Thesis (MSc)--University of Stellenbosch, 2005. / Bibliography. Also available via the Internet.

No description available.

Thesis (M.S.) in Chemistry--University of Maine, 2001. / Includes vita. Includes bibliographical references (leaves 61-67).

No description available.

Lignocellulose can become the best opportunity for the society to reduce its dependency on the harmful petroleum based products as well as to produce clean energy. In each part of the production cycle, biomass based products have a better environmental profiles than their petroleum based counterparts. Woody biomass has a vast availability, but it suffers from recalcitrance that is mostly caused by lignin that is functioning as a matrix, surrounding and binding the carbohydrates that are currently the most valuable of the wood components. Lignin-carbohydrate (LC) bonds are believed to be a key element in this recalcitrance and research has shown that these types of bonds are common in wood. These bonds are important in an economical point of view as well, as e.g. residual lignin structures in pulp (lignins bonded to the cellulose and hemicelluloses) require expensive bleaching sequences for their removal. The LC-structures can also be exploited technically as we now have demonstrated. We developed a method that utilizes phenolic end groups that are bonded to different hemicelluloses for cross-linking. The enzyme laccase was used for the cross-linking to create a cost-efficient processing scheme to both isolate and increase the molecular weight of the hemicelluloses. Membrane filtration was used as the key separation technique, which enables the establishment of industrial scale production. The final product had improved mechanical and thermal properties and could be used e.g. as barrier film component in renewable packaging. Nanocomposite formation with nanofibrillated cellulose was also studied. This improved the film properties further. The complexes are also possible to use as model compounds for lignin-carbohydrate complexes in wood. This technique can also be seen to mimick the lignification and lignin-carbohydrate network formation phenomena in plants enabling the formation of entire networks of wood components. Our results suggests that the side chains of hemicellulose might play an important role in network formation and that hemicellulose molecules can carry more than one lignin phenolic end group to fulfill this capability. / <p>QC 20140825</p>

The modern concept of “biorefinery” is dominantly based on chemical pulp mills to create more value than cellulose pulp fibres, and energy from the dissolved lignins and hemicelluloses. This concept is characterized by the conversion of biomass into various bio-based products. It includes thermochemical processes such as gasification and fast pyrolysis. In thermo-mechanical pulp (TMP) mills, the feedstock available to the gasification-based biorefinery is significant, including logging residues, bark, fibre material rejects, bio-sludges and other available fuels such as peat, recycled wood and paper products. On the other hand, mechanical pulping processes consume a great amount of electricity, which may account for up to 40% of the total pulp production cost. The huge amount of purchased electricity can be compensated for by self-production of electricity from gasification, or the involved cost can be compensated for by extra revenue from bio-transport fuel production. This work is to study co-production of bio-automotive fuels, bio-power, and steam via gasification of the waste biomass streams in the context of the mechanical pulp industry. Ethanol and substitute natural gas (SNG) are chosen to be the bio-transport fuels in the study. The production processes of biomass-to-ethanol, SNG, together with heat and power, are simulated with Aspen Plus. Based on the model, the techno-economic analysis is made to evaluate the profitability of bio-transport fuel production when the process is integrated into a TMP mill.The mathematical modelling starts from biomass gasification. Dual fluidized bed gasifier (DFBG) is chosen for syngas production. From the model, the yield and composition of the syngas and the contents of tar and char can be calculated. The model has been evaluated against the experimental results measured on a 150 KWth Mid Sweden University (MIUN) DFBG. As a reasonable result, the tar content in the syngas decreases with the gasification temperature and the steam to biomass (S/B) ratio. The biomass moisture content is a key parameter for a DFBG to be operated and maintained at a high gasification temperature. The model suggests that it is difficult to keep the gasification temperature above 850 ℃ when the biomass moisture content is higher than 15.0 wt.%. Thus, a certain amount of biomass or product gas needs to be added in the combustor to provide sufficient heat for biomass devolatilization and steam reforming.For ethanol production, a stand-alone thermo-chemical process is designed and simulated. The techno-economic assessment is made in terms of ethanol yield, synthesis selectivity, carbon and CO conversion efficiencies, and ethanol production cost. The calculated results show that major contributions to the production cost are from biomass feedstock and syngas cleaning. A biomass-to-ethanol plant should be built over 200 MW.In TMP mills, wood and biomass residues are commonly utilized for electricity and steam production through an associated CHP plant. This CHP plant is here designed to be replaced by a biomass-integrated gasification combined cycle (BIGCC) plant or a biomass-to-SNG (BtSNG) plant including an associated heat &amp; power centre. Implementing BIGCC/BtSNG in a mechanical pulp production line might improve the profitability of a TMP mill and also help to commercialize the BIGCC/BtSNG technologies by taking into account of some key issues such as, biomass availability, heat utilization etc.. In this work, the mathematical models of TMP+BIGCC and TMP+BtSNG are respectively built up to study three cases: 1) scaling of the TMP+BtSNG mill (or adding more forest biomass logging residues in the gasifier for TMP+BIGCC); 2) adding the reject fibres in the gasifier; 3) decreasing the TMP SEC by up to 50%.The profitability from the TMP+BtSNG mill is analyzed in comparison with the TMP+BIGCC mill. As a major conclusion, the scale of the TMP+BIGCC/BtSNG mill, the prices of electricity and SNG are three strong factors for the implementation of BIGCC/BtSNG in a TMP mill. A BtSNG plant associated to a TMP mill should be built in a scale above 100 MW in biomass thermal input. Comparing to the case of TMP+BIGCC, the NR and IRR of TMP+BtSNG are much lower. Political instruments to support commercialization of bio-transport fuel are necessary. / Gasification-based Biorefinery for Mechanical Pulp Mills

Thesis (Ph. D.)--Institute of Paper Science and Technology, Georgia Institute of Technology, 2001. / Includes bibliography.

A crucial parameter in the production of mechanical pulp through refining is energy consumption. Although low consistency (LC) refining has been shown to be more energy efficient than conventional high consistency refining, the degradation of mechanical properties of the end-product paper due to fiber cutting has limited the widespread adoption of LC refining. In conventional control strategies, the onset of fiber cutting is determined by post-refining measurement of pulp properties which does not enable rapid in-process adjustment of refiner operation in response to the onset of fiber cutting. In this dissertation, we exploit a piezoelectric force sensor to detect the onset of fiber cutting in real time. Detection of the onset of fiber cutting is potentially beneficial in low consistency refining as part of a control system to reduce fiber cutting and increase energy efficiency. The sensor has a probe which replaces a short length of a refiner bar, enabling measurement of normal and shear forces applied to pulp fibers by the refiner bars. The custom-designed sensors are installed in an AIKAWA pilot-scale 16-in. single-disc refiner at the Pulp and Paper Centre at the University of British Columbia. Trials were run using different pulp furnishes and refiner plate patterns at differing rotational speeds and a wide range of plate gaps. Pulp samples were collected at regular intervals and the pulp and paper properties were measured. We observe distinct transitions in the parameters that characterize the distributions of peak normal and shear forces which consistently correspond to the onset of fiber cutting. In addition, the analysis of the power spectrum of the sensor data shows that the magnitude of the dominant frequency can be used as an indicator of fiber cutting. The power of the time domain signal of the normal force is shown to be the most reliable and consistent indication of the onset of fiber cutting. This parameter consistently identifies the onset of fiber cutting, as determined by fiber length data, for all tested pulp furnishes and plate patterns. In addition, we investigate the effect of pulp furnish and plate pattern on bar forces in LC refining. For tested pulp furnishes and at all plate gaps, the plate with higher bar edge length (which has smaller bar width and groove width) results in lower mean peak normal and shear forces but higher mean coefficient of friction. Moreover, at the onset of fiber cutting, the mean peak normal force of softwood pulp is higher than that for hardwood pulp. Our results also show that the mean coefficient of friction at the onset of fiber cutting is a function of plate gap, pulp furnish, and plate pattern. / Graduate / 2019-01-09

No description available.

Hallsta Paper Mill, which is a part of Holmen Paper, uses the Thermo Mechanical Pulping process to produce paper pulp. One of their process steps is a plug screw feeder that transport and compresses chips. Jams often occur in the plug screw and there is currently a lack of knowledge of how it should be operated for the highest possible production quantity. The purpose of the thesis is to identify the causes that lead to failures of the plug screw and to find an optimal way of operating it.  In order to gain a deeper understanding of the different areas covered by the study, the theory of the Thermo Mechanical Pulping process used at Holmen for production of paper pulp has been presented. Also, theory about how the chips is being processed, the plug screw and its dimensions, the improvement strategy used in the study and about maintenance.  Collecting documents was done using business systems such as IFS and WinMops and interviews were conducted. The data analysis method used were a regression analysis and a fishbone diagram. From this, optimal parameters for operating the plug screw have been developed.  From the results, an improvement proposal has been designed to create clear guidelines for operating and maintaining the screw as well as other production steps that have an impact on the screw, in order to avoid unnecessary wear and failures of the plug screw.