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Multistage hydraulic fracturing of horizontal wells continues to be a major technological tool in the oil and gas industry. Creation of multiple transverse fractures in shale gas has enabled production from very low permeability. The strategy entails the development of a Stimulated Reservoir Volume (SRV), defined as the volume of reservoir, which is effectively stimulated to increase the well performance. An ideal model for a shale gas SRV is a rectangle of length equal to horizontal well length and width equal to twice the half length of the created hydraulic fractures. This project focused on using the Multistage Transverse Fractured Horizontal Wells (MTFHW) for two novel applications. The first application considers using the SRV of a shale gas well, after the gas production rate drops below the economic limit, for low grade geothermal heat extraction. Cold water is pumped into the fracture network through one horizontal well drilled at the fracture tips. Heat is transferred to the water through the fracture surface. The hot water is then recovered through a second horizontal well drilled at the other end of the fracture network. The basis of this concept is to use the already created stimulated reservoir volume for heat transfer purposes. This technique was applied to the SRV of Haynesville Shale and the results were discussed in light of the economics of the project. For the second application, we considered the use of a similarly created SRV for producing hydrocarbon products from oil shale. Thermal decomposition of kerogen to oil and gas requires heating the oil shale to 700 degrees F. High quality saturated steam generated using a small scale nuclear plant was used for heating the formation to the necessary temperature. Analytical and numerical models are developed for modeling heat transfer in a single fracture unit of MTFHW. These models suggest that successful reuse of Haynesville Shale gas production wells for low grade geothermal heat extraction and the project appears feasible both technically and economically. The economics of the project is greatly aided by eliminating well drilling and completion costs. The models also demonstrate the success of using MTFHW array for heating oil shale using SMR technology.

Development of microsized batteries plays an important role in the design of in-situ electrochemical investigation systems and portable/wearable electronics. This emerging field intimately correlates with the topics of rechargeable batteries, nanomaterials, on-chip microfabrication, flexibility with reliable mechanical properties etc. Among the various energy materials, conversion-type materials have been proposed as high-energy-density alternatives to traditional intercalation-based materials. However, these materials usually show complex reaction processes accompanied by multi-reaction intermediates, which poses a great challenge to understand the chemical mechanisms. Benefiting from the merits of microsized battery devices, we develop a novel strategy to investigate and then optimize the electrochemical performance of a specific conversion-type material: nickel-iron oxide (NFO). Subsequently, this kind of materials are employed for flexible minimized energy storage systems. Unlike traditional characterization methods based on slurry-coated electrodes, micro-platforms directly probe the intrinsic electrochemical properties of a single active material in real-time due to the elimination of other additives. In this thesis, we firstly design a micro-lithium batteries (MLBs), based on a single “Swiss-roll” microtubular nanomembrane electrode. This platform enables us to investigate the electrochemical mechanisms of electrode materials in lithium batteries by in-situ Raman spectroscopy, electrical conductivity measurements, and electrochemistry characterization. With this designed MLBs, we systematically studied NFO nanomembranes. Using in-situ Raman spectroscopy during the delithiation/lithiation process, we monitored the transition of the chemical component directly. Guided by our investigations of micro-batteries, composite NFO nanomembrane electrodes were fabricated and tested in coin cells, which showed an excellent rate performance: 440 mAh g-1 at a high rate of 20 A g-1 and a long-term stable cycling performance over 1600 cycles. One step further, a flexible energy storage micro-device is achieved using such optimized materials. We demonstrate a thin, lightweight, and flexible micro-full lithium-ion battery based on nickel-iron oxide with a high-rate performance and energy density that can be repeatedly bent to 180° without structural failure and performance loss. It delivers a stable output capacity of 140 mAh g-1 over 1000 charge/discharge cycles. Meanwhile, the excellent rate performance guarantees high energy output up to 255 W h kg-1 at a high power density of 12000 W kg-1 at the microscale.