The Biscayne Aquifer is a primary source of water supply in Southeast Florida. As a coastal aquifer, it is threatened by saltwater intrusion (SWI) when the natural groundwater flow is altered by over-pumping of groundwater. SWI is detrimental to the quality of fresh groundwater sources, making the water unfit for drinking due to mixing and reactions with aquifer minerals. Increasing water demand and complex environmental issues thus force water utilities in South Florida to sustainably manage saltwater intrusion and develop alternative water supplies (e.g., aquifer storage and recovery, ASR). The objectives of this study were to develop and use calibrated geochemical models to estimate water quality changes during saline intrusion and during ASR in south Florida. A batch-reaction model of saltwater intrusion was developed and important geochemical reactions were inferred. Additionally, a reactive transport model was developed to assess fate and transport of major ions and trace metals (Fe, As) at the Kissimmee River ASR. Finally, a cost-effective management of saltwater intrusion that involves using abstraction and recharge wells was implemented and optimized for the case of the Biscayne Aquifer. Major processes in the SWI areas were found to be mixing and dissolution-precipitation reactions with calcite and dolomite. Most of the major ions (Cl, Na, K, Mg, SO4) behaved conservatively during ASR while Ca and alkalinity were affected by carbonate reactions and cation exchange. A complex set of reactions involving thermodynamic equilibrium, kinetics and surface complexation reactions was required in the ASR model to simulate observed concentrations of Fe and As. The saltwater management model aimed at finding optimal locations and flow rates for abstraction and recharge wells. Optimal solutions (i.e., minimum total salt and total cost Pareto front) were produced for the Biscayne Aquifer for scenarios of surface recharge induced by climate change-affected precipitation. In general, abstraction at the maximum rate near the coast and artificial recharge at locations much further inland were found to be optimal. Knowledge developed herein directly supports the understanding of SWI caused by anthropogenic stressors, such as over-pumping and sea level rise, on coastal aquifers.

Managed aquifer recharge (MAR) is the purposeful recharge of an aquifer for later recovery or environmental benefits and represents a valuable method for sustainable water resources management. Models can be helpful tools for the assessment of MAR systems. This review encompasses a survey and an analysis of case studies which apply flow and transport models to evaluate MAR. The observed modeling objectives include the planning or optimization of MAR schemes as well as the identification and quantification of geochemical processes during injection, storage and recovery. The water recovery efficiency and the impact of the injected water on the ambient groundwater are further objectives investigated in the reviewed studies. These objectives are mainly solved by using groundwater flow models. Unsaturated flow models, solute transport models, reactive geochemical models as well as water balance models are also frequently applied and often coupled. As each planning step to setup a new MAR facility requires cost and time investment, modeling is used to minimize hazard risks and assess possible constraints of the system such as low recovery efficiency, clogging and geochemical processes.

Lieu de développement économique et démographique intense, les zones littorales font l'objet de pressions importantes sur l'environnement et, en particulier, sur les ressources en eau. Bien que la gestion des eaux souterraines côtières bénéficie de nombreux résultats issus de la recherche scientifique, une des problématiques majeures reste la connaissance de la géométrie des aquifères. Des interprétations géologiques de la genèse du bassin Plio-Quaternaire du Roussillon, issues de la stratigraphie séquentielle, sont confrontées, par l'intermédiaire d'une base données, à l'hydrogéologie de cet hydrosystème complexe localisé sur la partie littorale des Pyrénées-Orientales. L'étude statistique des points de prélèvement (distribution des crépines, productivité des forages...), l'analyse fonctionnelle (traitement du signal des chroniques piézométriques), l'hydrochimie et la géophysique électrique ont été utilisées afin d'élaborer un modèle conceptuel hydrogéologique des écoulements à l'échelle du bassin et de son prolongement vers le domaine offshore. La présence de la mer, de zones à salinité résiduelle et de cours d'eaux littoraux contribue à augmenter la salinité d'un aquifère libre supérieur (Quaternaire) sus-jacent aux différents aquifères captifs (Pliocène) exploités pour l'eau potable dans la zone littorale. La vulnérabilité face aux intrusions salines de cette ressource de bonne qualité, tant sur le point de vue quantitatif que qualitatif est appréhendée par modélisation. Dans le domaine offshore, le rôle protecteur des formations géologiques à faible et moyenne perméabilité est mis en évidence vis-à-vis de la préservation de la qualité de l'eau potable.