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Purtsas, Alexander, Rosenkranz, Marco, Dmitrieva, Evgenia, Kataeva, Olga, Knölker, Hans-Joachim
04 June 2024
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We describe the oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols. The key step of these coupling reactions is an iron-catalyzed oxidative C−O or C−N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations are accomplished using hexadecafluorophthalocyanine−iron(II) (FePcF16) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant.
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