<p>Disturbances introduced in wall-bounded flows can grow and lead to transition from laminar to turbulent flow. In order to reduce losses or enhance mixing in energy systems, a fundamental understanding of the flow stability and transition mechanism is important. In the present thesis, the stability, transition mechanism and early turbulent evolution of wall-bounded flows are studied. The stability is investigated by means of linear stability equations and the transition mechanism and turbulence are studied using direct numerical simulations. Three base flows are considered, the Falkner-Skan boundary layer, boundary layers subjected to wall suction and the Blasius wall jet. The stability with respect to the exponential growth of waves and the algebraic growth of optimal streaks is studied for the Falkner-Skan boundary layer. For the algebraic growth, the optimal initial location, where the optimal disturbance is introduced in the boundary layer, is found to move downstream with decreased pressure gradient. A unified transition prediction method incorporating the influences of pressure gradient and free-stream turbulence is suggested. The algebraic growth of streaks in boundary layers subjected to wall suction is calculated. It is found that the spatial analysis gives larger optimal growth than temporal theory. Furthermore, it is found that the optimal growth is larger if the suction begins a distance downstream of the leading edge. Thresholds for transition of periodic and localized disturbances as well as the spreading of turbulent spots in the asymptotic suction boundary layer are investigated for Reynolds number Re=500, 800 and 1200 based on the displacement thickness and the free-stream velocity. It is found that the threshold amplitude scales like Re^-1.05 for transition initiated by streamwise vortices and random noise, like Re^-1.3 for oblique transition and like Re^-1.5 for the localized disturbance. The turbulent spot is found to take a bullet-shaped form that becomes more distinct and increases its spreading rate for higher Reynolds number. The Blasius wall jet is matched to the measured flow in an experimental wall-jet facility. Both the linear and nonlinear regime of introduced waves and streaks are investigated and compared to measurements. It is demonstrated that the streaks play an important role in the breakdown process where they suppress pairing and enhance breakdown to turbulence. Furthermore, statistics from the early turbulent regime are analyzed and reveal a reasonable self-similar behavior, which is most pronounced with inner scaling in the near-wall region.</p>

Raman spectroscopy is a promising technique because it contains abundant vibrational chemical information. However, Raman spectroscopy is restricted by its small scattering cross section, and many techniques have been developed to amplify Raman scattering intensity. In this dissertation, I study two of these techniques, coherent Raman scattering and surface enhanced Raman scattering and discuss their properties. In the first part of my dissertation, I investigate two coherent Raman processes, coherent anti-Stokes Raman scattering (CARS) and stimulated Raman scattering (SRS). In CARS project, I mainly focus on the molecular resonance effect on detection sensitivity, and I find the detection sensitivity can be pushed into 10 [micromolar] with the assistance of molecular resonance. Also, I am able to retrieve background-free Raman spectra from nonresonant signals. For SRS, we develop a new SRS system by applying spectral focusing mechanism technique. We examine the feasibility and sensitivity of our SRS system. The SRS spectra of standards obtained from our system is consistent with literature, and the sensitivity of our system can achieve 10 times above shot-noise limit. In second part of this dissertation, I study surface enhanced Raman scattering (SERS) and related plasmonic effects. I synthesize different shapes of nanoparticles, including nanorod, nanodimer structure with gap and pyramids by template method, and study how electric field enhancement effects correlate to SERS by two photon luminescence (TPL). Also, I build an optical system to study optical image, spectra and particle morphology together. I find that SERS intensity distribution is inhomogeneous and closely related to nanoparticle shape and polarization direction. However, TPL and SERS are not completely correlated, and I believe different relaxation pathways of TPL and SERS and coupling of LSPR and local fields at different frequencies cause unclear correlation between them. / text

L‐glutamate is associated with several neurological disorders; thus, monitoring fast dynamics of L‐glutamate is of great importance in the field of neuroscience. Electrode miniaturization demanded by many applications leads to reduced surface area and decreased amounts of immobilized enzymes on coated electrodes. As a result, lower signal‐to‐noise ratios are observed for oxidase‐enzyme based sensors. To increase the signal‐to‐noise ratio we have developed a process to fabricate micro‐ and nano‐ structures on the microelectrode surface. Localized surface‐plasmon resonances (SPR) has been extensively used to design label‐free biosensors that can monitor receptor‐ligand interactions. A major challenge with localized SPR sensors is that they remain highly susceptible to interference because they respond to both solution refractive index changes and surface binding of the target analyte. The key concept introduced in the present work is the exploitation of transverse and longitudinal resonance modes of nanorod arrays to differentiate between bulk refractive index changes and surface interactions. The transverse bulk sensitivity of the localized SPR sensor (107 nm/RIU) remains competitive with typical single mode gold nanosphere SPR sensors. The figure of merit for the device’s cross‐sensitivity (1.99) is comparable to that of typical wavelength‐interrogated propagating SPR sensors with self referencing.

No description available.

In this work, several beam finite element formulations are proposed for failure analysis of planar reinforced concrete beams and frames under monotonic static loading. The localized failure of material is modeled by the embedded strong discontinuity concept, which enhances standard interpolation of displacement (or rotation) with a discontinuous function, associated with an additional kinematic parameter representing jump in displacement (or rotation). The new parameters are local and are condensed on the element level. One stress resultant and two multi-layer beam finite elements are derived. The stress resultant Euler-Bernoulli beam element has embedded discontinuity in rotation. Bending response of the bulk of the element is described by elasto-plastic stress resultant material model. The cohesive relation between the moment and the rotational jump at the softening hinge is described by rigid-plastic model. Axial response is elastic. In the multi-layer beam finite elements, each layer is treated as a bar, made of either concrete or steel. Regular axial strain in a layer is computed according to Euler-Bernoulli or Timoshenko beam theory. Additional axial strain is produced by embedded discontinuity in axial displacement, introduced individually in each layer. Behavior of concrete bars is described by elastodamage model, while elasto-plasticity model is used for steel bars. The cohesive relation between the stress at the discontinuity and the axial displacement jump is described by rigid-damage softening model in concrete bars and by rigid-plastic softening model in steel bars. Shear response in the Timoshenko element is elastic. Finally, the multi-layer Timoshenko beam finite element is upgraded by including viscosity in the softening model. Computer code implementation is presented in detail for the derived elements. An operator split computational procedure is presented for each formulation. The expressions, required for the local computation of inelastic internal variables and for the global computation of the degrees of freedom, are provided. Performance of the derived elements is illustrated on a set of numerical examples, which show that the multi-layer Euler-Bernoulli beam finite element is not reliable, while the stress-resultant Euler-Bernoulli beam and the multi-layer Timoshenko beam finite elements deliver satisfying results.

Optical microcavities exhibit high resonance quality, so that, they are of key interest for the design of low-threshold lasers or for achieving strong coupling regime. But, such systems support modes whose the volume remain diffraction limited.In this manuscript, we are interested in their plasmonic counterparts because they support confined modes at the sub-wavelength scale. First, we study an in-plane plasmonic cavity which is the transposition of 1D optical cavity to surface wave. We characterize the cavity by measuring the fluorescence lifetime of dye molecules deposited inside.Then, we are interested in 3-dimension mode confinement achieved by spherical metal nanoparticles. We discuss on the definition of the mode volume used in cavity quantum electrodynamic and based on the calculation of energy confinement around the particle. We also simulate the fluorescence enhancement of rare-earth ions embedded inside core-shell plasmonic particles. Finally, we disturb the photodynamic emission of a single-photon source by puttingthe extremity of a plasmonic tip nearby the emitter

A new technique for optical pattern recognition with two-center recording of persistent holograms in doubly doped LiNbO₃3:Fe:Mn crystal is presented, by which the holograms are localized in separate slices along the recording medium. The localized recording method has the distinctive advantage of selective recording and erasure of the individual holograms without affecting the entire holographic recording medium. This capability enables dynamic content modification of the optical pattern recognition systems. Also, the diffraction efficiency of localized holograms is much larger than that of the normal volume multiplexed holograms. It is theoretically shown that the localized holographic correlator (LHC) outperforms the conventional volume holographic correlators in terms of crosstalk, shift invariance, and capacity. The LHC is experimentally demonstrated. Several persistent holograms are localized within separate slices as close as 33 μm apart along the crystal. The excessive diffraction efficiency of the localized holograms is employed to enhance the LHC robustness through multiplexing several holograms per pattern within individual slices of the recording medium. A holographic data storage system based on two-center holographic recording in a doubly doped LiNbO3:Fe:Mn crystal is developed with angular multiplexing capability. The associated imaging system has been optimized for the pixel matching of pixelated bit patterns generated by a spatial light modulator (SLM) through the recording medium onto a camera. The initial multiplexed holograms show promising contrast of dark and bright pixels. With the optimized imaging system of the developed holographic memory, the implementation of a dynamic read/write data storage system with localized recording is envisioned. The large diffraction efficiency of the localized holograms enables multilevel (M-ary) data coding to improve the storage density of the system.

Nesta tese discutimos sistematicamente os efeitos magnetocalórico e barocalórico em sistemas físicos com transição de fase magnética de primeira e de segunda ordem em sistemas físicos cujo magnetismo tem carater local. Para essa finalidade, utilizamos um modelo de momentos magnéticos locais interagentes, incluindo um termo de acoplamento magnetoelástico. Nossos cálculos mostram que a relação entre a interação de troca e o acoplamento magnetoelástico é responsável pela ordem da transição de fase e pelo aparecimento da histerese térmica e magnética. Os resultados mostram que as grandezas magnetocalóricas exibem grandes valores quando o sistema sofre uma transição de fase de primeira ordem. Além disso, quando existe uma histerese visível as grandezas magnetocalóricas dependem do processo de aquecimento e resfriamento do sistema. Ainda de acordo com nossos resultados, existe um efeito barocalórico normal (sistema aquece sob aumento de pressão) quando a pressão aplicada aumenta a temperatura de ordenamento magnético sem alterar a ordem da transição de fase magnética. O efeito barocalórico inverso (sistema resfria sob aumento de pressão) ocorre quando a pressão aplicada diminui a temperatura crítica sem mudar a ordem da transição de fase. Nossos cálculos mostram, ainda, que um efeito barocalórico anômalo (mudança de sinal nas grandezas barocalóricas) ocorre em casos especiais onde a pressão aplicada muda a natureza da transição de fase magnética do primeira para segunda ordem e vice-versa. / In this thesis we systematically discuss the magnetocaloric and barocaloric effects in physical systems, whose magnetism has a localized character and undergo both second and first order phase transitions. For this purpose, we use a model of interacting localized magnetic moments, including the magnetoelastic coupling. Our calculations show that the ratio between the exchange and magnetoelastic parameters is responsible for the appearance of the first order transition and consequently the thermal and magnetic hysteresis. Our calculations also show that the magnetocaloric quantities exhibit large values when the system undergoes a first order transition. Furthermore, when the hysteresis is not negligible, the magnetocaloric quantities depend on the heating and cooling processes. As far as the barocaloric effect is concerned, our calculations show that the normal barocaloric effect occurs (the system heat up with increasing applied pressure) when the applied pressure increases the magnetic ordering temperature without changing the order of the magnetic phase transition. On the other hand, the inverse barocaloric effect (the system cools down with increasing applied pressure) occurs when the applied pressure reduces the magnetic ordering temperature without changing the order of the magnetic phase transition. Finally, our calculations show that an anomalous barocaloric effect (i.e., change of sign in the barocaloric quantities) occurs in special cases when the applied pressure change the nature of the magnetic phase transition from first to second order and vice-versa.

Objectifs de la thèse : l’analyse à rupture de structure de type solides et membranes et la modélisation de la rupture quasi-fragile par la méthode des éléments finis à forte discontinuité en cas de solide 2D. Dans ce travail, la méthode de continuation avec une équation de contrainte quadratique est présentée sous sa forme linéarisée. En présence de ruptures locales, la méthode de continuation standard peut échouer. Afin d’améliorer la performance de cette méthode, nous proposons de nouvelles versions plus sophistiquées qui prennent en compte les ruptures locales des matériaux. D’une part, une version est basée sur une équation supplémentaire adaptative imposant une limitation. Cette version est considérée relativement satisfaisante pour les matériaux adoucissants. D’autres versions sont basées sur le contrôle de la dissipation incrémentale pour les matériaux inélastiques. Plusieurs formulations d’éléments finis à forte discontinuité sont présentées en détails pour l’analyse de rupture quasi-fragile. Les approximations discrètes du champ de déplacement sont basées sur des éléments quadrilatéraux isoparamétriques ou des éléments quadrilatéraux enrichis par la méthode des modes incompatibles. Afin de décrire la formation d’une fissure ainsi que son ouverture, la cinématique de l’élément est enrichie par quatre modes de séparation et des paramètres cinématiques. On a également proposé un nouvel algorithme de repérage de fissure pour l’évaluation de la propagation de la fissure à travers le maillage. Plusieurs exemples numériques sont réalisés afin de montrer la performance de l’élément quadrilatéral à forte discontinuité ainsi que l’algorithme de repérage de fissure proposé. / The thesis studies: the methods for failure analysis of solids and structures, and the embedded strong discontinuity finite elements for modelling material failures in quasi brittle 2d solids. As for the failure analysis, the consistently linearized path-following method with quadratic constraint equation is first presented and studied in detail. The derived path-following method can be applied in the nonlinear finite element analysis of solids and structures in order to compute a highly nonlinear solution path. However, when analysing the nonlinear problems with the localized material failures (i.e. materialsoftening), standard path-following methods can fail. For this reason we derived new versions of the pathfollowing method, with other constraint functions, more suited for problems that take into account localized material failures. One version is based on adaptive one-degree-of-freedom constraint equation, which proved to be relatively successful in analysing problems with the material softening that are modelled by the embedded-discontinuity finite elements. The other versions are based on controlling incremental plastic dissipation or plastic work in an inelastic structure. The dissipation due to crack opening and propagation, computed by e.g. embedded discontinuity finite elements, is taken into account. The advantages and disadvantages of the presented path-following methods with different constraint equations are discussed and illustrated on a set of numerical examples. As for the modelling material failures in quasi brittle 2d solids (e.g. concrete), several embedded strong discontinuity finite element formulations are derived and studied. The considered formulations are based either on: (a) classical displacement-based isoparametric quadrilateral finite element or (b) on quadrilateral finite element enhanced with incompatible displacements. In order to describe a crack formation and opening, the element kinematics is enhanced by four basic separation modes and related kinematic parameters. The interpolation functions that describe enhanced kinematics have a jump in displacements along the crack. Two possibilities were studied for deriving the operators in the local equilibrium equations that are responsible for relating the bulk stresses with the tractions in the crack. For the crack embedment, the major-principle-stress criterion was used, which is suitable for the quasi brittle materials. The normal and tangential cohesion tractions in the crack are described by two uncoupled, nonassociative damage-softening constitutive relations. A new crack tracing algorithm is proposed for computation of crack propagation through the mesh. It allows for crack formation in several elements in a single solution increment. Results of a set of numerical examples are provided in order to assess the performance of derived embedded strong discontinuity quadrilateral finite element formulations, the crack tracing algorithm, and the solution methods. / Doktorska disertacija obravnava: (i) metode za porušno analizo trdnih teles in konstrukcij, ter (ii) končne elemente z vgrajeno močno nezveznostjo za modeliranje materialne porušitve v kvazi krhkih 2d trdnih telesih. Za porušno analizo smo najprej preučili konsistentno linearizirano metodo sledenja ravnotežne poti skvadratno vezno enačbo (metoda krožnega loka). Metoda omogoča izračun analize nelinearnih modelov, ki imajo izrazito nelinearno ravnotežno pot. Kljub temu standardne metode sledenja poti lahko odpovedo,kadar analiziramo nelinearne probleme z lokalizirano materialno porušitvijo (mehčanje materiala). Zatosmo izpeljali nove različice metode sledenja poti z drugimi veznimi enačbami, ki so bolj primerne zaprobleme z lokalizirano porušitvijo materiala. Ena različica temelji na adaptivni vezni enačbi, pri katerivodimo izbrano prostostno stopnjo. Izkazalo se je, da je metoda relativno uspešna pri analizi problemov zmaterialnim mehčanjem, ki so modelirani s končnimi elementi z vgrajeno nezveznostjo. Druge različicetemeljijo na kontroli plastične disipacije ali plastičnega dela v neelastičnem trdnem telesu ali konstrukciji.Upoštevana je tudi disipacija zaradi širjenja razpok v elementih z vgrajeno nezveznostjo. Prednosti inslabosti predstavljenih metod sledenja ravnotežnih poti z različnimi veznimi enačbami so predstavljeni naštevilnih numeričnih primerih. Za modeliranje porušitve materiala v kvazi krhkih 2d trdnih telesih (npr. betonskih) smo izpeljali različne formulacije končnih elementov z vgrajeno močno nezveznostjo v pomikih. Obravnavane formulacije temeljijo bodisi (a) na klasičnem izoparametričnem štirikotnem končnem elementu bodisi (b) na štirikotnem končnem elementu, ki je izboljšan z nekompatibilnimi oblikami za pomike. Nastanek in širjenje razpoke opišemo tako, da kinematiko v elementu dopolnimo s štirimi osnovnimi oblikami širjenja razpoke in pripadajočimi kinematičnimi parametri. Interpolacijske funkcije, ki opisujejo izboljšano kinematiko, zajemajo skoke v pomikih vzdolž razpoke. Obravnavali smo dva načina izpeljave operatorjev, ki nastopajo v lokalni ravnotežni enačbi in povezujejo napetosti v končnem elementu z napetostmi na vgrajeni nezveznosti. Kriterij za vstavitev nezveznosti (razpoke) temelji na kriteriju največje glavne napetosti in je primeren za krhke materiale. Normalne in tangentne kohezijske napetosti v razpoki opišemo z dvema nepovezanima, poškodbenima konstitutivnima zakonoma za mehčanje. Predlagamo novi algoritem za sledenje razpoki za izračun širjenja razpoke v mreži končnih elementov. Algoritem omogoča formacijo razpok v več končnih elementih v enem obtežnem koraku. Izračunali smo številne numerične primere, da bi ocenili delovanje izpeljanih formulacij štirikotnih končnih elementov z vgrajeno nezveznostjo in algoritma za sledenje razpoki kot tudi delovanje metod sledenja ravnotežnih poti.

L ’intérêt des nano-particules pour le domaine de l ’optique visible a été suscité lors du premier rapport rédigé par Faraday en 1857 et qui a initié les bases de la production de nanoparticules métalliques en vue de leur propriété optiques inattendues (coloration des solutions). Plus récemment, le contrôle et le guidage de la lumière basés sur l’excitation de résonance plasmon dans les nanostructures a permis beaucoup d’applications liées à la vie quotidienne et impliquant la lumière. La résonance plasmonique de structures métalliques estun phénomène essentiel qui conduit à des propriétés optiques uniques à travers l’interaction de la lumière avecles électrons libres du métal. L’excitation de la résonance plasmon localisé (LSPR) permet d’exalter localement l’énergie électromagnétique comme dans le cas des nano-antennes mais aussi d’acheminer la lumière à travers des canaux de dimensions sub-l sur de grandes distances distances grâce à l’excitation du Plasmonde Surface Propagatif (PSP). Au cours de cette thèse, nous avons étendu un algorithme existant afin de calculer la réponse optique (sections efficaces de diffusion et d’absorption) de NPs ayant une forme géométrie quelconque. Ce type de NP anisotrope (vis-à-vis de la polarisation incidente) peut présenter à la résonance plasmonique une section efficace de diffusion 25 fois supérieure à celle géométrique. De plus, une étude systématique importante a été effectuée afin d’optimiser la géométrie de tels Nps.En ce qui concerne la PSP qui est impliqué dans la transmission exaltée à travers les matrices d’ouvertures annulaires AAA, nous avons entrepris une étude systématique des propriétés de l’excitation du mode particul particulier sans coupure de ces nano - guides. Il s’agit du mode Transverse Electrique et Magnétique (TEM). Une étude numérique complète est alors effectuée pour correctement concevoir la structure avant qu’elle ne soit expérimentalement fabriquée et caractérisée. Pour palier certaines contraintes expérimentale, une structure inclinée est proposée et étudiée dans le cas d’un métal parfaitement conducteur. Nous avons démontrée numériquement et analytiquement certaines propriétés intrinsèques de la structure montrant un coefficient de d’au moins 50% d’un faisceau incident non polarisé indépendamment des conditions d’éclairage (polarisation,angle et plan d’incidence). Lorsque le mode TEM est excité, le flux laminaire de l’énergie à travers la structure présente une déviation géante sur de très petites distances inférieures à la longueur d’onde. Les résultats présentés dans cette thèse pourraient être considérés comme une contribution importante à la compréhension du phénomène de transmission exaltée basé sur l’excitation de ce type de mode guidé. / The release of the rst report by Faraday in 1857 set the foundation of the production of metal nanoparticlesand their unexpected optical properties (coloring). More recently, controlling and guiding light via plasmonicresonance in nanostructures enable a lot of applications affecting everyday life that involves light. Plasmonresonance of metallic structures is a key phenomenon that allows unique optical properties through the interactionof light with the free electrons of the metal. The excitation of Localized Surface Plasmon Resonance(LSPR) leads to turn-on large local enhancements of electromagnetic energy as within antennas or to routelight as waveguide to desired region with high transmission through the excitation of Propagating SurfacePlasmon (PSP). During this thesis, we have developed an existing algorithm in order to calculate the opticalresponse of NPs of any shape. We have especially determined the localized energy enhancement factor interm of optical response of nano-antenna. This anisotropic (polarization dependent) NPs type can feature, atplasmon resonance, scattering efciency factor higher than 25. Moreover, an important systematic study hasbeen performed in order to optimize design of such NPs.Concerning the PSP that are involved in the enhanced transmission through Annular Aperture Arrays (AAAs),we systematically study the properties of the excitation of the peculiar Transverse ElectroMagnetic (TEM) guidedmode inside such nano-apertures. A complete numerical study is performed to correctly design the structurebefore it is experimentally characterized. For reasons associated to fabrication constraints and efciency,a slanted AAA made in perfectly conducting metal is proposed and studied. We numerically and analyticallydemonstrate some intrinsic properties of the structure showing a transmission coefcient of at least 50%ofan un-polarized incident beam independently of the illumination configuration (polarization, angle, and planeof incidence). At the TEM peak transmission, the laminar flow of the energy through the structure can exhibitgiant deviation over very small distances ( ). The results presented in this thesis could be considered as animportant contribution to the understanding of the enhanced transmission phenomenon based on the excitationof guided modes