Agriculture and Agri-Food Canada (AAFC), the Ontario Greenhouse Vegetable Growers Association (OGVG), and Queen’s University’s Solar Calorimetry Laboratory (SCL) are undertaking a joint project to evaluate the energy and crop-yield benefits of operating commercial greenhouses in isolation from the outdoor environment, i.e., eliminating natural or forced ventilation to the exterior. Implementing such a scheme requires “closing” the greenhouse envelope and the installation of an active air-conditioning system to control temperature and moisture levels that could be harmful to crop growth. To this end, a prototype air-conditioning system, centered around a liquid desiccant dehumidifier, was designed, constructed and instrumented such that its thermal and functional performance could be evaluated over extended periods. The prototype unit was installed in a “research” greenhouse located at the Agriculture Canada, Greenhouse and Processing Crops Research Center (GPCRC) located in Harrow, Ontario. Both the novel air-conditioning and monitoring systems were implemented during the course of the thesis and operated for two preliminary crop trials to characterize system performance and identify aspects needing further refinement. Data obtained over these two initial periods, indicated that, the latent and sensible cooling capacity of the novel desiccant system averaged: 2.25 kW and -0.25 kW, respectively, during the severe summer trial; and 1.25 kW and -0.1 kW, respectively, during the milder spring trial. Values obtained from the preliminary monitored data also indicate that the liquid desiccant unit operated at electrical and thermal coefficients of performance (COPs) between 0.74 and 3.1 and between 0.15 and 0.52, respectively. Finally, using the monitored data, a simple regression-based empirical model was formulated to describe the average performance of the liquid desiccant unit. This was attempted to illustrate how performance results could be generalized to assist in the future design of similar commercial-scale systems. The results of this part of the thesis indicated, however, that further test data is required to confidently characterize the unit’s performance. As well, it was concluded that addition instrumentation (specifically, the addition of a meter to measure the flowrate of the regenerator air-stream) would enhance the potential to develop a practical performance correlation. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2013-11-01 14:12:54.326

Air-conditioning systems driven by solar energy have can save primary energy and reduce peak power consumption, which is particularly important for utility providers in the summer months. Additionally solar cooling is a promising application of solar thermal technology since the cooling load is well correlated to the overall solar availability. Liquid desiccant air-conditioning, which uses a salt solution to dehumidify air, can be used in a thermally driven air-conditioning system and offers many benefits for solar applications including the ability to store solar energy in the form of concentrated liquid desiccant. The current work focuses on the Queen’s University Solar Liquid Desiccant Cooling Demonstration Project. In previous work, a pre-commercial Liquid Desiccant Air Conditioner (LDAC) was installed and experimentally characterized using a gas-fired boiler to provide heat. As part of the current study a 95m2 solar array was added as a heat source. The Solar LDAC was tested for 20 days in the summer of 2012 to evaluate performance. The solar LDAC was found to provide between 9.2kW and 17.2kW of cooling power with an overall thermal Coefficient of Performance (COP) of 0.40 and electrical COP of 2.43. The collector efficiency was 53%, and 40% of the required thermal energy was provided by the solar array. A model was developed in TRNSYS to predict the performance of the solar LDAC and simulation results were compared to the experimental results with reasonable accuracy. The validated model was then used to simulate the annual performance of the solar LDAC in Toronto, Ontario; Vancouver, British Columbia; and Miami, Florida. The highest performance was achieved in Miami, where an overall thermal COP of 0.48 was predicted. It is proposed that additional improvements be made to the system by replacing inefficient pumps and fans, adding desiccant storage, and improving the control scheme. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2012-10-29 16:34:02.906

A numerical model for isothermal and non-isothermal flat-plate liquid-desiccant dehumidifiers and regenerators was developed and implemented. The two-dimensional model takes into account the desiccant, water and air flow streams. A parametric analysis was performed to evaluate the influence of some of the most important operational parameters on mass transfer performance, such as flow configuration, water mass flow rate and inlet temperature, and desiccant mass flow rate. The results indicate that the water temperature and mass flow rate have a strong effect on the performance of the dehumidifier and regenerator, with the isothermal wall case acting as an upper limiting case. Increasing the desiccant mass flow rate improves the water transfer performance, but the improvement is asymptotic with mass flow rate. An experimental rig with a single channel prototype was also built and tests were run for 18 different cases, with varying water mass flow rate, desiccant mass flow rate and flow configuration. The results show trends similar to those observed in the numerical results. However, the discrepancies between the numerical and experimental results are larger than the estimated experimental uncertainty at a 95% confidence level. There is some indication that poor desiccant wetting of the channel walls was partially responsible for the discrepancies. / Thesis (Ph.D, Mechanical and Materials Engineering) -- Queen's University, 2007-12-31 22:12:39.184

A thermal liquid desiccant air handling machine was procured, installed, and field tested. The goal of the present investigation is to evaluate the field performance of the machine and characterize its operation for the temperature range of a solar thermal array. The system studied includes a natural gas boiler supplying the heat, and a cooling tower for heat rejection. System performance was evaluated for the 50 to 90 C temperature range, the operating range of solar thermal collectors. Cooling power varied between 4.3 kW and 22.8 kW for this range of temperature, with a latent heat ratio between 1.1 and 1.9, confirming that the unit is significantly dehumidifying the process air stream. Electrical COP varied between 0.58 and 4.48. Performance data indicates higher temperature solar collectors such as evacuated tube or double glazed flat plat collectors would be optimum in a solar cooling application with this system. Empirical correlations for the regenerator and conditioner components were obtained using a multivariate linear regression model. 5 empirical relations were derived and can be used to characterize the thermal dehumidification concept. These relations and methods will be used in future work to simulate and optimize a solar thermal driven dehumidification system for dedicated outdoor air systems. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2008-09-28 04:36:36.26

Buildings are responsible for over a third of the energy consumption in the United States annually. This energy consumption contributes to some of the most pressing problems facing our society. Modeling of buildings and their systems is an integral part of most strategies for reduction of energy use in buildings. Modeling allows for informed building designs, optimization of systems, and greater market acceptance of new energy-saving technologies. This work addresses two particular modeling applications concerned with reduction of energy usage in buildings: convective heat transfer modeling in perimeter zones, and liquid desiccant dehumidification modeling. The first objective of this work is concerned with modeling convective transport in buildings and creation of inputs for energy modeling programs and passive pollutant removal calculations. This is accomplished through four investigations. In the first investigation, the influence of floor diffusers on convection heat transfer at perimeter zone windows in commercial buildings is measured. In the second, the impact of blinds on convection under a variety of circumstances is quantified. In the third, movement of air jets issuing from floor diffusers is predicted, and the effect of buoyancy on convective heat transfer at perimeter zone surfaces is analyzed. In the fourth investigation, convective mass transfer at indoor surfaces is investigated. Full scale experiments were conducted in support of these four investigations and semi-empirical correlations vii consistent with theory are given to predict jet movement and convective transport under a variety of circumstances. The second objective of this dissertation is concerned with modeling and analysis of liquid desiccant dehumidification systems and is pursued through three additional investigations. The first is concerned with modeling small-scale transport within the channels of a liquid desiccant absorber and regenerator. Physical and empirical models are developed which agree well with laboratory data. During the second investigation, a dynamic model of a liquid desiccant dehumidification system is developed and integrated into a full-building energy simulation. This is used to assess the potential applicability of the system in supermarkets in various climates. The models developed are used to optimize the system and develop a procedure to size components in the final investigation. / text

In Gulf Cooperation Council (GCC) countries, a lack of freshwater, poor soil quality, and ambient temperatures unsuitable for cultivation for parts of the year hinders domestic agriculture. The result is a reliance on a fluctuating supply of imported fresh produce which may have high costs and compromised quality. There are agricultural technologies available such as hydroponics and controlled environment agriculture (CEA) that can allow GCC countries to overcome poor soil quality and ambient temperatures unsuitable for cultivation, respectively. Evaporative cooling is the most common form of cooling for CEA and requires a significant amount of water. In water-scarce regions, it is desirable for sea or brackish water to be used for evaporative cooling. Unfortunately, in many coastal desert regions, evaporative cooling does not provide enough cooling due to the high wet-bulb temperature of the ambient air during hot and humid months of the year. A liquid desiccant dehumidification system has been proven to lower the wet-bulb temperature of ambient air in the coastal city of Jeddah, Saudi Arabia to a level that allows for evaporative cooling to meet the needs of heat-sensitive crops. Much of the past research on the regeneration of the liquid desiccant solution has been on configurations that release water vapor back to the atmosphere. Studies have shown that the amount of water captured by the liquid desiccant when used to dehumidify a greenhouse can supply a significant amount of the water needed for irrigation. This thesis studied the regeneration of a magnesium chloride (MgCl2) liquid desiccant solution from approximately 20 to 31wt% by direct contact membrane distillation and explored the possibility of using the recovered water for irrigation. Two microporous hydrophobic PTFE membranes were experimentally tested and modeled when the bulk feed and coolant temperature difference was between 10 and 60°C. In eight experiments, the salt rejection was higher than 99.97% and produced permeate suitable for irrigation with a concentration of MgCl2 less than 94 ppm.

The thesis explores the technical feasibility of an alternative method of decoupling air-conditioning systems function within the context of ecological issues. The system is a variant of dedicated outdoor air systems to separate dehumidification and cooling in air conditioning equipment. The project specifically investigates locating these components within the building envelope. Placement in the envelope moves the systems closer to fresh air and offers architectural expression for components that are normally out of sight. Designers, engineers, building science, mechanical, structural, biologist, and architectural engineers ideally as agents offer beneficial improvement to the system. The reduction in size of components into the building envelope offers risk. The thesis design space uses historical works, biological analogues, and past work to ground the technical understanding of the topic. Specific use of biological inspired design realizes translation from other systems to improve the alternative decoupled air conditioning system. The thesis develops prototype models for lighting analysis and for sensible and latent heat calculations. Psychrometric charts serve as tools to understand the thermodynamic air-conditioning process in conventional direct expansion vapor compression and solar liquid desiccant air conditioning systems. Data, models, and sketches provide tools for improvements to the 'thick' building envelope. Finally, the diagrams translate into functional decompositions for modifications to improve the system. The thesis probes the constraints in the areas of cost, fabrication, and technology that may not yet exist for selective improvement rather than a barrier to development of the thesis.

The main objective of this thesis research is to test the applicability of a novel heat and moisture transfer panel (HAMP) in an office building to control the space humidity. A HAMP is a panel that uses a liquid desiccant to add or remove heat and moisture to or from a space. This thesis research uses the TRNSYS computer package to model an office building in four different cities representing four climatic conditions. The cities are Saskatoon, Saskatchewan; Chicago, Illinois; Phoenix, Arizona; and Miami, Florida; representing cold-dry, cool-humid, hot-dry, and hot-humid climates, respectively. The HAMP is employed in the office building with a radiant ceiling panel (RCP) system. Three other HVAC systems are examined and compared to the system employing the HAMP. The systems are: a conventional all-air system, a RCP system with 100% outdoor air, a RCP system with a parallel dedicated outdoor air system (DOAS), and the RCP system with the HAMP and 100% outdoor air. In the latter, the HAMP covers 10% of the ceiling area and uses lithium chloride solution as the liquid desiccant at different temperatures and concentrations. The results show that the HAMP is able to control the space humidity within the control limits in all climates. The HAMP also shows the ability to provide better humidity control than the other systems as it directly responds to the space latent loads. The HAMP is able to control the relative humidity between 26% RH and 62%, 24% RH and 57% RH, 27% RH and 60%, and 40% RH and 62% RH in Chicago, Saskatoon, Phoenix, and Miami, respectively. The HAMP is able to achieve a relative humidity of 35% in Chicago, Saskatoon, and Phoenix for 14%, 13%, and 20% of the working hours of the year, respectively. It is also able to achieve a relative humidity of 60% in Chicago, and Miami 10% and 55% of the working hours of the year, respectively. The results also show the potential of the RCP system with the HAMP to reduce the total energy consumed by a conventional all-air system in the hot climates by 40%, and 54% in Miami and Phoenix respectively, and in the cold climates by 14% and 23% in Saskatoon and Chicago, respectively.

<div>Liquid desiccant air dehumidification (LDAD) is a promising substitute for the conventional dehumidification systems that use mechanical cooling. However, the LDAD system shares a little market because of its high installation cost, carryover problem, and severe corrosion problem caused by the conventional liquid desiccant. The research reported in this thesis aimed to address these challenges by applying membrane technology and ionic liquid desiccants (ILDs) in LDAD. The membrane technology uses semi-permeable materials to separate the air and liquid desiccants, therefore, the solution droplets cannot enter into the air stream to corrode the metal piping and degrade the air quality. The ILDs are synthesized salts in the liquid phase, with a large dehumidification capacity but no corrosion problems. In order to study the applicability and performance of these two technologies, both experimental and modeling investigations were made as follows.</div><div>In the study, experimental researches and existing models on the membrane-based LDAD (MLDAD) was extensively reviewed with respects of the characteristics of liquid desiccants and membranes, the module design, the performance assessment and comparison, as well as the modeling methods for MLDAD.</div><div>A small-scale prototype of the MLDAD was tested by using ILD in controlled conditions to characterize its performance in Oak Ridge National Lab. The preliminary experimental results indicated that the MLDAD was able to dehumidify the air and the ILD could be regenerated at 40 ºC temperature. However, the latent effectiveness is relatively lower compared with conventional LDAD systems, and the current design was prone to leakage, especially under the conditions of high air and solution flow rates.</div><div>To improve the dehumidification performance of our MLDAD prototype, the two-dimensional numerical heat and mass transfer models were developed for both porous and nonporous membranes based on the microstructure of the membrane material. The finite element method was used to solve the equations in MATLAB. The models for porous and nonporous membranes were validated by the experimental data available from literature and our performance test, respectively. The validated models were able to predict the performance of the MLDAD module and conduct parametric studies to identify the optimal material selection, design, and operation of the MLDAD.</div><div><br></div>

Liquid desiccant air conditioning (LDAC) has received much attention in recent years. This is mainly because LDAC systems are able to control latent loads in a more energy efficient way than conventional air conditioning systems. Although many research studies have been conducted on LDAC technologies, the following gaps in the scientific literature are addressed in this thesis: (1) carryover of desiccant droplets in air streams, (2) direct comparisons between different configurations of LDAC systems, (3) fundamentals of capacity matching in heat-pump LDAC systems, (4) optimal-control strategies for heat-pump LDAC systems, and (5) importance of transients in evaluating the performance of a LDAC system. Items (1) to (4) are addressed using TRNSYS simulations, and item (5) is addressed using data collected from a field test. The use of liquid-to-air membrane energy exchangers (LAMEEs) as dehumidifiers and regenerators in LDAC systems eliminate the desiccant droplets carryover problem in air streams. This is because LAMEE separate the air and solution streams using semi-permeable membranes, which allow the transfer of heat and moisture but do not allow the transfer of the liquid desiccant. A preliminary configuration for a membrane LDAC system, which uses LAMEEs as the dehumidifier and regenerator, is proposed and investigated under fixed operating conditions in this thesis. The influences of key design and operating parameters on the heat and mass transfer performances of the membrane LDAC system are evaluated. Results show that the membrane LDAC technology is able to effectively remove latent loads in applications that the humidity to be controlled. A comprehensive evaluation is conducted in this thesis for the thermal, economic and environmental performances of several configurations of membrane LDAC systems. The solution cooling load is covered using a cooling heat pump in all systems studied, while the solution heating load is covered using one of the following five different heating systems: (1) a gas boiler, (2) a heating heat pump, (3) a solar thermal system with gas boiler backup, (4) a solar thermal system with heat pump backup, and (5) the condenser of the solution cooling heating pump. Each of the membrane LDAC systems studied is evaluated with/without an energy recovery ventilator (ERV) installed in the air handling system. The influence of operating the ERV under balanced/unbalanced operating conditions is studied. It is found that the most economic membrane LDAC system is the one which uses the evaporator and condenser of the same heat pump to cover the solution cooling and heating loads, respectively (i.e. heat-pump membrane LDAC system). No clear guidance was found in the literature for sizing the evaporator and condenser in a heat-pump LDAC system to simultaneously meet the solution cooling and heating loads. When the heating and cooling provided by the heat pump exactly match the heating and cooling requirements of the solution, the system is “capacity matched”. A parametric study is conducted on a heat-pump membrane LDAC system to identify the influence of key operating and design parameters on achieving capacity matching. It is concluded that the solution inlet temperatures to the dehumidifier and regenerator are the most influential parameters on the moisture removal rate, capacity matching and coefficient of performance (COP). Three control strategies are developed for heat-pump membrane LDAC systems, where these strategies meet the latent loads and achieve one of the following three objectives: (1) meet the sensible loads, (2) achieve capacity matching, or (3) optimize the COP. Results show that the COP of a heat-pump LDAC system can be doubled by selecting the right combination of solution inlet temperatures to the regenerator and dehumidifier. The importance of transients in evaluating the performance of a LDAC system is addressed in the thesis using a data collected from a field test on a solar LDAC system. It is found that the sensible, latent and total cooling energy, and the total primary energy consumption of the LDAC system are changed by less than 10% during an entire test day when transients are considered. Thus, it can be concluded that steady-state models are reliable to evaluate the energy performances of LDAC systems.