Mafic and intermediate intrusions commonly accompany Variscan granitoid plutons in Europe. They are documented from different localities of Iberian Peninsula, from the French Massif Central, Schwarzwald, from different parts of the Bohemian Massif, in Romania, Greece, Corsica and Sardinia. They comprise wide petrographic varieties from quartz gabbros, diorites, granodiorites to monzonites. They usually constitute small bodies or veins, they often occur as mafic microgranular enclaves (MME) in granodiorites and in some granites. Dioritic intrusions are characterized by a relatively high amounts of lithophile elements (Rb, Sr, Ba, Cs, LREE), and they are simultaneously high in compatible elements (Ni, Cr, V a Co). Their isotopic ratios 87 Sr/86 Sr are in all compared locations similar and are close to the Bulk Earth (0.704 - 0.708). εNd values show larger scatter, some intrusions have more crustal composition (to -8), on the other hand, another intrusions have εNd positive, that points to a contribution of basic magma. The age of dioritic intrusions differs according to individual locality suggesting more than one magmatic episode. The oldest occur in the French Massif Central (361 - 365 Ma), whereas the youngest are documented in Iberia (312 - 310 Ma). The oldest mafic intrusions in the Bohemian...

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This study is an effort to characterize the magma sources, plumbing system, and eruptive behavior of Mount Hood, a low-explosivity recharge-dominated volcano in the Oregon Cascades. The three manuscripts in this dissertation make use of melt inclusion data, phenocryst compositions, and whole rock petrology and geochemistry to build a schematic model of plumbing, mixing, and eruption at Mount Hood. Volatile contents in melt inclusions were measured by Fourier Transform Infrared Spectroscopy (FTIR) and Secondary Ion Mass Spectometry (SIMS). These measurements indicate that the pre-eruptive volatile contents at Mount Hood are comparable to concentrations in more explosive volcanoes, and do not sufficiently explain the low explosivity of Mount Hood. Measured H₂O contents were also used to test the validity of multiple different hygrometers. Various geothermobarometers were applied to the melt inclusions and phenocrysts from Mount Hood, and demonstrate that pre-eruptive temperatures increase by 100-150 ̊C immediately after mafic recharge, which occurs days to weeks prior to eruption and is accompanied by a 5-10 fold decrease in magma viscosity. Numerical simulations of magma ascent indicate that magma fragmentation is significantly delayed with this magnitude of pre-eruptive heating, which reduces the likelihood of explosive eruption. Analyses of amphibole demonstrate two markedly different populations, which correspond to different magma compositions, temperatures, and pressures. Pressure and temperature calculations were compared to other geothermobarometers to crosscheck the validity of these results and generally agreed well. Trace element concentrations in lavas, enclaves, and inclusions from Mount Hood confirm previous models for simple binary mixing at Mount Hood. A linear regression technique for extrapolating the major element contents of the mixing endmembers works acceptably well to characterize the trace element budgets of these endmembers. Additionally, we observe that the "recharge filter" that is responsible for the compositionally monotonous lavas at Mount Hood is also the likely cause of long-term low explosivity, and is indicative of a two-part magma plumbing system that may be a general model for a number of other recharge-dominated arc volcanoes. The results presented in this dissertation, in concert with previous results by other authors, converge on a generally consistent model for the production, hybridization, and eruption of intermediate lavas at Mount Hood and elsewhere. / Graduation date: 2012 / Access restricted to the OSU Community at author's request from Sept. 16, 2011 - March 16, 2012

Southeast Iceland exhibits a granophyre pluton called Reyðarártindur, which has never been described in detail before. The Reyðarártindur magma chamber formed 7.30 ± 0.06 Ma ago (Padilla, 2015). Glacial and coastal erosion expose the pluton, and a river cuts through the pluton roof and walls, revealing interaction between different blob-like structures of magma. The formation of magma chambers can take a very long time, it is therefore likely for several different magmas to interact. Incremental formation of different magma batches give rise to mixing and mingling in magma chambers. To understand when the magma mixing was initiated and the mechanisms controlling it, descriptive analysis were made to obtain textural properties of collected rock samples from the field. The purpose for this thesis study was to examine if there is a frequency size and shape distribution of the magma blobs and if the different magma blobs are systematically distributed across the river. Previous studies have inferred conduit locations and magma mixing processes through similar methods. Extensive field studies have provided all samples for this thesis. Five distinct, magma types were described and found to be interacting. There was one ‘host magma’ which the other four different magma types are exposed as ‘blobs’ within. The statistical analysis involved mapping the blob-like structures from photos taken with an Unmanned Aerial System (URA; drone), using the software Inkscape. The data and measurements for the blobs was collected and summarized in ImageJ. The data was then statistically analyzed in Excel, illustrating the frequency of the magma blob’s size and shape distribution in selected parts of the river. The results of the statistical analysis of the magma blobs showed that ~80 % of the blobs existed in a size interval between 0 – 0.1 m2 . This thesis provides a discussion about the implications of the blob distributions for magma chamber recharge and processes within this section of the magma chamber. The shape distribution analysis showed an indication for all the blobs to be more rounded and equant. This suggest that the magma mixing event probably happened at the same time, during a liquid phase. / På sydöstra Island återfinns en granofyrisk pluton kallad Reyðarártindur. Det är en magmakammare som aldrig tidigare blivit beskriven i detalj. Magmakammaren bildades för 7,30 ± 0,06 Ma sedan (Padilla, 2015). Plutonen har blivit exponerad genom glacial- och fluvial erosion samt att en flod skär igenom plutonens tak och väggar. Den eroderande floden exponerar olika fläckliknande strukturer av magmainteraktioner. Ett gradvist bildande av olika magmasatser har över lång tid gett upphov till en blandning i magmakammaren. För att förstå när magmablandningen initierades och mekanismerna bakom fenomenet, har en beskrivande analys gjorts för att ta reda på texturella egenskaper av insamlade bergartsprover från fält. Syftet med denna studie var att undersöka om det fanns en storleks- och formdistribuering av magmafläckarna samt om de olika magmafläckarna är systematiskt distribuerade i flodbädden. Tidigare studier har antytt var undersökta magmakanalsystemen kan finnas samt hur blandningsprocesser för magma går till med hjälp av liknande metoder. Redan genomförda fältstudier har samlat in allt råmaterial som ligger till grund för denna studie. Fem olika magmatyper har beskrivits och påvisades interagera. Det fanns en ”värdmagma” som de andra fyra magmatyperna var exponerade som fläckar i. De statistiska analyserna inkluderade kartering av de fläckliknande magmaformerna baserat på foton tagna med hjälp av en drönare. Tre olika mjukvaror användes för att samla in, mäta och analysera data; Inkscape, Image J och Excel. Resultaten från den statistiska analysen visade att ungefär 80 % av alla fläckar existerade inom ett areaintervall mellan 0 – 0,1 m2 . Denna studie innehåller en diskussion om implikationerna av magmafläckarnas distribution med avseende på magmaomladdning och -processer inuti denna sektion av magmakammaren. Den generella formdistributionen visade en indikation för att alla fläckar tenderar att vara mer rundade och kvadratiska. Detta antyder att magmans blandningsförlopp troligtvis inträffade vid ungefär samma tidpunkt, under en flytande fas.

Samli Fe-oxide (+Cu&plusmn / Au) deposit is hosted by Samli pluton and rocks of Karakaya Complex in western Anatolia. The pluton consists of both mafic and felsic phases showing magma mixing textures. 40Ar/39Ar geochronology yielded an age range of 23.2&plusmn / 0.5 to 22.42&plusmn / 0.11 Ma for the Samli pluton, overlapping with 40Ar/39Ar age of 22.33&plusmn / 0.59 Ma and U-Pb age of 23.34&plusmn / 0.19 Ma from alterations. Sr-Nd isotope data are suggestive of a metasomatized subcontinental lithospheric mantle (SCLM) source for the magma. Alteration-mineralization pattern is defined by a series of overlapping halos characterized by sodic-calcic (plagioclase-pyroxene&plusmn / scapolite), calcic (garnet-pyroxene&plusmn / epidote), potassic (biotite+magnetite+chalcopyrite), hematite-limonite, and late stage (chalcedony-calcite+native Cu) alterations. Stable (&delta / 18O, &delta / 34S) and radiogenic (87Sr/86Sr,143Nd/144Nd) isotope compositions suggest a magmatic source for the fluids responsible for alteration-mineralization. Given the spatial-temporal association of alteration- mineralization with magmatic rocks, the hydrothermal system that controls mineralization in Samli appears to be linked with emplacement and cooling of Samli pluton. Samli Fe-oxide (+Cu&plusmn / Au) deposit has features characteristic for both skarn- and Iron-Oxide-Copper-Gold (IOCG) type deposits. The spatial and temporal association with a porphyritic intrusion, widespread calc-silicate assemblage, metal content (abundant Fe-oxide with high copper content) are similar to calcic Fe-Cu skarns, whereas low-Ti (&le / 0.05% TiO2) magnetite/hematite, low-S sulfides (chalcopyrite&gt / pyrite), high Cu (up to 6.78%) and moderate Au (up to 8.82 ppm) grades, local structural control in alteration-mineralization, and the derivation of the causative magma from a SCLM resembles the features pertinent to IOCG type mineralization. Therefore, Samli deposit is defined as a skarn type Fe-Cu mineralization with a potential for IOCG type deposit.

Composition and texture of the Middle and Late Eocene volcanic, volcaniclastic, and volcanic-sedimentary rocks in the Bijgerd-Kuh e Kharchin area, in the Uromieh-Dokhtar zone northwest of Saveh, Iran, suggest the complexity of the magmatic system that involved multiple eruptions from one or more sources. Hydrated volcanic fragments in hyaloclastic rocks, and the presence of a sequence of shallow and intermediate-depth marine microfossils, suggest that the Middle Eocene units were erupted in a marine basin. The bimodal volcanism of the Late Eocene is distinguished by the presence of four alternating sequences of hyaloclastite lava and ignimbrite. The REE patterns show spatial homogeneity and temporal heterogeneity in the composition of all the Late Eocene sequences, suggesting origination of magma from varying sources that erupted at different times. The trace element distributions of the hyaloclastites and ignimbrites are compatible with those evolved through fractional crystallization of the lower and upper continental crust, respectively.

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On June 15, 1991, Mount Pinatubo, Philippines, ejected 20 million tonnes of sulfur dioxide into the atmosphere, significantly impacting global climate and stratospheric ozone. Recharging basaltic magma mixed into the 50 km³ dacitic magma reservoir 6 to 11 km beneath Mount Pinatubo, and triggered the 1991 eruption. The result of the magma mixing was a hybrid andesite with quenched basalt inclusions that erupted as a dome between June 7 and June 12. On June 15, approximately 5 km³ of anhydrite-bearing magma was erupted from the main phenocryst-rich, dacitic reservoir. This study will utilize this extraordinary framework of the 1991 Pinatubo eruption to investigate the systematics of sulfur uptake by apatite in order to further develop apatite as a monitor for magmatic sulfur. In the dacite and hybrid andesite, apatite occurs as individual phenocrysts (up to ~200 μm diameter) or included within anhydrite, hornblende, and plagioclase phenocrysts. In the basaltic magmatic inclusions, apatite is found as acicular microphenocrysts. Electron microprobe data collected on apatite yield low- (0.7 wt.% SO₃) apatites in all juvenile products, and show that two distinct populations of apatites exist: "silicic" apatites (hosted in dacite and andesite) and basalt apatites. Apatites crystallizing from silicic melt have predominantly low- to medium-sulfur contents, but high-sulfur apatites with as much as 1.2-1.7 wt.% SO₃ occur sporadically as inclusions in plagioclase, hornblende, Fe-Ti oxide, and anhydrite. These concentrations are much higher than what could be achieved through equilibrium crystal-melt partitioning at pre-eruption conditions (760±20°C, 220MPa, NNO+1.7, 77 ppm S in melt inclusions) and a partition coefficient of 13. Apatite in the basalt is always sulfur-rich with compositions forming a continuous array between 0.7 to 2.6 wt.% SO₃. The population of apatite that crystallized from silicic melt has elevated cerium, fluorine, and chlorine and lower magnesium concentrations (average dacite values in wt.%: 0.21 Ce₂O₃, 1.4 F, 1.1 Cl, & 0.14 MgO) relative to the population of apatite from the basalt (average basalt values in wt.%: 0.05 Ce₂O₃, 1.0 F, 0.78 Cl, & 0.22 MgO). LA-ICP-MS trace element data also show distinct apatite populations between silicic and basalt apatites. Silicic apatites have elevated REE concentrations (La avg. = 750 ppm), lower Sr (avg.= 594 ppm), and a pronounced negative Eu anomaly (avg. Eu/Eu* = 0.57) relative to basalt apatites (avg. values: 217 ppm La, 975 ppm Sr, and Eu/Eu* = 1.16). The correlation of EMP sulfur data and LA-ICP-MS trace element data show no difference between high-S and low-S silicic apatites. These compositional systematics rule out the possibility that sulfur-rich apatite from dacite are inherited from mafic magma. Sulfur element maps of apatites show no evidence of S-diffusion from anhydrite hosts. Areas of high-S concentrations show complicated patterns that suggest multiple periods of sulfur enrichment. High-S silicic apatites are likely the product of "fluid-enhanced crystallization" from early enrichment of a SO₂ rich fluid phase from the underplating basalt, which occurred prior to or at anhydrite saturation. This fluid phase is the only possible sufficient source of sulfur for generating high-S apatites in a cool, "wet", dacitic melt. The dynamics of apatite sulfur enrichment via "fluid-enhanced crystallization" is yet unclear and requires further experimental laboratory investigation.

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The North American Wall mafic dikes and the diorite of the Rockslides mafic complex in the intrusive suite of Yosemite Valley show evidence of mixing with their host granites as well as with earlier components. Whole rock major element variation diagrams indicate the mafic rocks mixed with a more silicic component, but extrapolating to the silica end member does not yield the same result with each element. Trace element concentrations show a wide variation in concentration of Cr and Ni, with two samples showing enrichment in Cr (>300 ppm) and Ni (~44 ppm) compared to other samples (Cr =13-94 ppm; Ni = 5-26 ppm). These samples have the most primitive epsilon Nd values (-3.3, -3.5 at 100 Ma) analyzed thus far for the intrusive suite, indicating the suite has a larger range of isotopic values than previously thought. Delta 18 oxygen for Rockslides samples vary from 6.6 to 7.5 per mille (6 samples, average 7.03), higher than the 5.5 + 0.3 range for the mantle, indicating the presence of a crustal component in the system. Plagioclase phenocrysts within each unit display bimodal compositional populations. Subhedral to euhedral partially resorbed calcic cores (mode = An84-88) are reminiscent of a mafic magma, while sodic rims (mode = An48-50) are the product of a more silicic component. Very little to no intermediate zoning is present between cores and rims. Mineral-scale 87Sr/86Sr analysis of plagioclase cores and rims are consistent with previously published enriched bulk-rock ratios for the suite (0.7065-0.7078), but are unable to distinguish between mixing components. The plagioclase isotopic data show no direct evidence for a depleted mantle melt component contaminated by crustal assimilation. However, the mafic rocks are comparable to high-alumina basalts, whose generation involves crystal fractionation and magma mixing/crustal assimilation. The evolution of these high-alumina basalts provides an opportunity for magma contamination to take place before plagioclase crystallization, thus explaining why plagioclase core-rim analysis could not distinguish between mixing components. Therefore, it is possible but not necessary to derive the rocks from an enriched mantle source, especially since the bulk-rock oxygen isotopic values indicate a significant crustal component is present.