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A study of the high turbulence plunging jet reactorSofolarin, Adeniyi Babatunde January 1990 (has links)
No description available.
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The effect of Prewetting on the Pressure Drop, Liquid Holdup and Gas-Liquid Mass Transfer in Trickle-Bed ReactorsLoudon, Dylan 02 May 2006 (has links)
The prewetting of a trickle-bed reactor has important implications in the design and operation of these reactors. This is because the prewetting changes the flow morphology (shape and texture) of the liquid flowing through the bed and leads to the existence of multiple hydrodynamic states. The extent of this change in flow morphology can be seen in the effect the prewetting of the reactor has on the pressure drop, liquid holdup and gas-liquid mass transfer. The following prewetting procedures were used: -- Levec-wetted: the bed is flooded and drained and after residual holdup stabilisation the gas and liquid flow is reintroduced -- Kan-wetted: the bed is operated in the pulse flow regime and liquid and gas flow rates are reduced to the desired set point -- Super-wetted: the bed is flooded and gas and liquid flow are introduced once draining commences For the pressure drop: -- The different prewetting procedures resulted in two distinct regions (Upper region Kan and Super-wetted, Lower region Dry and Levec-wetted) -- There was no significant difference between the Dry and Levec-wetted beds -- The pressure drop in the Kan and Super-wetted beds can be as much as seven times greater than the pressure drop in the Dry and Levec-wetted beds For the liquid holdup: -- The different prewetting procedures resulted in four distinct regions (Kan-wetted, Super-wetted, Levec-wetted, Dry bed) -- The liquid holdup in the Kan-wetted bed can be as much as four times greater than the liquid holdup in the Dry bed -- The liquid holdup in the Levec-wetted can be as much as thirty percent lower than the liquid holdup in the Kan-wetted bed For the gas-liquid mass transfer: -- The different prewetting procedures resulted in three distinct regions (Kan and Super-wetted, Levec-wetted, Dry bed) -- The volumetric gas-liquid mass transfer coefficient in the Kan and Super-wetted beds can be as much as six times greater than the mass transfer coefficient in the Dry bed -- The volumetric gas-liquid mass transfer coefficient in the Kan and Super-wetted beds can be as much as two and a half times greater than the mass transfer coefficient in the Levec-wetted bed While an increase in the liquid flow rate results in an increase in the pressure drop, liquid holdup and gas-liquid mass transfer for all of the experiments, the effect of increasing gas flow on the measured variables were more pronounced for the prewetted beds. In a prewetted bed (Kan, Super and Levec-wetted) an increase in the gas flow rate causes an increase in the volumetric gas-liquid mass transfer coefficient and a decrease in the liquid holdup. The decrease in the liquid holdup is due to the fact that the increased gas flow rate causes the films around the particles to thin and spread out. In the dry bed the flow is predominantly in the form of rivulets and the increase in gas flow rate does not affect the liquid holdup. In the case of the volumetric gas-liquid mass transfer coefficient the increased gas flow rate causes an increase in the mass transfer coefficient regardless of the prewetting procedure. This increase is due to the effect that the gas flow rate has on the liquid holdup as well as the increase in the gas-liquid interfacial area due to the increased gas-liquid interaction. If the pulsing in the Kan-wetted bed is induced by increasing the gas flow rate and keeping the liquid flow rate constant the results are significantly different. The pressure drop in the gas-pulsing experiments was lower than the pressure drop in the recorded in the Kan and Super-wetted beds, but higher than the pressure drop in the dry and Levec-wetted beds. However, the liquid holdup in the gas-pulsing experiments was higher than the liquid holdup in any of the other beds. The volumetric gas-liquid mass transfer coefficient in the gas-pulsing experiments was lower than the mass transfer coefficients of the Kan and Super-wetted beds, but higher than the mass transfer coefficients in the dry and Levec-wetted beds. The multiple operating points obtained from the different prewetting procedures are by no means the only possible operating points. By simply decreasing the draining time in the Levec-wetted bed steady state operating points can be found between those of the Super and Levec-wetted beds. This alludes to the fact that the operating conditions determined from the different prewetting modes are only boundaries and that the actual operating point can lie anywhere between these boundaries. The existence of these multiple hydrodynamic states complicates things further when a correlation is developed to determine the pressure drop, liquid holdup or the volumetric gas-liquid mass transfer coefficient. No correlation tested was able to accurately predict the pressure drop, liquid holdup or volumetric gas-liquid mass transfer coefficient in the dry or prewetted beds. / Dissertation (MEng (Chemical Engineering))--University of Pretoria, 2007. / Chemical Engineering / unrestricted
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Solid-liquid mass transfer in trickle bed reactorsJoubert, Rita 24 June 2009 (has links)
Hydrodynamic multiplicity in the trickle flow, or low interaction, regime is a well documented phenomenon. Multiple hydrodynamic states are often presented in the form of hysteresis loops where the hydrodynamic parameter studied are shown as a function of the operating history of the bed, i.e. liquid and gas flow rates. In extreme cases the lower leg, representing an increase in liquid flow rate on a pre-wetted and drained bed, is commonly referred to as the Levec mode. The upper extreme, referred to as the Kan-liquid mode, represents a decrease in liquid flow rate after operation in the high interaction regime. The many reported studies investigating liquid-solid mass transfer in trickle beds have generally used either the dissolution or electrochemical techniques. Numerous researchers have used their data to develop correlations predicting solid-liquid mass transfer coefficients. Most of these studies do not specify the multiplicity mode of operation. Only two studies (Sims et al. (1993) and Van der Merwe, Nicol&Al-Dahhan (2008)) use both the Levec and Kan-liquid operating modes. Both of these studies suggest that solid-liquid mass transfer also exhibit multiplicity behaviour although the trends suggested or speculated differ from each other. Sims et al. (1993) found that a Kan-liquid operated bed will outperform a Levec operated bed; however in contrast to this Van der Merwe et al. (2008) speculated that a Levec operated bed is better suited for liquid limited reactions due to enhanced liquid-solid mass transfer in the Levec mode as a result of faster interstitial velocity. This study showed that solid-liquid mass transfer coefficients, measured with both the dissolution and electrochemical technique, show multiplicity behaviour. Two distinct operating regions were found, which corresponds to the Levec and Kan-liquid modes. Measurements taken using the electrochemical technique yielded solid-liquid mass transfer coefficients larger than those measured using the dissolution method. The experimental results agree with the trend found by Sims et al. (1993) but the mass transfer coefficients in this study were significantly lower. Additionally it was shown that the difference in mass transfer coefficients, in the two modes, cannot be explained by merely compensating for the differences in wetting efficiency and interstitial velocity, suggesting that the Levec mode has a larger percentage of stagnant or poorly irrigated zones. It was also shown that mass transfer coefficients measured at the top of the column is higher than those measured at the bottom, suggesting that the flow structure is changing as a function of axial length. Lastly, with regards to electrochemical measurements of liquid-solid mass transfer, it was shown that measurements using a single particle electrode compared well to that of a multiple packing electrode. / Dissertation (MEng)--University of Pretoria, 2009. / Chemical Engineering / unrestricted
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Development of a Biomass-to-Methanol Process Integrating Solid State Anaerobic Digestion and Biological Conversion of Biogas to MethanolSheets, Johnathon P. 12 October 2017 (has links)
No description available.
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Carbon Capture Using The Microalgae Chlorella Vulgaris in a Packed Bubble Column PhotobioreactorZame, Kenneth Kofiga 05 November 2010 (has links)
No description available.
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Hidrodinamika i prenos mase u airlift reaktoru sa membranom / Hydrodynamics and mass transfer of an airlift reactor with inserted membraneKojić Predrag 20 May 2016 (has links)
<p>U okviru doktorske disertacije izvedena su eksperimentalna istraživanja osnovnih hidrodinamičkih i maseno-prenosnih karakteristika airlift reaktora sa spoljnom recirkulacijom sa ugrađenom višekanalnom cevnom membranom u silaznu cev (ALSRM). ALSRM je radio na dva načina rada: bez mehurova u silaznoj cevi (način rada A) i sa mehurovima u silaznoj cevi (način rada B) u zavisnosti od nivoa tečnosti u gasnom separatoru. Ispitivani su uticaji prividne brzine gasa, površinskih osobina tečne faze, tipa distributora gasa i prisustva mehurova gasa u silaznoj cevi na sadržaj gasa, brzinu tečnosti u silaznoj cevi i zapreminski koeficijent prenosa mase u tečnoj fazi u ALSRM. Rezultati su poređeni sa vrednostima dobijenim u istom reaktoru ali bez membrane (ALSR). Sadržaj gasa u uzlaznoj i silaznoj cevi određivan je pomoću piezometarskih cevi merenjem hidrostatičkog pritiska na dnu i vrhu uzlazne i silazne cevi. Brzina tečnosti merena je pomoću konduktometrijskih elektroda dok je zapreminski koeficijent prenosa mase dobijen primenom dinamičke metode merenjem promene koncentracije kiseonika u vremenu optičkom elektrodom. Eksperimentalni rezultati pokazuju da sadržaj gasa, brzina tečnosti i zapreminski koeficijent prenosa mase zavise od prividne brzine gasa, vrste alkohola i tipa distributora gasa kod oba reaktora. Višekanalna cevna membrana u silaznoj cevi uzrokovala je povećanje ukupnog koeficijenta trenja za 90% i time dovela do smanjenja brzine tečnosti u silaznoj cevi do 50%. Smanjena brzina tečnosti u silaznoj cevi povećala je sadržaj gasa do 16%. Predložene neuronske mreže i empirijske korelacije odlično predviđaju vrednosti za sadržaj gasa, brzinu tečnosti i zapreminski koeficijent prenosa mase.</p> / <p>An objective of this study was to investigate the hydrodynamics and the gas-liquid mass transfer coefficient of an external-loop airlift membrane reactor (ELAMR). The ELAMR was operated in two modes: without (mode A), and with bubbles in the downcomer (mode B), depending on the liquid level in the gas separator. The influence of superficial gas velocity, gas distributor’s geometry and various diluted alcohol solutions on hydrodynamics and gas-liquid mass transfer coefficient of the ELAMR was studied. Results are commented with respect to the external loop airlift reactor of the same geometry but without membrane in the downcomer (ELAR). The gas holdup values in the riser and the downcomer were obtained by measuring the pressures at the bottom and the top of the riser and downcomer using piezometric tubes. The liquid velocity in the downcomer was determined by the tracer response method by two conductivity probes in the downcomer. The volumetric mass transfer coefficient was obtained by using the dynamic oxygenation method by dissolved oxygen probe. According to experimental results gas holdup, liquid velocity and gas-liquid mass transfer coefficient depend on superficial gas velocity, type of alcohol solution and gas distributor for both reactors. Due to the presence of the multichannel membrane in the downcomer, the overall hydrodynamic resistance increased up to 90%, the liquid velocity in the downcomer decreased up to 50%, while the gas holdup in the riser of the ELAMR increased maximally by 16%. The values of the gas holdup, the liquid velocity and the gas-liquid mass transfer coefficient predicted by the application of empirical power law correlations and feed forward back propagation neural network (ANN) are in very good agreement with experimental values.</p>
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Flottation réactive à l'ozone de contaminants modèles issus de papiers récupérés : étude hydrodynamique et réactivité / Ozone reactive flotation of model contaminants contained in recovered papers : hydrodynamics and reactivity studyHerisson, Alexandre 25 June 2018 (has links)
La diminution de la qualité des collectes des papiers récupérés ainsi que l’accumulation de substances dissoutes dans les eaux de procédés affecte l’efficacité des lignes de désencrage industrielles et contamine davantage les effluents liquides. Dans ce contexte, le LGP2 a développé depuis quelques années un procédé innovant de désencrage, la flottation réactive à l’ozone, afin de dégrader chimiquement les polluants dissouts en parallèle de l’élimination de l’encre. Afin de mieux comprendre les mécanismes mis en jeu, des essais de flottation à l’air et à un mélange ozone/oxygène, sur trois contaminants modèles, sélectionnés après une étude bibliographique préalable, ont été réalisés dans un milieu diphasique gaz/liquide, en l’absence de fibres cellulosiques. Les expérimentations ont été conduites sur deux pilotes de laboratoire instrumentés : une colonne à bulles fonctionnant avec de l’air uniquement, pour l’étude du comportement hydrodynamique (taille et distribution de bulles, rétention gazeuse) en présence des contaminants dissouts, et une deuxième colonne à bulles, similaire mais conçue avec des matériaux résistants aux gaz corrosifs, dédiée à l’étude des réactions d’oxydation en présence d’ozone. L’examen du comportement hydrodynamique montre que les conditions de débit de gaz et d’injection retenues conduisent à des tailles de bulles optimales pour une flottation efficace, que ce soit en présence ou absence de contaminants. Ces conditions obtenues avec de l’air ont été transposées en première approximation au système ozone/oxygène. L’étude du transfert de l’ozone et de sa réactivité avec les trois contaminants modèles, à différentes températures et concentrations en ozone, a conduit à la détermination des constantes cinétiques de réaction et a montré que les contaminants étaient, selon leur nature, oxydés ou dépolymérisés. Bien que la DCO des solutions traitées diminue très peu après la flottation réactive à l’ozone, la qualité des effluents est améliorée sur le plan de leur biodégradabilité. / The decrease of the recovered paper collection quality and the accumulation of dissolved substances in process water affect the deinking line efficiency and contaminate more and more the liquid effluents. In this context the LGP2 has developed an innovative deinking process, the ozone reactive flotation, to chemically degrade dissolved pollutants in parallel with ink removal. To better understand the mechanisms involved, air and ozone/oxygen flotation trials have been conducted on three model contaminants selected in a preliminary bibliographic review, in a two-phase gas/liquid system, in the absence of fibers. Experiments have been carried out on two instrumented laboratory pilots: a bubble column operating only with air for the study of the hydrodynamics of the reactor (bubbles size and distribution, gas hold-up) in the presence of dissolved contaminants, and a second one, similar in its conception but built using materials resistant to corrosive gas, dedicated to the study of the oxidation reactions with ozone. The evaluation of the hydrodynamics related to gas flow and injection system selected, studied with air but supposed to be the same with ozone/oxygen gas mixture, shows that the bubble size, with or without contaminants, is optimal for an efficient flotation process. The study of ozone mass transfer and reactivity with the three model contaminants, for several temperatures and ozone concentrations, leads to the calculation of kinetic constants and shows that the contaminants, depending on their nature, have been oxidized or depolymerized. Although the COD of the treated solutions does not decrease a lot after the ozone reactive flotation, the effluent quality has been improved in terms of biodegradability since contaminants are partially degraded.
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Local investigations of gas-liquid mass transfer around Taylor bubbles flowing in straight and meandering millimetric channels using a colorimetric method / Etudes locales par colorimétrie du transfert de matière gaz-liquide autour de bulles de Taylor en écoulement dans des canaux millimétriques droits et ondulésYang, Lixia 24 March 2017 (has links)
Les réacteurs-échangeurs à plaques (HEX) sont une technologie clé en intensification des procédés. Cependant, la plupart des recherches existantes portant sur ce type d'équipement ont été réalisées dans le cas d’écoulements monophasiques. Pour les réactions gaz-liquide, peu d'études ont été conduites. Cette thèse a pour objectif d’étudier localement le transfert de matière gaz-liquide autour de bulles de Taylor en écoulement dans des canaux millimétriques droits et ondulés par une méthode dite colorimétrique. Ceci constitue une étape préliminaire indispensable avant la mise en œuvre de systèmes réactifs diphasiques. Il a d’abord déterminé si une possible accélération du transfert de matière gaz-liquide pouvait avoir lieu en présence de la réaction chimique utilisée. La deuxième phase de ce travail s’est focalisée sur l'étape de formation des bulles de Taylor dans un microréacteur. Ensuite, l'hydrodynamique gaz-liquide a été caractérisée et les effets des coudes sur le mécanisme de transfert de masse ont été étudiés localement dans un canal carré millimétrique ondulé. Enfin, une comparaison rigoureuse a pu être effectuée entre les différentes géométries de canaux (ondulé et droit). Elle a permis de montrer comment et pourquoi une géométrie ondulé permet d’intensifier le transfert de masse gaz-liquide (notamment en terme d’efficacité de transfert). L’ensemble de ces résultats ont conduit à la formulation une loi d'échelle, exprimée en termes de nombres de Sherwood, de Graetz et de Péclet, capable de décrire l'évolution du transfert de matière gaz-liquide en fonction de la position axiale dans le canal et des conditions opératoires mises en œuvre. / Compact Heat-EXchanger reactors (HEX) are an important part of process intensification technology. However, most of the existed research dealing with such type of equipment has been focused on the application of one-phase reactive flows. For gas-liquid reactions, few investigations have been out carried. This thesis aims at locally studying gas-liquid mass transfer around Taylor bubbles flowing in straight and meandering millimetric channels using a colorimetric method; this is a preliminary step essential before implementing two-phase reactive systems. Firstly, the occurrence of a possible enhancement of the gas-liquid mass transfer by the chemical reaction involved was investigated. Secondly, the gas-liquid mass transfer occurring in Taylor flows right after the bubble formation stage in a microreactor was studied. Thirdly, the gas-liquid hydrodynamics were characterized and the effects of bends on the mass transfer mechanism were locally investigated in a millimetric meandering channel. At last, a rigorous comparison could be made between the meandering and straight channels. It showed how and why the meandering geometry leads to intensify gas-liquid mass transfer. All these findings enabled to formulate a scaling law, expressed in terms of Sherwood, Graetz and Péclet numbers, able to describe the evolution of gas-liquid mass transfer as a function of axial position and operating conditions.
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Strömungsinstabilitäten bei Stoffübergang und chemischer Reaktion an der ebenen Grenzfläche zwischen zwei nicht mischbaren FlüssigkeitenGrahn, Alexander 31 March 2010 (has links) (PDF)
In verfahrenstechnischen Anlagen der Flüssig-Flüssig-Stoffübertragung kommt es an der Phasengrenze zwischen den nicht mischbaren Flüssigphasen häufig zur Ausbildung hydrodynamischer Instabilitäten. Sie sind mit komplexen Geschwindigkeitsfeldern in den Flüssigphasen, insbesondere in den grenzschichtnahen Regionen verbunden und führen zu einem starken Anstieg der pro Zeiteinheit übertragenen Stoffmenge. Die Lösung der Diffusionsgleichung reicht in diesem Fall zur Vorausberechnung des für Auslegungszwecke bedeutsamen Stoffdurchgangskoeffizienten nicht mehr aus. Chemische Reaktionen stellen Quellen oder Senken von Wärme und Stoff dar, die das Auftreten von Instabilitäten begünstigen und die mathematische Beschreibung zusätzlich erschweren. Im Rahmen der vorliegenden Arbeit wurden experimentelle und numerische Untersuchungen zum Flüssig-Flüssig-Stoffübergang in einem vertikalen Kapillarspalt durchgeführt. Reaktionsfreie Stoffübergänge und solche mit einer exothermen chemischen Reaktion an der Phasengrenze zeigten eine große Vielfalt von Konvektionsstrukturen, wie Rollzellen, Thermiken und das doppeldiffusive Fingerregime. Die Visualisierung der Transportvorgänge erfolgte durch das Schattenschlierenverfahren. Die Beobachtungen wurden hinsichtlich geometrischer Eigenschaften von Konvektionsstrukturen sowie deren zeitlicher Änderung ausgewertet. Dazu zählten insbesondere das Längenwachstum von Thermiken und horizontale Wellenlängen von Fingerstrukturen. Zur mathematischen Beschreibung der Phänomene im Kapillarspalt wurde ein Modell entwickelt, welches auf den gekoppelten, zweidimensionalen Transportgleichungen von Impuls, Wärme und Stoff beruht. Es berücksichtigt dichte- und grenzflächenspannungsgetriebene Instabilitätsmechanismen sowie die besonderen Durchströmungseigenschaften des Kapillarspalts. Die Phasengrenze wurde als eben angenommen. Die Lösung der Modellgleichungen erfolgt auf numerischem Wege durch ein Computerprogramm. Das Modell ist in der Lage, die beobachteten Instabilitätsphänomene qualitativ richtig wiederzugeben. Mit Hilfe von Simulationsrechnungen konnte der Mechanismus aufgeklärt werden, der zum schnelleren Rückgang des Stoffdurchgangskoeffizienten im Rollzellenregime der rein grenzflächenspannungsgetrieben Instabilität im Vergleich zum Vorgang mit überlagerter Dichtekonvektion führt. Des Weiteren gelang der Nachweis des doppeldiffusiven Fingerregimes beim Stoffübergang mit exothermer Grenzflächenreaktion. Die berechnete Erhöhung des Stoffdurchgangskoeffizienten stimmt mit Angaben in experimentellen Arbeiten anderer Autoren überein.
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Strömungsinstabilitäten bei Stoffübergang und chemischer Reaktion an der ebenen Grenzfläche zwischen zwei nicht mischbaren FlüssigkeitenGrahn, Alexander January 2005 (has links)
In verfahrenstechnischen Anlagen der Flüssig-Flüssig-Stoffübertragung kommt es an der Phasengrenze zwischen den nicht mischbaren Flüssigphasen häufig zur Ausbildung hydrodynamischer Instabilitäten. Sie sind mit komplexen Geschwindigkeitsfeldern in den Flüssigphasen, insbesondere in den grenzschichtnahen Regionen verbunden und führen zu einem starken Anstieg der pro Zeiteinheit übertragenen Stoffmenge. Die Lösung der Diffusionsgleichung reicht in diesem Fall zur Vorausberechnung des für Auslegungszwecke bedeutsamen Stoffdurchgangskoeffizienten nicht mehr aus. Chemische Reaktionen stellen Quellen oder Senken von Wärme und Stoff dar, die das Auftreten von Instabilitäten begünstigen und die mathematische Beschreibung zusätzlich erschweren. Im Rahmen der vorliegenden Arbeit wurden experimentelle und numerische Untersuchungen zum Flüssig-Flüssig-Stoffübergang in einem vertikalen Kapillarspalt durchgeführt. Reaktionsfreie Stoffübergänge und solche mit einer exothermen chemischen Reaktion an der Phasengrenze zeigten eine große Vielfalt von Konvektionsstrukturen, wie Rollzellen, Thermiken und das doppeldiffusive Fingerregime. Die Visualisierung der Transportvorgänge erfolgte durch das Schattenschlierenverfahren. Die Beobachtungen wurden hinsichtlich geometrischer Eigenschaften von Konvektionsstrukturen sowie deren zeitlicher Änderung ausgewertet. Dazu zählten insbesondere das Längenwachstum von Thermiken und horizontale Wellenlängen von Fingerstrukturen. Zur mathematischen Beschreibung der Phänomene im Kapillarspalt wurde ein Modell entwickelt, welches auf den gekoppelten, zweidimensionalen Transportgleichungen von Impuls, Wärme und Stoff beruht. Es berücksichtigt dichte- und grenzflächenspannungsgetriebene Instabilitätsmechanismen sowie die besonderen Durchströmungseigenschaften des Kapillarspalts. Die Phasengrenze wurde als eben angenommen. Die Lösung der Modellgleichungen erfolgt auf numerischem Wege durch ein Computerprogramm. Das Modell ist in der Lage, die beobachteten Instabilitätsphänomene qualitativ richtig wiederzugeben. Mit Hilfe von Simulationsrechnungen konnte der Mechanismus aufgeklärt werden, der zum schnelleren Rückgang des Stoffdurchgangskoeffizienten im Rollzellenregime der rein grenzflächenspannungsgetrieben Instabilität im Vergleich zum Vorgang mit überlagerter Dichtekonvektion führt. Des Weiteren gelang der Nachweis des doppeldiffusiven Fingerregimes beim Stoffübergang mit exothermer Grenzflächenreaktion. Die berechnete Erhöhung des Stoffdurchgangskoeffizienten stimmt mit Angaben in experimentellen Arbeiten anderer Autoren überein.
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