Thesis (Ph. D.)--University of Hong Kong, 1999. / Includes bibliographical references.

Thesis (M.S.)--University of Missouri-Columbia, 2005. / The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (July 14, 2006) Vita. Includes bibliographical references.

It is widely accepted that the accuracy and efficiency of computational fluid dynamics (CFD) simulations is heavily influenced by the quality of the mesh upon which the solution is computed. Unfortunately, the computational tools available for assessing mesh quality remain rather limited. This report describes a methodology for rigorously investigating the interaction between a flow solver and a variety of mesh configurations for the purposes of deducing which mesh properties produce the best results from the solver. The techniques described herein permit a more detailed exploration of what constitutes a quality mesh in the context of a given solver and a desired flow regime. In the present work, these newly developed tools are used to investigate mesh quality as it pertains to a high-order accurate discontinuous Galerkin solver when it is used to compute inviscid and high-Reynolds number flows in domains possessing smoothly curving boundaries. For this purpose, two flow models have been generated and used to conduct parametric studies of mesh configurations involving curved elements. The results of these studies allow us to make some observations regarding mesh quality when the discontinuous Galerkin method is used to solve these types of problems. Briefly, we have found that for inviscid problems, the mesh elements used to resolve curved boundaries should be at least third order accurate. For viscous problems, the domain boundaries must be approximated by mesh elements that are of the same order as the polynomial approximation of the solution if the theoretical order of accuracy of the scheme is to be maintained. Increasing the accuracy of the boundary elements to at least one order higher than the solution approximation typically results in a noticeable improvement in the computed error norms. It is also noted that C1-continuity of the mesh is not required at element interfaces along the boundary.

No description available.

No description available.

published_or_final_version / Industrial and Manufacturing Systems Engineering / Doctoral / Doctor of Philosophy

This thesis provides improvements to computational fluid dynamics accuracy and ef- ficiency through two main methods: a new boundary condition verification procedure and preconditioning techniques. First, a new verification approach that addresses boundary conditions was developed. In order to apply the verification approach to a large range of arbitrary boundary condi- tions, it was necessary to develop unifying mathematical formulation. A framework was developed that allows for the application of Dirichlet, Neumann, and extrapolation bound- ary condition, or in some cases the equations of motion directly. Verification of boundary condition techniques was performed using exact solutions from canonical fluid dynamic test cases. Second, to reduce computation time and improve accuracy, preconditioning algorithms were applied via artificial dissipation schemes. A new convective upwind and split pressure (CUSP) scheme was devised and was shown to be more effective than traditional precon- ditioning schemes in certain scenarios. The new scheme was compared with traditional schemes for unsteady flows for which both convective and acoustic effects dominated. Both boundary conditions and preconditioning algorithms were implemented in the context of a "strand grid" solver. While not the focus of this thesis, strand grids provide automatic viscous quality meshing and are suitable for moving mesh overset problems.

Concern for child wellness has led play professionals to explore natural playscapes as a means to enhance free play and consequently child development. For preschool-aged children, dramatic play is a particularly valuable free play that advances cognitive skills, social skills, and emotional intelligence. This study compared thedramatic play affordances of natural and manufactured outdoor play settings to determine which afford the most dramatic play for preschool-aged children. Twenty-four 3- to 5- year-olds were observed during daily playtime on a “natural playground” and an equipment-based “manufactured playground.” Behavior mapping identified settings that afforded the most solitary dramatic, sociodramatic, and complex sociodramatic play. The study suggests that environments designed with child-scale constructive play props, a sense of enclosure, and natural surroundings are more likely to support complex dramatic play. Intentional inclusion of these design elements may afford greater dramatic play in the preschool play yard.

This study utilized individual and county-level analysis to examine the impact of demographic and distal factors on individual level mortality as well as spatial and county specific attributes on county death rates. The data used in the individual level analyses come from the linked NHANES NDI data set and the county level data come from multiple sources including spatially referenced sources. Findings suggest that having private or Federal insurance attenuates the mortality discrepancy between racial groups at the individual level and that spatial factors have an impact on county death rates that are not explained by county attributes. These analyses present questions about using common indicators to measure mortality at different levels suggesting that the variables used to understand mortality on the individual level are different from those that should be used to understand mortality at the county level.

The presence of coal tars in the subsurface associated with former manufactured gas plants (MGPs) offers a remediation challenge due to their complex chemical composition, dissolution behaviour and recalcitrant characteristics. A former MGP site in Clearwater Beach, Florida was characterized and bench-scale analyses were conducted to assess the potential for in situ chemical oxidation (ISCO) using persulfate to treat MGP residuals. Completion of a conceptual site model identified a homogeneous, silty sand aquifer, with an average hydraulic conductivity of approximately 2.3x10-3 cm/s and a groundwater flow rate of 2 cm/day in the direction of S20°E. Six source zones, three near the water table and three in the deep aquifer were estimated to have a total volume of 108 m3. A multi-level well transect was installed to monitor concentrations of dissolved compounds and to estimate mass discharge downgradient of the source zones over time. On average, the morphology of the aqueous concentrations remained consistent with time. A total mass discharge across the transect of 94 mg/day was estimated for site-specific compounds. Bench-scale tests were conducted on aquifer sediments and groundwater samples. The aquifer was determined to have a low buffering capacity, low chemical oxygen demand, and low natural oxidant interaction (NOI) with persulfate. Aqueous batch experiments identified the potential for iron (II) activated persulfate to reduce concentrations of BTEX and PAHs below method detection limits (MDLs). Unactivated persulfate was able to reduce BTEX concentrations to below MDLs after 14 days; however, the concentration of PAH compounds remained above MDLs after 14 days. Higher iron doses within the system were shown to be more effective in reducing BTEX and PAH compounds. Column experiments designed to mimic site conditions were used to evaluate the feasibility of persulfate treatment on impacted sediments from the Clearwater site. Two sets of column experiments were conducted: one using unactivated persulfate followed by alkaline activated persulfate; and one using iron (II) activated persulfate. On average, unactivated persulfate was able to reduce BTEX and PAH aqueous effluent concentrations by > 75% and 40%, respectively, after a total dose of 60 g/g soil. Two additional doses of alkaline activated persulfate (total persulfate dose of ~80g/g soil) in these columns were able to further reduce effluent BTEX and PAH concentrations by > 90% and > 75%, respectively. Iron (II) activated persulfate reduced effluent BTEX concentrations by > 70% and PAHs by > 65% after a total dose of 35 g/g soil. Average reductions in mass for BTEX and PAH compounds were approximately of 48% and 26% respectively in the iron (II) activated persulfate columns, and 24% and 10%, respectively in the alkaline activated persulfate columns. The potential for the ability to use in situ chemical oxidation using persulfate for the remediation of MGP residuals in the subsurface is evaluated using field measurements and bench-scale experimentation. The reductions observed in aqueous phase compounds in MGP groundwater as observed in the laboratory indicate the potential for reductions in groundwater concentrations at this and other contaminated former MGP sites. However, column experiments, indicating the inability for activated persulfate to reduce all identified compounds in the MGP NAPL suggest source treatment with activated persulfate would not reduce concentrations to below Florida Department of Environmental Protection natural attenuation concentrations.