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noneLiu, Yi-Ming 01 August 2000 (has links)
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Molecular Dynamics Simulation of Polyethylene Oxide Containing Li6-(V10O28) SaltTang, Ming-Shiuan 25 August 2008 (has links)
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Nanostructuring silicon and germanium for high capacity anodes in lithium ion batteriesHarris, Justin Thomas 30 January 2013 (has links)
Colloidally synthesized silicon (Si) and germanium (Ge) were explored as high capacity anode materials in lithium ion batteries. a-Si:H particles were synthesized through the thermal decomposition of trisilane in supercritical n-hexane. Precise control over particle size and hydrogen content was demonstrated. Particles ranged in size from 240-1500 nm with hydrogen contents from 10-60 atomic%. Particles with low hydrogen content had some degree of local ordering and were easily crystallized during Raman spectroscopy. The as-synthesized particles did not perform well as an anode material due to low conductivity. Increasing surface conductivity led to enhanced lithiation potential.
Cu nanoparticles were deposited on the surface of the a-Si:H particles through a hydrogen facilitated reduction of Cu salts. The resulting Cu coated particles had a lithiation capacity seven times that of pristine a-Si:H particles. Monophenylsilane (MPS) grown Si nanowire paper was annealed under forming gas to reduce a polyphenylsilane shell into conductive carbon. The resulting paper required no binder or carbon additive and achieved capacities of 804 mA h/g vs 8 mA h/g for unannealed wires.
Si and Ge heterostructures were explored to take advantage of the higher inherent conductivity of Ge. Ge nanowires were successfully coated with a-Si by thermal decomposition of trisilane on their surface, forming Ge@a-Si core shell structures. The capacity increased with increasing Si loading. The peak lithiation capacity was 1850 mA h/g after 20 cycles – higher than the theoretical capacity of pure Ge. MPS additives created a thin amorphous shell on the wire surfaces. By incubating the wires after MPS addition the shell was partially reduced, conductivity increased, and a 75% increase in lithiation capacity was observed for the nanowire paper.
The syntheses of Bi and Au nanoparticles were also explored. Highly monodisperse Bi nanocrystals were produced with size control from 6-18 nm. The Bi was utilized as seeds for the SLS synthesis of Ge nanorods and copper indium diselenide (CuInSe2) nanowires. Sub 2 nm Au nanocrystals were synthesized. A SQUID magnetometer probed their magnetic behavior. Though bulk Au is diamagnetic, the Au particles were paramagnetic. Magnetic susceptibility increased with decreasing particle diameter. / text
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Structural and electrochemical characterization of high-energy oxide cathodes for lithium ion batteriesLee, Eun Sung 25 February 2013 (has links)
Lithium-ion batteries are the most promising rechargeable battery system for both vehicle applications and stationary storage of electricity produced from renewable sources such as solar and wind energies. However, the current lithium ion technology does not fully meet the requirements of these applications in terms of energy and power density. One approach to realizing a combination of high energy and power density is to use a composite cathode that consists of the high-capacity lithium-rich layered oxide Li[Li,Mn,Ni,Co]O2 and the high-voltage spinel oxide LiMn1.5Ni0.5O4. This dissertation explores the unique structural characteristics and their effect on the electrochemical performance of the layered-spinel composite oxide cathodes along with individual layered and spinel oxides over a wide voltage range (5.0 – 2.0 V).
Initially, the effect of cation ordering on the electrochemical and structural characteristics of LiMn1.5Ni0.5O4 during cycling between 5.0 and 2.0 V were investigated by an analysis of the X-ray diffraction (XRD) and electrochemical data. Structural studies revealed that the cation ordering affects the size of the empty-octahedral sites in the spinel lattice. The differences in the size of the empty-octahedral sites affect the discharge profile below 3 V due to the variation in lattice distortion during lithium ion insertion into 16c octahedral sites. With the doped LiMn1.5Ni0.5-xMxO4 (M = Cr, Fe, Co, and Ga) spinels, different dopant ions have different effects on the degree of cation ordering due to the differences in ionic radii and surface-segregation characteristics.
The compositional and wt.% variations of the layered and spinel phases from the nominal values in the layered-spinel composites were obtained by employing a joint XRD and neutron diffraction (ND) Rietveld refinement method. With the obtained composition and ex-situ XRD data, the mechanism for the increase in capacity and the facile phase transformation of the layered phase in the composite cathodes to a 3 V spinel-like phase during cycling was proposed. Investigations focused on synthesis temperature revealed that the electrochemical characteristics of the composites are highly affected by the synthesis temperature due to the change in the surface area of the sample and cation ordering of the spinel phase.
In addition, the electrochemical performance of the lithium-rich layered oxide Li[Li,Mn,Ni,Co]O2 could be improved by blending it with a lithium-free insertion host VO2(B) and by controlling the amount of lithium ions extracted from the layered lattice during the first charge process. / text
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Understanding the electrochemical properties and safety characteristics of spinel cathodes for lithium-ion batteriesChemelewski, Katharine Rose 23 October 2013 (has links)
Manganese spinel cathodes LiMn₂O₄ offer the advantage of a strong, edge-shared octahedral framework with fast, 3-dimensional Li⁺-ion conduction. To better understand the safety of these materials, the thermal stability characteristics of spinel oxide and oxyfluoride cathodes Li[subscript 1.1]Mn[subscript 1.9-y]M[subscript y]O₄[subscript-z]F[subscript z] (M = Ni and Al, 0 ≤ y ≤ 0.3, and 0 ≤ z ≤ 0.2) have been investigated systematically. The thermal characteristics are assessed in terms of the onset temperature and reaction enthalpy for the exothermic reaction. The thermal stability increases with decreasing lithium content in the cathode in the charged state. High-voltage spinel cathodes LiMn[subscript 1.5]Ni[subscript 0.5]O₄ are promising candidates for electric vehicles and stationary storage of electricity produced by renewable energies due to their high power capability. However, widespread adoption of this high-voltage spinel cathode is hampered by severe capacity fade resulting from aggressive reaction with the electrolyte to form a thick solid-electrolyte interphase (SEI) layer. The synthesis conditions of the co-precipitation method are found to influence the microstructure and morphology through nucleation and growth of crystals in solution. Two samples prepared by similar wet-chemical routes have been characterized by microscopy and electrochemical methods to determine the role of microstructure and morphology on the electrochemical performance. It is found that the surface crystal planes play a key role in the capacity retention and rate performance. In order to achieve consistent electrochemical properties essential for the commercialization of the high-voltage spinel cathode LiMn[subscript1.5]Ni[subscript 0.5]O₄, the relationship between cation ordering, presence of impurity phase, and particle morphology must be elucidated. Accordingly, comparison of the stoichiometric LiMn[subscript1.5]Ni[subscript 0.5]O₄ cathodes with a Mn/Ni ratio of 3.0 prepared by different methods having varying morphologies and degrees of cation ordering is presented. It is found that although an increase in the degree of cation ordering decreases the rate capability, the crystallographic planes in contact with the electrolyte have a dominant effect on the electrochemical properties. To examine the effect of cation substitution on morphology, an investigation of the nucleation and growth of doped co-precipitated mixed-metal hydroxide precursor particles and the resulting stabilization of preferred crystallographic surface planes in the final spinel samples are presented. It is found that doping with certain cations stabilizes the growth of low-energy (111) surface planes, facilitating a long cycle life and fast high-rate performance. With an aim to develop a better understanding of the factors influencing the electrochemical properties, a systematic investigation of LiMn[subscript 1.5]Ni[subscript0.5-x]M[subscript x]O₄ (M = Cu and Zn and x = 0.08 and 0.16), in which Ni²⁺ ions are substituted by divalent Cu2+ and Zn2+ ions, is presented. It is found that although both Zn and Cu are divalent with ionic radii similar to that of Ni2+, they behave quite differently with respect to cation ordering and site occupancy, and higher levels of doping leads to distinct differences in cycling and rate performances. / text
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Magnetic, electronic, and electrochemical properties of high-voltage spinel cathodes for lithium-ion batteriesMoorhead-Rosenberg, Zachary 15 September 2015 (has links)
Lithium-ion technology has revolutionized the electronics and electric vehicle industry in the past two decades. First commercialized by Sony in 1991, the lithium-ion battery is composed of three main components: (i) the cathode, (ii) the anode, and (iii) the electrolyte. Graphitic carbon remains the most widely used anode material due to its low voltage vs. the Li/Li+ redox couple and high specific capacity. However, there are several popular cathode materials, including layered oxides, spinel oxides, and polyanion materials.
In an effort to increase the energy density of lithium-ion batteries, much focus is given to improving the gravimetric charge capacity and the overall cell voltage. The latter must be accomplished by employing high-voltage cathodes, the most promising of which is the lithium manganese nickel oxide spinel with a specific capacity of 146 mAh/g and a redox voltage of 4.7 V vs. Li/Li+. However, there are still several problems with this material that must be understood and overcome in order to develop high-voltage spinel as a viable commercial cathode.
Physical property measurements can reveal the underlying electronic and atomic interactions in the solid in order to better understand high-voltage spinel and its odd behavior. Novel magnetic techniques have been developed, which reliably indicate the degree of Mn-Ni ordering and quantitative determination of the concentration of the Mn3+ ion. Measurements of several physical properties as a function of lithium content were also undertaken to determine the effects of Mn-Ni ordering on the electronic conductivity and the importance of electron-ion interactions.
In addition to understanding the physical properties of high voltage spinel, the understanding of the solid state chemistry and unique structure was utilized to realize a new full cell construction technique. The spinel structure offers a unique way to deal with first cycle irreversible capacity loss in full cells stemming from solid-electrolyte interphase (SEI) layer growth on the anode surface. To that end, a novel microwave-assisted chemical lithiation process was developed using non-toxic and air-stable chemicals. New composite anode chemistry was combined with a pre-lithiated spinel cathode to demonstrate the feasibility of this approach to realizing practical next-generation Li-ion cells. / text
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Novel synthesis of nanostructured electrode materials for lithium-ion batteriesTheivanayagam, Murali Ganth 06 December 2010 (has links)
Lithium-ion batteries have revolutionized the portable electronics market, and they are currently pursued intensively for vehicle applications and storage of renewable energies (solar and wind energy). Cost, safety, cycle life, and energy and power densities are the critical parameters for these applications. With this perspective, there has been immense interest to develop new cathode and anode materials as well as to develop novel synthesis and processing approaches. This dissertation explores the use of novel synthesis approaches to obtain high-performance, nanostructured phosphate and silicate cathodes and iron oxide nanowire anodes and investigates their structure-property relationships. First, a novel microwave-solvothermal (MW-ST) approach has been developed to synthesize phase-pure, highly crystalline LiFePO₄ nanorods within 5-15 minutes at low temperatures of < 300 °C, without requiring reducing gas atmospheres. The LiFePO₄ nanorods, after forming a nanocomposite with conducting polymer or multi-walled carbon nanotubes or coating with conductive carbon, offer excellent cycle life and rate performance when implemented as cathodes in lithium-ion cells. In addition, other LiMPO₄ (M = Mn, Co, and Ni) olivine nanorods have also been synthesized by the MW-ST approach and characterized. The MW-ST process has then been extended to prepare a new class of carbon-coated, nanostructured silicates of the formula Li₂MSiO₄ (M = Fe and Mn). These materials have two times higher theoretical capacities (~ 330 mAh/g) than olivine phosphates (~ 170 mAh/g). Li₂FeSiO₄ exhibits practical discharge capacities of 148 mAh/g at room temperature and 203 mAh/g at 55 °C, with good rate capability and stable cycle life. Li₂MnSiO₄, on the other hand, shows higher discharge capacities of 210 mAh/g at room temperature and 250 mAh/g at 55 °C, but it exhibits poor rate performance and rapid capacity fade during cycling. In addition, carbon-coated olivine solid solution nano-particles of the formula LiM[subscript 1-y]M[subscript y]PO₄ (M = Fe, Mn, Co, and Mg), synthesized by a facile, high-energy mechanical milling process (HMME), have also been investigated. The electrochemical data reveal a systematic shift in the redox potential (open-circuit voltage) of the M²⁺/³⁺ couples in the LiM[subscript 1-y]M[subscript y]PO₄ solid solutions compared to those of the pristine LiMPO₄. The shifts in the redox potentials have been explained by the changes in the M-O covalence (inductive effect), which are caused by changes in the electronegativity of M or the M-O bond length or M-O-M interactions. Finally, a two-step microwave-hydrothermal process has been developed to synthesize carbon-decorated, single-crystalline Fe₃O₄ nanowires. The resulting iron oxide nanowires exhibit capacity values > 800 mAh/g with stable cycle life and high rate performance as an anode in lithium-ion cells. / text
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Improving Precision and Accuracy in Coulombic Efficiency Measurements of Lithium Ion BatteriesBond, Toby Mishkin 02 October 2012 (has links)
Lithium-ion batteries have been used extensively over the past two decades in the
portable consumer electronics industry. More recently, Li-ion batteries have become
candidates for much larger-scale applications such as electric vehicles and energy grid
storage, which impose much more stringent requirements on batteries, especially in terms
of cell lifetime. In order to develop batteries with improved lifetimes, a means of quickly
and accurately evaluating battery life is required. The use of coulombic efficiency (CE)
is an important tool in this regard, which provides a way to quantify parasitic reactions
occurring within the cell. As more stable battery chemistries are developed, the rates of
parasitic reactions occurring in the cell become reduced, and differences in CE among
cells become increasingly smaller. In order to resolve these differences, charger systems
must be developed which can measure CE with increased precision and accuracy.
This thesis investigates various ways to improve the precision and accuracy of CE
measurements. Using the high-precision charger (HPC) at Dalhousie University (built in
2009) as a starting point, a new prototype charger was built with several modifications to
the design of the existing HPC. The effect of each of these modifications is investigated
in detail to provide a blueprint for the development of next-generation charger systems.
This prototype charger shows greatly improved precision and accuracy, with CE results
that are approximately four times more precise than those of the existing HPC and over
an order of magnitude more precise than high-end commercially available charger
systems
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Lithium-Ion Battery Modeling for Electric Vehicles and Regenerative Cell Testing PlatformMoshirvaziri, Andishe 05 December 2013 (has links)
Electric Vehicles (EVs) have gained acceptance as low or zero emission means of transportation. This thesis deals with the design of a battery cell testing platform and Lithium-Ion (Li-Ion) battery modeling for EVs. A novel regenerative cell testing platform is developed for cell cycling applications. A 300 W - 5 V cell cycler consisting of a buck and a boost converter is designed.
Furthermore, a novel battery modeling approach is proposed to accurately predict the battery performance by dynamically updating the model parameters based on the battery temperature and State of Charge (SOC). The comparison between the experimental and the model simulation results of an automotive cell under real-world drive-cycle illustrates 96.5% accuracy of the model. In addition, the model can be utilized to assess the long-term impact of battery impedance on performance of EVs under real-world drive-cycles.
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Lithium-Ion Battery Modeling for Electric Vehicles and Regenerative Cell Testing PlatformMoshirvaziri, Andishe 05 December 2013 (has links)
Electric Vehicles (EVs) have gained acceptance as low or zero emission means of transportation. This thesis deals with the design of a battery cell testing platform and Lithium-Ion (Li-Ion) battery modeling for EVs. A novel regenerative cell testing platform is developed for cell cycling applications. A 300 W - 5 V cell cycler consisting of a buck and a boost converter is designed.
Furthermore, a novel battery modeling approach is proposed to accurately predict the battery performance by dynamically updating the model parameters based on the battery temperature and State of Charge (SOC). The comparison between the experimental and the model simulation results of an automotive cell under real-world drive-cycle illustrates 96.5% accuracy of the model. In addition, the model can be utilized to assess the long-term impact of battery impedance on performance of EVs under real-world drive-cycles.
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