Interpreting soil wetness in upland transported soils on flat broad summits in the central Piedmont of Virginia containing chroma ≥ 3 redoximorphic features (RMFs) can be difficult. It is imperative to understand their saturation regimes because onsite wastewater disposal systems, which are sited based upon soil evaluations, have failed prematurely when installed into these problematic soils. My objectives were to determine if soil morphology was an accurate predictor of soil wetness and permeability, to differentiate interpretations for colluvial soils from residual soils, and to determine the effect of canopy cover on seasonal wetness. Soil morphology, soil wetness regimes in open and wooded canopies, and in-situ saturated hydraulic conductivity were documented in transported Appomattox, Bentley, Brockroad, Catharpin, and Dothan and residual Clifford, Minnieville, and Penhook soil series at eight sites. Transported soils had average winter water levels, and met 30-day and 20-day NRCS oxyaquic criteria at 81, 66, and 91 cm, respectively. Transported soils with depleted ped faces, Fe- concentrations, and chroma 3 depletions were saturated an average of 41, 23, and 41% of the winter, respectively. Residuum found ≥ 1.5 m beneath transported soils exhibited little saturation, thus confirming epiaquic conditions. Residual soils did not perch water for extended periods; and were saturated for significantly (p<0.001) shorter durations and shallower depths (average 93 and 82 cm for 30-day and 20-day oxyaquic criteria, respectively). Transported soils under clear cuts had significantly (p<0.001) shallower average water levels (79 cm) and 30-day and 20-day oxyaquic conditions (51 and 88 cm, respectively) than wooded locations (87 and 83 cm average water levels and 30-day oxyaquic water table, respectively). In-situ hydraulic testing confirmed the presence of low permeability layers as determined by soil evaluation. Restrictive layers were thicker and less permeable in transported soils than in residual soils. In summary, water perches seasonally for extended periods over thick impermeable layers in transported soils. A recommended best management practice for problematic transported soils would be to not install septic systems in zones of saturation and low permeability, including the 1.5 m below a discontinuity. Drainfield designs should utilize permeable saprolite beneath transported material and an upslope curtain drain. / Ph. D.

Grain assemblages in organic-rich mudrocks of the Eagle Ford Formation of South Texas are assessed to determine the relative contributions of intra- and extrabasinal sediment sources, with the ultimate goal of producing data of relevance to prediction of diagenetic pathways. Integrated light microscopy, BSE imaging, and X-ray mapping reveal a mixed grain assemblage of calcareous allochems, biosiliceous grains (radiolaria), quartz, feldspar, lithics, and clay minerals. Dominant fossils are pelagic and benthic foraminifers and thin-walled and prismatic mollusks; echinoderms, calcispheres, and oysters are present. Early-formed authigenic minerals, including calcite, kaolinite, dolomite, albite, pyrite, quartz, and Ca-phosphate, some reworked, add to the overall lithologic heterogeneity. Point counting of images produced using energy-dispersive X-ray mapping in the SEM provides observations at a scale appropriate to classifying the mudrocks based on the composition of the grain assemblage, although grains and other crystals of clay-size cannot be fully characterized even with the SEM. Each sample is plotted on a triangle, whose vertices correspond to terrigenous and volcanic grains (extrabasinal components), calcareous allochems, and biosiliceous grains. As a subequal mix of grains of intrabasinal and extrabasinal origins the detrital grain assemblage of the Eagle Ford, presents a formidable challenge to the task of lithologic classification of this unit, as neither conventional limestone nor sandstone classifications can be readily applied. The abundant marine skeletal debris in the Eagle Ford is accompanied by abundant calcite cementation and the dissolution and replacement of biosiliceous debris is accompanied by authigenic quartz, suggesting that mudrock grain classification has potential for yielding diagenetic predictions. / text

In conventional remote sensing, visible-near infrared (VNIR) and shortwave infrared (SWIR) part of the electromagnetic spectrum (EMS) have been utilized for lithological discrimination extensively. Additionally, TIR part of the EM spectrum can also be utilized for discrimination of surface materials either through emissivity characteristics of materials or through radiance as in VNIR and SWIR. In this study, ASTER thermal multispectral infrared data is evaluated in regard to lithological discrimination and mapping through emissivity values rather than conventional methods that utilize radiance values. In order to reach this goal, Principle Component Analysis (PCA) and Decorrelation Stretch techniques are utilized for ASTER VNIR and SWIR data. Furthermore, the spectral indices which directly utilize the radiance values in VNIR, SWIR and TIR are also included in the image analysis. The emissivity values are obtained through Temperature-Emissivity Separation (TES) algorithm. The results of the image analyses, except spectral indices, are displayed in RGB color composite along with the geological map for visual interpretation. The results showed that utilizing emissivity values possesses potential for discrimination of organic matter bearing surface mixtures which has not been possible through the conventional methods. Additionally, PCA of emissivity values may increase the level of discrimination even further. Since the emissivity utilization is rather unused throughout in literature and new, further assessment of accuracy is highly recommended along with the field validations.

<p>In 2009, the Regional Municipality of Halton and McMaster University initiated a 2-year collaborative study (Georgetown Aquifer Characterization Study-GACS) of the groundwater resource potential of Quaternary sediments near Georgetown, Ontario. As part of that study, this thesis investigated the Quaternary infill stratigraphy of the Middle Sixteen Mile Creek (MSMC) and Cedarvale (CV) buried valley systems using newly acquired core and borehole geophysical data. Multi-parameter geophysical log suites (natural gamma, EM conductivity, resistivity, magnetic susceptibility, full-waveform sonic, caliper) were acquired in 16 new boreholes (16 m to 55 m depth), pre-existing monitoring wells and from archival data. Characteristic log responses (electrofacies) were identified and correlated with core to produce a detailed subsurface model of a 20-km² area to the southwest of Georgetown. Nine distinctive lithostratgraphic units were identified and their geometry mapped across the study area as structure contour and isochore thickness maps. The subsurface model shows that the CV valley truncates the Late Wisconsin MSMC stratigraphy along a channelized erosional unconformity and is a younger (post-glacial?) sediment-hosted valley system. Model results demonstrate the high level of stratigraphic heterogeneity and complexity that is inherent in bedrock valley systems and provides a geological framework for understanding groundwater resource availability.</p> <p>Principal component analysis (PCA) was applied to selected log suites to evaluate the potential for objective lithologic classification using log data. Gamma, resistivity and conductivity logs were most useful for lithologic typing, while p-wave velocity and resistivity logs were more diagnostic of compact diamict units. Cross plots of the first and second principal components of log parameters discriminated silts and clays/shales from sand/gravel and diamict lithofacies. The results show that PCA is a viable method for predicting subsurface lithology in un-cored boreholes and can assist in the identification of hydrostratigraphic units.</p> / Master of Science (MSc)

The depth of the sulfate-methane transition (SMT) above gas hydrate systems is a direct proxy to interpret upward methane flux and hydrate saturation. However, two competing reaction pathways can potentially form the SMT. Moreover, the pore water profiles across the SMT in shallow sediment show broad variability leading to different interpretations for how carbon, including CH4, cycles within gas-charged sediment sequences over time. The amount and distribution of marine gas hydrate impacts the chemistry of several other dissolved pore water species such as the dissolved inorganic carbon (DIC). A one-dimensional (1-D) numerical model is developed to account for downhole changes in pore water constituents, and transient and steady-state profiles are generated for three distinct hydrate settings. The model explains how an upward flux of CH4 consumes most SO42- at a shallow SMT implying that anaerobic oxidation of methane (AOM) is the dominant SO42- reduction pathway, and how a large flux of 13C-enriched DIC enters the SMT from depth impacting chemical changes across the SMT. Crucially, neither the concentration nor the d13C of DIC can be used to interpret the chemical reaction causing the SMT. The overall thesis objective is to develop generalized models building on this 1-D framework to understand the primary controls on gas hydrate occurrence. Existing 1-D models can provide first-order insights on hydrate occurrence, but do not capture the complexity and heterogeneity observed in natural gas hydrate systems. In this study, a two-dimensional (2-D) model is developed to simulate multiphase flow through porous media to account for heterogeneous lithologic structures (e.g., fractures, sand layers) and to show how focused fluid flow within these structures governs local hydrate accumulation. These simulations emphasize the importance of local, vertical, fluid flux on local hydrate accumulation and distribution. Through analysis of the fluid fluxes in 2-D systems, it is shown that a local Peclet number characterizes the local hydrate and free gas saturations, just as the Peclet number characterizes hydrate saturations in 1-D, homogeneous systems. Effects of salinity on phase equilibrium and co-existence of hydrate and gas phases can also be investigated using these models. Finally, infinite slope stability analysis assesses the model to identify for potential subsea slope failure and associated risks due to hydrate formation and free gas accumulation. These generalized models can be adapted to specific field examples to evaluate the amount and distribution of hydrate and free gas and to identify conditions favorable for economic gas production.