Composite magneto-dielectric materials have been investigated over the years because of their potential applications in RF and microwave devices as the dielectric constant and permeability can be individually changed in these materials. In the recent past, there is a renewed interest in systems classified as ferroelectromagnets or multiferroics, which possess simultaneous ferroelectric and magnetic ordering as well as interesting magnetoelastic phenomena. In all these ferrite-ferroelectric materials, the coupling between the permeability (μ) of the magnetically ordered phase and permittivity (e) of the ferroelectric phase make them attractive candidates for multifunctional applications. Ba0.5Sr0.5TiO3 (BSTO) is a ferroelectric with potential applications in tunable filters, antennas, and thin film capacitors. BaFe12O19 (BaF) is a hard ferromagnet with large in-plane anisotropy which makes it promising for use in microwave and RF devices that need permanent magnets for biasing requirements. We have used magnetron sputtering to deposit multilayer films of BSTO and BaF on Al2O3 and heated Si/SiO2. To our knowledge this is the first attempt at combining these technologically important materials in multilayer form. The as-deposited films were amorphous and post-annealing was optimized until distinct BSTO and BaF x-ray peaks could be identified. Surface and images were obtained by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The multilayer structure and BSTO/BaF interfaces were identified using cross-sectional SEM. Magnetic properties of the multilayer films were measured using a Physical Properties Measurement System (PPMS) by Quantum Design at 10K and 300K over a range of magnetic field (0 < H < 7T). We have attempted to correlate some of the magnetic characteristics with the film microstructure. In addition, we have deposited layers of Fe3O4 nanoparticles onto both bare Si/SiO2 substrates and the surfaces of the multilayers using Langmuir-Blodgett technique. Preliminary images of monolayer Fe3O4 particles reveal some ordering present. We have also used the PPMS to look at the magnetic properties of the particles, both by themselves and deposited onto the multilayers to see what magnetic effects the particles have on ferrite-ferroelectric systems.

<p>This report presents a model to determine the solar Extreme UltraViolet (EUV) intensity and the ion flux in the vicinity of Saturn, by using measurements from the Langmuir probe, a plasma investigation instrument, of the Cassini satellite. The model is based on in situ measurements and does therefore provide an improved estimation of the wanted parameters compared to previously used calculations based only on the EUV flux measured near Earth. The solar EUV and ion flux were determined by analysing and processing the current measurements from the Cassini Langmuir probe in several steps. Initially the time intervals where the measured current were expected to be due only to the photoelectron current was extracted. The photoelectron current is the part of the measured probe current that is only due to electrons ejected from the probe by photons coming from the Sun. The measurements showed a periodic behaviour which was concluded to be due to the attitude of the satellite. This interfering effect was corrected for and the data was then plotted against an EUV index, estimated from a traditionally used proxy of the EUV flux near Earth; the F10.7 solar radio flux index. In agreement with the theory of the photoelectric effect a linear relationship between the EUV flux and the photoelectron current <em>m_ph</em> was expected. A least square linear fit to the extracted photoelectron current data provided the relation, for the Langmuir probe on Cassini, in the form of the equation <em>m_ph</em>=0.1842<em>EUV</em>+0.2405, where <em>m_ph</em> is the photoelectron current in nA and <em>EUV</em> is the EUV index in W/Hzm^2. The derived equation is the result of the study, showing how to estimate the solar EUV flux using the Langmuir probe current measurements. This result was used to derive the other wanted parameter, the ion flux. The derivation was done by calculating the photoelectron current <em>m_ph </em>at all time and subtracting the result from the total current. The retrieved difference gives the magnitude of the ion current for every measurement.</p>

Quantum dots (QDs) of II-VI semiconductors (CdS, CdSe, and CdTe) in the size range of 1~12 nm have attracted great interest in both fundamental research and technical applications in recent years. Due to their tunable size-dependent emission with high photoluminescence quantum yields, their broad excitation spectra and narrow emission bandwidths, the semiconductor QDs have been intensively investigated in versatile applications, including thin-film light emitting devices (LEDs), low-threshold lasers, optical amplifier media for telecommunication networks and biological labels. Thus, constructing and fabricating highly ordered QDs are of great importance in the field of nanotechnology. The surface chemistry behavior of the TOPO-CdSe QDs and TOPO-(CdSe)ZnS QDs at the air-water interface was carefully examined by various physical measurements. The surface pressure-area isotherms of the Langmuir monolayers of both types of QDs gave the average diameter which matched the value determined by TEM measurements. Topographic study of the Langmuir monolayers of both QDs revealed the 2D aggregation during the early stage of the compression process. The stability of the Langmuir monolayer of the TOPO-(CdSe)ZnS QDs was measured by the compression/decompression cycle and the kinetic measurements, both of which indicated that TOPO capped (CdSe)ZnS QDs can form stable Langmuir monolayers at the air-water interface. Langmuir-Blodgett (LB) film of the TOPO-(CdSe)ZnS QDs were prepared on quartz slides at different surface pressures and characterized by photoluminescence (PL) spectroscopy. The linear increase of the PL intensity with the increase of the number of layers deposited onto the quartz slide implied a homogeneous deposition of the Langmuir monolayer. The conjugates of 10, 12-pentacosadiynoic acid (PDA) and short chain peptide was used to modify the surface of (CdSe)ZnS core-shell QDs. The PDA-peptide capped QDs formed stable Langmuir monolayer. After the photopolymerization of PDA-peptide-QDs/PDA-peptide system at the air-water interface, a more uniform and robust Langmuir monolayer was constructed. The 3-mercaptopropyltrimethoxysilane (MPS) was linked to (CdSe)ZnS QDs by ligand exchange method. The sol-gel process of the MPS capped QDs Langmuir monolayer was studied under various subphases of pH and reaction time. The fast sol-gel process under a subphase of pH 12.0 led the formation of a more homogeneous Langmuir monolayer. A smooth MPS-QDs LB film deposited under pH 12.0 was also observed by AFM measurements. The imaging of the aggregates of lysozyme using lysozyme/(CdSe)ZnS QDs conjugate as a PL label was investigated. The amyloid fibrils formed by lysozyme/lysozyme-QDs conjugate were observed by epifluorescence microscopy, atomic force microscopy (AFM) and transmission electron microscopy (TEM) measurements. The emission intensity of the QDs labeled lysozyme was increased about 3 fold after formation of amyloid. This approach, for the first time, provided a convenience method to image the amyloid fibrils by epifluorescence microscopy.

Accumulation or aggregation of amyloidogenic proteins in the brain plays a central role in neurodegenerative diseases. The most common and highly growing form of dementia in the elderly population is Alzheimer's disease (AD) followed by Parkinson's disease (PD). The major proteins associated are amyloid beta (Abeta) and alpha-synuclein (alpha-syn) in AD and PD, respectively. These proteins are released or found near the neuronal membranes in the brain. Consequently to understand the behavior of the proteins using a model membrane system becomes an important facet of understanding these diseases. Langmuir monolayer approach was used to study the surface chemistry and spectroscopy of Abeta (1-40), Abeta(1-42) and alpha-synuclein. Moreover, surface chemistry of a model protein namely, lysozyme was investigated. In recent times, quantum dots (QDs) are considered as potential probes for bio-imaging. These particles can be beneficial when it comes to the investigation of neurodegenerative diseases. The effect of nanoparticles, i.e., CdSe/ZnS QDs on Abeta (1-42) morphology was investigated. Nevertheless, it was observed that the capping ligand plays a significant role in the surface chemistry of QDs when mixed with or conjugated to Abeta (1-42). Surface pressure- and surface potential-area isotherms were used to characterize the lysozyme Langmuir monolayer. The compression-decompression cycles and stability measurements showed a homogeneous and stable monolayer at the air-water interface. Salt concentration in the subphase and pH of the subphase were parameters controlling homogeneity and stability of the Langmuir monolayer. In situ UV-vis and fluorescence spectroscopies were used to verify the homogeneity of the lysozyme monolayer, and to identify the chromophore residues in the lysozyme. Optimal experimental conditions were determined to prepare a homogeneous and stable lysozyme Langmuir monolayer. The surface chemistry and spectroscopy of the reduced lysozyme Langmuir monolayer were investigated at different pH values and were compared to a native lysozyme. It was established that the limiting molecular area of the reduced lysozyme was not subphase pH dependent as was found for the native one. To explain this result in terms of the conformation and orientation of the lysozyme Langmuir monolayer at various subphase pH values, we have used Infrared Reflection Absorption Spectroscopy (IRRAS). The interpretation of the results suggests a change in the conformation and orientation of the native lysozyme Langmuir monolayer with the subphase pH 3, 6 and 11. The surface chemistry of Abeta (1-40) and its interaction with the lipid raft Langmuir monolayer were examined where the stability of the lipid raft Langmuir monolayer came out as an essential parameter. Lipid raft Langmuir monolayer in the presence or absence of ganglioside GM1 having POPC as one of the phospholipids was found to be very unstable and collapsed within 26 min. Whereas, the phospholipid DPPG improved the stability of the monolayer significantly when cholesterol was used in excess. We have examined the surface and spectroscopic properties of Abeta (1-42) mixed with or conjugated to dihydrolipoic acid (DHLA)- and polyethylene glycol (PEG)- capped CdSe/ZnS QDs. Surface pressure-area isotherms, in situ UV-vis absorption, and fluorescence spectroscopy were used to characterize the Abeta (1-42) mixed with or conjugated to QDs at the air-water interface. The capping of QDs played a role in surface chemistry as was determined by surface pressure-area isotherms and spectroscopic properties of the Langmuir monolayer. Furthermore Abeta(1-42) was bioconjugated to DHLA-capped CdSe/ZnS QDs. Upon conjugation of Abeta (1-42) to DHLA-capped QDs, the sample was incubated at 37oC, the process of fibrillation was inhibited as compared with a sample where Abeta (1-42) was simply mixed with the QDs. Transmission electron microscopy (TEM) and atomic force microscopy (AFM) were employed for the analysis of the samples. The morphology of fibrils and reduction in number of fibrils was substantial in the case of Abeta(1-42) conjugated to QDs. Reduction in fibrillation was also confirmed using a Thioflavin T assay. Moreover, quenching of tyrosine signal was observed in presence of the QDs, which indicates an interaction of QDs to the tyrosine residue in Abeta (1-42). The Surface chemistry and spectroscopy of alpha-syn, which is a natively unstructured protein important in the neuropathology of PD was investigated. IRRAS was utilized to investigate its conformation, alpha-syn was found to form a Langmuir monolayer in alpha-helical conformation with its helical axis parallel to the air-water interface.

Langmuir-Blodgett (LB) organic monomolecular (monolayer) films containing fatty acids and their perfluorinated counterparts separate into phases under certain conditions. These perfluorinated surfactant containing mixed-phase systems have been shown to exhibit many favourable attributes in comparison to non- perfluorinated surfactant monolayers. In this thesis project, two of these films were investigated. One film is a 2:1 ratio mixture of arachidic acid (C19H39COOH AA) to perfluorotetradecanoic acid (C13F27COOH PA), which phase-separates into hexagonal domains ~6 ìm large (2:1 ratio of AA to PA 2AA1PA). The other film is a 2:1 mixture of stearic acid (C17H35COOH - SA) to PA, which phase-separates into linear domains ~300 nm wide (2:1 ratio of SA to PA 2SA1PA).<p> Through the use of atomic force microscopy (AFM), and various synchrotron photoemission electron microscopy-based (PEEM) techniques, the films were characterized. As properties such as molecular organization, and dispersion of the molecules in the film, affect film function, it is necessary to use a variety of techniques to better understand order and composition in the films.<p> First, the well-known and previously-studied film, 2AA1PA, was used to better understand contrast mechanisms in the energy filtered x-ray photoemission electron microscope (X-PEEM) at the CLS. Through the use of techniques such as secondary electron emission microscopy (SEEM), ultraviolet photoelectron spectroscopy (UPS), and x-ray linear dichroism microscopy (XLDM), the effects of secondary electrons, valence character, and polarization dependence were studied so as to better understand their contribution to contrast in energy-filtered PEEM-based spectromicroscopy.<p> Second, the composition and organization of a novel system (2SA1PA), was characterized using traditional near-edge x-ray absorption fine-structure (NEXAFS) spectroscopy. As the size of the domains in the 2SA1PA system are below the spatial resolution limit of PEEM spectromicroscopy, methods involving selective phase dissolution, and spectrum subtraction, were used to acquire phase composition and molecular order information.<p> The high lateral and vertical spatial resolution of AFM allowed physical imaging and confirmation of sample structure, as well as very accurate domain height determination. X-PEEM supplements this with chemical sensitivity using high spatial resolution spectromicroscopy. Therefore, using AFM and X-PEEM as complimentary techniques, it is possible to physically and chemically characterize phase-separated monolayer films.

This report presents a model to determine the solar Extreme UltraViolet (EUV) intensity and the ion flux in the vicinity of Saturn, by using measurements from the Langmuir probe, a plasma investigation instrument, of the Cassini satellite. The model is based on in situ measurements and does therefore provide an improved estimation of the wanted parameters compared to previously used calculations based only on the EUV flux measured near Earth. The solar EUV and ion flux were determined by analysing and processing the current measurements from the Cassini Langmuir probe in several steps. Initially the time intervals where the measured current were expected to be due only to the photoelectron current was extracted. The photoelectron current is the part of the measured probe current that is only due to electrons ejected from the probe by photons coming from the Sun. The measurements showed a periodic behaviour which was concluded to be due to the attitude of the satellite. This interfering effect was corrected for and the data was then plotted against an EUV index, estimated from a traditionally used proxy of the EUV flux near Earth; the F10.7 solar radio flux index. In agreement with the theory of the photoelectric effect a linear relationship between the EUV flux and the photoelectron current mph was expected. A least square linear fit to the extracted photoelectron current data provided the relation, for the Langmuir probe on Cassini, in the form of the equation mph=0.1842EUV+0.2405, where mph is the photoelectron current in nA and EUV is the EUV index in W/Hzm^2. The derived equation is the result of the study, showing how to estimate the solar EUV flux using the Langmuir probe current measurements. This result was used to derive the other wanted parameter, the ion flux. The derivation was done by calculating the photoelectron current mph at all time and subtracting the result from the total current. The retrieved difference gives the magnitude of the ion current for every measurement.

Saturn’s largest moon, Titan, presents a very interesting subject for study because of its atmosphere’s complex organic chemistry. Processes taking place there might shed some light on the origins of organic compounds on Earth in its early days. The international spacecraft Cassini-Huygens was launched to Saturn in 1997 for a detailed study of the gas giant and its moons, specifically Titan. The Swedish Institute of Space Physics in Uppsala has manufactured the Langmuir probe instrument for the Cassini spacecraft now orbiting Saturn, and is responsible for its operation and data analysis. This project concerns the analysis of Titan’s ionosphere measurements from this instrument, from all “deep” flybys of the moon (&lt;1400km altitude) in the period October 2004 - April 2010. Using the Langmuir Probe analysis tools, the ion flux is derived by compensating for the atmospheric EUV extinction (that varies with the photoelectron current from the probe). The photoelectron current emitted from the probe also gives an artifact in the data that for this project needs to be deducted before analysis. This factor has already been modeled, while the extinction of Titan’s atmosphere has only been taken into account on event basis (not systematically). The EUV corrected ion flux data is then used to derive the ion number density in Titan’s atmosphere, by setting up an average ion mass altitude distribution (using the Ion Neutral Mass Spectrometer results for comparison) and deriving the spacecraft speed along the Cassini spacecraft trajectory through Titan’s ionosphere. The ion number density results proved to correlate very well with the theoretical ionospheric profiles on the day side of Titan (see graphical representation in the Results section). On the night side, a perturbation of the ion flux data was discovered by comparison with Ion Neutral Mass Spectrometer data, supporting earlier measurements of negative ions reported by Coates et al 2009. The project was carried out at the Swedish Institute of Space Physics (Institutet för Rymdfysik, IRF) in Uppsala. / Saturnus största måne Titan är ett väldigt intressant forskningsobjekt på grund av dess atmosfärs komplexa organiska kemi. Processer som pågår i Titans täta atmosfär kan hjälpa oss att förstå ursprunget till organiska föreningar på Jorden i dess unga ålder. Den internationella rymdsonden Cassini-Huygens blev uppskjuten mot Saturnus 1997, för att i detalj undersöka gasjätten och dess månar, speciellt Titan. Institutet för Rymdfysik (IRF) i Uppsala är ansvariga för operation och dataanalys av Langmuirsonden ombord Cassini som ligger i omloppsbanan kring Saturnus sedan 2004. Detta projekt omfattar analys av Langmuirsondens mätningar av Titans jonosfär från alla ”djupa” förbiflygningar av månen under perioden oktober 2004 – april 2010. Med hjälp av analysverktygen för Langmuirsonden, tas jonflödet fram efter kompensation för den atmosfäriska EUV extinktionen som ger upphov till fotoelektronströmmen från sonden. Fotoelektronströmmen som utsänds från proben ger en artefakt i data och måste (för detta projekt) korrigeras före analysen. Denna faktor är redan bestämd, men extinktionen av Titans atmosfär har endast korrigerats för i enstaka fall. Det korrigerade datat används för att få fram jondensiteten i Titans atmosfär genom att en genomsnittlig jonmass/höjd fördelning antas (jämförs med resultat från INMS-instrumentet) och kombineras med den beräknade hastighet som Cassini håller i banan genom jonosfären. Projektet utfördes vid Institutet för Rymdfysik, Uppsala.

This work studies the current collected by the spherical Langmuir probes to be mounted on the ESA Swarm satellites in order to quantify deviations from idealized cases caused by non-ideal probe geometry. The finite-element particle-in-cell code SPIS is used to model the current collection of a realistic probe, including the support structures, for two ionospheric plasma conditions with and without drift velocity. SPIS simulations are verified by comparing simulations of an ideal sphere at rest to previous numerical results by Laframboise parametrized to sufficient accuracy. It is found that for probe potentials much above the equivalent electron temperature, the deviations from ideal geometry decrease the current by up to 25 % compared to the ideal sphere case and thus must be corrected if data from this part of the probe curve has to be used for plasma density derivations. In comparison to the non-drifting case, including a plasma ram flow increases the current for probe potentials around and below the equivalent ion energy, as the contribution of the ions to the shielding is reduced by their high flow energy.

This thesis analyses the effect spin-orbit coupling has on the dispersion of Langmuir waves in magnetized plasmas, using recently developed kinetic theories of plasmas including quantummechanical and relativistic effects. Two new wave modes appearclose to the resonance <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5CDelta%20%5Comega_%7Bc%7D" /> = ( g/2 − 1)<img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Comega_%7Bc%7D" /> , where <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Comega_%7Bc%7D" /> is the cyclotron frequency and g is the electron gyromagnetic ratio. Forconsidered long wave lengths the deviation from this resonanceis very small. The wave modes are also very weakly damped.

Langmuir-Blodgett (LB) organic monomolecular (monolayer) films containing fatty acids and their perfluorinated counterparts separate into phases under certain conditions. These perfluorinated surfactant containing mixed-phase systems have been shown to exhibit many favourable attributes in comparison to non- perfluorinated surfactant monolayers. In this thesis project, two of these films were investigated. One film is a 2:1 ratio mixture of arachidic acid (C19H39COOH AA) to perfluorotetradecanoic acid (C13F27COOH PA), which phase-separates into hexagonal domains ~6 ìm large (2:1 ratio of AA to PA 2AA1PA). The other film is a 2:1 mixture of stearic acid (C17H35COOH - SA) to PA, which phase-separates into linear domains ~300 nm wide (2:1 ratio of SA to PA 2SA1PA).<p> Through the use of atomic force microscopy (AFM), and various synchrotron photoemission electron microscopy-based (PEEM) techniques, the films were characterized. As properties such as molecular organization, and dispersion of the molecules in the film, affect film function, it is necessary to use a variety of techniques to better understand order and composition in the films.<p> First, the well-known and previously-studied film, 2AA1PA, was used to better understand contrast mechanisms in the energy filtered x-ray photoemission electron microscope (X-PEEM) at the CLS. Through the use of techniques such as secondary electron emission microscopy (SEEM), ultraviolet photoelectron spectroscopy (UPS), and x-ray linear dichroism microscopy (XLDM), the effects of secondary electrons, valence character, and polarization dependence were studied so as to better understand their contribution to contrast in energy-filtered PEEM-based spectromicroscopy.<p> Second, the composition and organization of a novel system (2SA1PA), was characterized using traditional near-edge x-ray absorption fine-structure (NEXAFS) spectroscopy. As the size of the domains in the 2SA1PA system are below the spatial resolution limit of PEEM spectromicroscopy, methods involving selective phase dissolution, and spectrum subtraction, were used to acquire phase composition and molecular order information.<p> The high lateral and vertical spatial resolution of AFM allowed physical imaging and confirmation of sample structure, as well as very accurate domain height determination. X-PEEM supplements this with chemical sensitivity using high spatial resolution spectromicroscopy. Therefore, using AFM and X-PEEM as complimentary techniques, it is possible to physically and chemically characterize phase-separated monolayer films.