Many properties of photosensitize material is applied to the holographic recording of the photosensitive materials. The diacrylateis(RM257) is liquid crystalline materials. Beasuse the RM257 with photopolymeriable acrylate endgroups, under the action of light, polymerization of the mesogen with two polymerization groups lesds to crosslinked polymer networks. As the RM257 has a sensitivity to light and good molecular arrangement , it can be applied to optical storage. In this study, the use of the RM257 thin films as holographic recording materials ; the holography patterns were written using two s-s polarized, mutually coherence He-Ne laser at 633nm light. First, a single beam of He-Ne laser irradiates the RM257, and control exposure time, irradiation intensity, to investigate the RM257 on He-Ne laser (633nm) absorption. Then RM257 thin film exposed to two beams of He-Ne laser induced holographic interferemce fileld. Holography irradiation RM257 thin film arranged molecular singular direction and periodic alignment of molecular, and to fabricate the formation of holographic gratings. The sample temperature is controlled during holography irradiation, can improve RM257 thin film record as holographic interferemce fileld. To investigate holographic fileld induced the molecular of RM257 thin film.

A series of sol-gel based photopolymerizable silica glass for holographic storage have been synthesized via a facile chemical design in an effort to overcome the cracking problem incurred during the irradiation stage. The holographic composite material includes a low molecular weight polydimethylsiloxane (PDMS) with end-capped hydroxyl groups, an epoxide-containing coupling agent, a photopolymerizable acrylate monomer, and the sol-gel-derived silica matrix. Inclusion of PDMS provides improved compression stress and strain and toughness over the original unmodified samples, without deterioration on the diffraction efficiency (£b). A plateau value of £b ~ 40 % can be found under a beam power of 5.02 mW. Correlation between the molecular weight of acrylate polymer and £b of the holographic composite material is described and the discrepancies analyzed. The premature saturation of polymerization in the holographic system is attributed to the retarded free radical polymerization within the silica matrix. Minor variation of £b with photoinitiator concentration is observed, indicating that only moderate molecular weight is required for a reasonably high £b. The crack-free mechanism is based on the chemical and physical interactions within the material system. We also investigated the pore size and volume effect for optical properties, especially in studies of diffraction efficiency. With mixing rubber additives, the pore characteristics change via measurement of BET technique. The results indicated that moderate pore size made high diffraction efficiency for porous matrix and some characterizations also were presented. On the other hand, the optical application of this recording medium was described via 3D projected fringes profilometry (PFP) measurement. We recorded coded pattern on medium by employing fiber devices as light source. Using endoscope as image-derived tool, we get double-projected fringe images on tiny object. By PFP technique, a performed retrieved image can be achieved.

Methods for analysis and optimization of volume holographic recording are presented for two main groups of applications. In the first group of applications (mainly storage systems), the designs and the techniques of volume holography are well known and the main optimization effort is finding the proper material to store the holograms. One of the results of this research is complete global optimization of dynamic range and sensitivity in two-center recording that is the best technique for persistent rewritable storage. For this purpose, a complete theoretical analysis as well as experimental demonstration is presented. Also, other effects and processes such as electron tunneling and recording at high temperature are considered for possible improvement of the dynamic range of the material. For the second group of applications (mainly holographic optical elements), the focus of this research is on analysis and optimization of the design of the volume holograms in contrast to material optimization. A new method (multi-grating method) is developed for the analysis of an arbitrary hologram that is based on the representation of the hologram as the superposition of several plane wave gratings. Based on this method, a new class of optical devices that integrates the functionalities of different optical elements into a simple volume hologram is introduced and analyzed. As a result, very compact, low cost, and easy to use devices such as portable spectrometers can be made with particular applications in biological and environmental sensing.

A new technique for optical pattern recognition with two-center recording of persistent holograms in doubly doped LiNbO₃3:Fe:Mn crystal is presented, by which the holograms are localized in separate slices along the recording medium. The localized recording method has the distinctive advantage of selective recording and erasure of the individual holograms without affecting the entire holographic recording medium. This capability enables dynamic content modification of the optical pattern recognition systems. Also, the diffraction efficiency of localized holograms is much larger than that of the normal volume multiplexed holograms. It is theoretically shown that the localized holographic correlator (LHC) outperforms the conventional volume holographic correlators in terms of crosstalk, shift invariance, and capacity. The LHC is experimentally demonstrated. Several persistent holograms are localized within separate slices as close as 33 μm apart along the crystal. The excessive diffraction efficiency of the localized holograms is employed to enhance the LHC robustness through multiplexing several holograms per pattern within individual slices of the recording medium. A holographic data storage system based on two-center holographic recording in a doubly doped LiNbO3:Fe:Mn crystal is developed with angular multiplexing capability. The associated imaging system has been optimized for the pixel matching of pixelated bit patterns generated by a spatial light modulator (SLM) through the recording medium onto a camera. The initial multiplexed holograms show promising contrast of dark and bright pixels. With the optimized imaging system of the developed holographic memory, the implementation of a dynamic read/write data storage system with localized recording is envisioned. The large diffraction efficiency of the localized holograms enables multilevel (M-ary) data coding to improve the storage density of the system.

Wavelength division multiplexing (WDM) is essential for further enhancement of the transmission capacities of optical telecommunication systems. Key devices in WDM networks are multiplexing/demultiplexing components, which enable the combination/separation of several carrier waves with different wavelengths for the purpose of simultaneous transmission through one optical fibre. These components can be realized using Bragg diffraction from volume holographic gratings. Especially reflection holograms provide a pronounced wavelength selectivity which makes them attractive for free-space WDM applications. Holograms can be stored permanently in photorefractive lithium niobate crystals by the method of Thermal Fixing. Heating of the crystal during or after the recording process and subsequent development by homogeneous illumination at room temperature create nonvolatile holograms. The recording and development processes of Thermal Fixing in iron- and copper-doped lithium niobate crystals were investigated. Macroscopic Gaussian-shaped intensity patterns were used to analyse the origin of the fixing mechanism. Spatially resolved absorption measurements were performed to determine the concentration profiles of electron traps (Fe II/III) and protons. Results of computer simulations were compared with experimental results, which showed that protons can be found to work as compensators during hologram recording at temperatures around 180 degree C. Nevertheless thermal fixing without protons was possible, another compensation mechanism stood in. The obtained refractive-index changes were due to the electro-optic effect, other contributions could be neglected. With this detailed knowledge about thermal fixing, a two-channel demultiplexing unit was built by superposition of two thermally fixed reflection holograms in an iron-doped lithium niobate crystal. For this purpose a special two-beam interference setup with precisely adjustable writing angles was arranged in a vacuum chamber to eliminate thermally induced phase disturbances of the holographic recording procedure. Continuous development of the holograms by incoherent light was necessary. In the dark, the enhanced dark conductivity of the crystal used gave rise to a hologram degradation within about one day. Large diffraction efficiencies were attained (intensity losses between 2.3 and 5.2 dB only) uilizing crystals with high-quality polished surfaces. The crosstalk supression of the realized demultiplexer was > 25 dB, which is comparable with the performance of other multiplexing techniques like fibre Bragg gratings or arrayed-waveguide gratings. The low polarization dependence of the demultiplexer can be improved by superposition of two holograms for each channel.