and recommendations regarding possible means of mitigating the effects of heat on the performance of GCLs are presented. For example, numerical modelling shows that the hydration of GCL prior to waste placement, liner temperature, overburden stress, depth to aquifer and moisture content and grain size of subsoil affect desiccation. / Thesis (Ph.D, Civil Engineering) -- Queen's University, 2011-07-31 07:34:33.165

A literature review of municipal solid waste landfill design was conducted to provide the knowledge base for development of an environmental decision support system (Landfill Advisor). Landfill Advisor integrates the current knowledge of barrier systems into a software program to assist in landfill design. The choices available for each liner component (e.g., drainage layer, geomembrane liner, compacted clay liner, geosynthetic clay liner) and their suitability for different situations (e.g., final cover, base liner, lagoon liner) are presented. Landfill Advisor covers both the design and related operational issues for municipal solid waste landfills, with consideration given to the interactions between components, operating conditions, and the natural environment with a view to maximization of long-term system performance. Unique to Landfill Advisor, the service life of each engineered component is estimated based on results from the latest research. Original research is also presented on the risk of geosynthetic clay liner (GCL) desiccation in low stress applications such as solar ponds. Numerical modelling was undertaken using a thermo-hydro-mechanical model with parameters that were developed and verified by comparison to previously reported laboratory data. A parametric study was performed to establish recommendations for future investigation. The water retention curve of the GCL was found to have a significant effect on the conditions that are expected to cause desiccation. The temperature coefficient of the water retention curve was also found to have a significant effect, yet this parameter is not well defined. Poisson’s ratio was found to affect the risk of desiccation in proportion to the applied stress. As reported by previous researchers, the initial degree of saturation of a GCL was found to be important to desiccation; however, the effect is diminished at low applied stress. / Thesis (Master, Civil Engineering) -- Queen's University, 2012-09-28 18:52:20.106

An extensive laboratory test program was conducted to analyze and compare the cation exchange processes in three different varieties of sodium bentonite (Na-B) geosynthetic clay liners (GCLs) over increased conditioning durations up to 32 days and investigate the effects of temperature, solution strength, and applied stress. The goal of this test program was to establish whether the variables of temperature, solution strength, and applied stress improved or degraded the engineering properties of GCLs in laboratory testing and municipal solid waste (MSW) landfill applications. The GCLs were conditioned in liquids of increasing ionic strength, using deionized water and 2, 50, and 200 mM CaCl2 solutions to represent control, pore water, mild MSW leachate, and harsh MSW leachate. Conditioning periods were 1 to 32 days. Tests were conducted at 5°C, 20°C, 40°C, and 60°C and at 0 kPa, 30 kPa, and 500 kPa to represent stresses experienced by the cover and bottom liner. These variables were selected to represent geoenvironmental conditions observed in MSW landfill systems. Cation exchange processes in the bentonite component of the GCL were quantified by measuring the bound cation (BC) concentrations and cation exchange capacities (CEC) of the specimens and by conducting index testing to determine the dimensional measurements, final moisture content, and swell index of the conditioned bentonite. The temperature, electrical conductivity, total dissolved solids, sodium and calcium concentrations of the conditioning fluids were measured periodically for all specimens and the sodium concentration was measured for all specimens tested at applied stress. Temperature, solution strength, and applied vertical stress all affected the cation exchange processes in the bentonite component of GCLs. Increasing temperature, increased solution strength and decreased applied vertical stress were observed to increase cation exchange processes. The results of this study can be applied to quality assurance evaluations of in-service GCLs. In addition, the observation of the study indicates that GCLs used in cover liner systems for MSW landfills may be susceptible to high rates of cation exchange due to low overburden stresses and high surface temperatures. GCLs used in bottom liner may experience inhibited cation exchange rates as a result of high vertical stresses and relative lower temperatures.