<p>Biomass is considered to be a sustainable energy source with significant potentials for replacing electricity and fossil fuels, not at least in the residential sector. However, present wood combustion is a major source of ambient concentrations of hydrocarbons (e.g. VOC and PAH) and particulate matter (PM) and exposure to these pollutants have been associated with adverse health effects. Increased focus on combustion related particulate emissions has been seen concerning the formation, characteristics and implications to human health. Upgraded biomass fuels (e.g. pellets) provide possibilities of more controlled and optimized combustion with less emission of products of incomplete combustion (PIC´s). For air quality and health impact assessments, regulatory standards and evaluations concerning residential biomass combustion, there is still a need for detailed emission characterization and quantification when using different fuels and combustion techniques.</p><p>This thesis summarizes the results from seven different papers. The overall objective was to carefully and systematically study the emissions from residential biomass combustion with respect to: i) experimental characterization and quantification, ii) influences of fuel, appliance and operational variables and iii) aspects of ash and trace element transformations and aerosol formation. Special concern in the work was on sampling, quantification and characterization of particulate emissions using different appliances, fuels and operating procedures.</p><p>An initial review of health effects showed epidemiological evidence of potential adverse effect from wood smoke exposure. A robust whole flow dilution sampling set-up for residential biomass appliances was then designed, constructed and evaluated, and subsequently used in the following emission studies. Extensive quantifications and characterizations of particulate and gases emissions were performed for residential wood and pellet appliances. Emission factor ranges for different stoves were determined with variations in fuel, appliance and operational properties. The emissions of PIC´s as well as PM_tot from wood combustion were in general shown to be considerably higher compared to pellets combustion. PAH_tot emissions were determined in the range of 1300-220000 µg/MJ for wood stoves and 2-300 µg/MJ for pellet stoves with phenantrene, fluoranthene and pyrene generally found as major PAH´s. The PM emissions from present residential appliances was found to consist of significant but varying fractions of PIC´s, with emissions in the range 35-350 mg/MJ for wood stoves compared to 15-45 mg/MJ for pellet stoves. Accordingly, the use of up-graded biomass fuels, combusted under continuous and controlled conditions give advantageous combustion conditions compared to traditional batch wise firing of wood logs. The importance of high temperature in well mixed isothermal conditions was further illustrated during pellets combustion to obtain complete combustion with almost a total depletion of PIC´s. Fine (100-300 nm) particles dominated in all studied cases the PM with 80-95% as PM1. Beside varying fractions of carbonaceous material, the fine PM consisted of inorganic volatilized ash elements, mainly found as KCl, K₃Na(SO₄)₂ and K₂SO₄ with mass concentrations at 15-20 mg/MJ during complete combustion. The importance of the behavior of alkali elements for the ash transformation and fine particle formation processes was further shown, since the stability, distributions and compositions also directly control the degree of volatilization. In addition to the alkali metals, zinc was found as an important element in fine particles from residential biomass combustion. Finally, the behaviour of volatile trace elements, e.g. Zn and Cd, during pellets production and combustion were studied. A significant enrichment in the pellet fuel during the drying process was determined. The magnitude and importance of the enrichment was, however, relative small and some alternative measures for prevention were also suggested.</p>

Biomass is considered to be a sustainable energy source with significant potentials for replacing electricity and fossil fuels, not at least in the residential sector. However, present wood combustion is a major source of ambient concentrations of hydrocarbons (e.g. VOC and PAH) and particulate matter (PM) and exposure to these pollutants have been associated with adverse health effects. Increased focus on combustion related particulate emissions has been seen concerning the formation, characteristics and implications to human health. Upgraded biomass fuels (e.g. pellets) provide possibilities of more controlled and optimized combustion with less emission of products of incomplete combustion (PIC´s). For air quality and health impact assessments, regulatory standards and evaluations concerning residential biomass combustion, there is still a need for detailed emission characterization and quantification when using different fuels and combustion techniques. This thesis summarizes the results from seven different papers. The overall objective was to carefully and systematically study the emissions from residential biomass combustion with respect to: i) experimental characterization and quantification, ii) influences of fuel, appliance and operational variables and iii) aspects of ash and trace element transformations and aerosol formation. Special concern in the work was on sampling, quantification and characterization of particulate emissions using different appliances, fuels and operating procedures. An initial review of health effects showed epidemiological evidence of potential adverse effect from wood smoke exposure. A robust whole flow dilution sampling set-up for residential biomass appliances was then designed, constructed and evaluated, and subsequently used in the following emission studies. Extensive quantifications and characterizations of particulate and gases emissions were performed for residential wood and pellet appliances. Emission factor ranges for different stoves were determined with variations in fuel, appliance and operational properties. The emissions of PIC´s as well as PMtot from wood combustion were in general shown to be considerably higher compared to pellets combustion. PAHtot emissions were determined in the range of 1300-220000 µg/MJ for wood stoves and 2-300 µg/MJ for pellet stoves with phenantrene, fluoranthene and pyrene generally found as major PAH´s. The PM emissions from present residential appliances was found to consist of significant but varying fractions of PIC´s, with emissions in the range 35-350 mg/MJ for wood stoves compared to 15-45 mg/MJ for pellet stoves. Accordingly, the use of up-graded biomass fuels, combusted under continuous and controlled conditions give advantageous combustion conditions compared to traditional batch wise firing of wood logs. The importance of high temperature in well mixed isothermal conditions was further illustrated during pellets combustion to obtain complete combustion with almost a total depletion of PIC´s. Fine (100-300 nm) particles dominated in all studied cases the PM with 80-95% as PM1. Beside varying fractions of carbonaceous material, the fine PM consisted of inorganic volatilized ash elements, mainly found as KCl, K3Na(SO4)2 and K2SO4 with mass concentrations at 15-20 mg/MJ during complete combustion. The importance of the behavior of alkali elements for the ash transformation and fine particle formation processes was further shown, since the stability, distributions and compositions also directly control the degree of volatilization. In addition to the alkali metals, zinc was found as an important element in fine particles from residential biomass combustion. Finally, the behaviour of volatile trace elements, e.g. Zn and Cd, during pellets production and combustion were studied. A significant enrichment in the pellet fuel during the drying process was determined. The magnitude and importance of the enrichment was, however, relative small and some alternative measures for prevention were also suggested.

The topic of my diploma thesis draws on my bachelor thesis, which described combustion products of selected substances in the complete combustion. The diploma thesis focused on the incomplete combustion in the same substances to make a comparison possible. In the chapter on the substances selected for burning, the substances were described theoretically first. Further, the burning was carried out, the products that came into being were collected into collection bags and sent to the laboratory of the Institute of Population Protection in Lázně Bohdaneč to be analysed. After receiving the records all possible effects on human health were carried out, and the results were compared with those of the bachelor thesis. The analyses showed that carbon monoxide and sulphur dioxide appeared in all analyses, while the remaining substances differed to a minimum extent, however, they are in much higher concentrations than in the perfect combustion. I added two more substances that had not been in my bachelor thesis to those that were burnt, but in the course of two years their application became a common practice, and they play an increasingly more significant role in our life. The task of the chapter dealing with the detection technique was to find out and describe the possibilities of the commander in detecting the combustion products directly on the spot of the actual operation in the shortest possible time, to enable him to propose the protection of the firemen, and possibly to establish the possibilities of taking samples, transport to the laboratory, conducting a laboratory analysis and establishing the approximate time when he could obtain the first sampling results. All of this was focused on the possibilities of the Fire Rescue Service of the Region of South Bohemia (HZS JčK). The next chapter concerned their colleagues of the Fire Rescue Service of the Region of South Bohemia in České Budějovice, in which a questionnaire investigation was focused on them, identical with that of my bachelor thesis. As I had succeeded in including the results of my bachelor thesis into a training course, I wondered whether the knowledge would improve or not. After a comparison with the results from my bachelor thesis with the new ones the conclusions turned out to be favourable, and suggested in which way the training courses - not only for the professional units - should proceed. The results of the new questionnaire investigation, which showed an improvement, should form a basis of a campaign focusing on the non-professional public, which should be acquainted with what they breathe in the event that they burn vast variety of waste. I believe that results would be achieved even here in the form of a deeper knowledge and a better quality of the air we breathe.

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Possible areas of improving the efficiencies of the Lincoln University flame weeder are identified and investigated. The Hoffmann burner initially used in the Lincoln University flame weeder was found not to entrain sufficient air to allow complete combustion of the LPG used. A new burner, the Modified Lincoln University burner, was designed to improve the entrainment of air. Results show that the new design entrained sufficient air to theoretically allow complete combustion of the LPG, and this resulted in a 22.7% increase in heat output per Kg of LPG used over the Hoffmann burner. Temperature x time exposure constants required to kill weeds 0 - 15, 15 - 30, and 30 - 45 mm in size, were found to be respectively 750, 882, and 989 degrees Celsius.Seconds. These constants can be used to calculate the maximum speed of travel an operator can use a flame weeder at, once the temperature profile underneath its shields are established at various travel speeds, and therefore ensure that the flame weeder is used at its maximum efficiency. The constants can also be used to establish the cost efficiency of any flame weeder (in $/Ha), depending on the size of the weeds to be treated. The materials and methods used in establishing the temperature x time exposure constants can be used to establish the temperature x time exposure constant of any weed species at any size.