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TRIP-assisted multiphase steels exhibit an excellent balance of strength and ductility, which makes them very attractive for the automotive industry. These remarkable mechanical properties can be attributed mainly to the continuous transformation of retained austenite into martensite during straining (TRansformation Induced Plasticity). The aim of this thesis was to clarify the interaction between the hot rolling conditions, the formation of microstructure, and the resulting mechanical properties. Various rolling simulation techniques were employed to determine how the composite microstructure is formed during the various steps of multi-stage thermomechanical processing. The interaction between deformation and phase transformation is highlighted, particularly from the viewpoint of the transformation texture.

TRIP-assisted multiphase steels exhibit an excellent balance of strength and ductility, which makes them very attractive for the automotive industry. These remarkable mechanical properties can be attributed mainly to the continuous transformation of retained austenite into martensite during straining (TRansformation Induced Plasticity). The aim of this thesis was to clarify the interaction between the hot rolling conditions, the formation of microstructure, and the resulting mechanical properties. Various rolling simulation techniques were employed to determine how the composite microstructure is formed during the various steps of multi-stage thermomechanical processing. The interaction between deformation and phase transformation is highlighted, particularly from the viewpoint of the transformation texture.

Abstract The evolutions of microstructure and texture in 2205 duplex stainless steel (DSS) welds produced by two high energy density (HED) processes, CO2 laser beam welding (LBW) and electron beam welding (EBW) were investigated. A variety of analytical techniques were applied for the study on microstructure and texture of the welds. In which, optical microscopy and electron microscopy were used to evaluate the detailed microstructure. X-ray diffraction (XRD) was put to investigate the crystallographic textures among the base metal, heat affected zone and fusion zone. Particular attention was focused on the determination of microtexture in HED welds by using electron backscatter diffraction (EBSD) technique. After that, an effort was put to compare the results by both of X-ray macro-texture and EBSD-microtexture. The recorded micrographs illustrates that the HED welds are mainly composed of d-ferrite grained structure, which is further decorated with allotriomorphic and Widmanst&#x00E4;tten austenite (g) at grain boundaries. With preheating treatment, the volume fraction of austenite in LB weld is gradually increased, and then leading to a completely different morphology. An apparent amount of transformation twins are found in g phase under TEM observations. No matter that they are Widmanst&#x00E4;tten austenite in nonpreheated welds or blocky austenite in preheated welds, all of the transformation twins have the same {111} twin boundary. Furthermore, modulated fringes composed of ferrite, secondary austenite and amorphous phase are also found in the nonpreheated LB weld. It is ascribed to the rapid cooling effect occurred in the nonpreheated LB weld. Two chromium nitrides (CrN and Cr2N) are also identified and attributed to their different driving forces. A remarkable texture gradient is found in the base metal along the thickness direction for both of austenite and ferrite phases in 2205 duplex stainless steel. The texture is governed separately by the {001}//ND-fibre, a-fibre, Goss and rotated cube components. Despite the analogous local texture evolutions revealing in both LB and EB welds, the global solidification textures in the two processes are considerably different. For which, the texture of LB weld is predominantly evolved with the Goss component. However, the texture of EB weld is mainly composed of the pronounced cube {001}<100>, while the Goss {011}<100> and rotated cube {001}<110> are weakened. The microtexture analysis shows that the centre region of the weld is dominated by oriented nucleation mechanism. Whereas, regions near the fusion boundaries are governed by oriented growth mechanism. The texture feature from EBSD does consist well with the XRD measured result. Moreover, the measurement of local texture from EB weld clearly indicates that a high percentage of high angle grain boundaries distributed in the crown. By contrary, a high percentage of low angle grain boundaries distributed in the root. Both of them again reflect the cooling effect of weld on the solidification mechanism. Throughout this study, the key factors to be responsible for the evolution of solidification texture of HED welded DSS are summarized. Those are thermal conductivity of the weld, turbulent flow in the molten pool, parent textures and the orientation relationship between ferrite and austenite.

La craie est définie comme étant une roche carbonatée microporeuse. Cette formation est largement exploitée en Mer du Nord pour ses hydrocarbures et constitue un aquifère dans le Bassin de Paris. Les propriétés réservoirs de la Craie (propriétés matricielles) varient considérablement comme Alam et al. (2011) le soulignent pour les craies de surface et de subsurface de Mer du Nord, avec des porosités de 4 à 52 %, des perméabilités de 0,01 à 100 mD et des vitesses des ondes P sur roche saturée de 2,4 à 4,4 km.s-1.Dans le secteur d'étude (Normandie, France), pris comme analogue de terrain, 114 échantillons (Cénomanien- Santonien) ont été prélevés dans le but d'illustrer l'hétérogénéité sédimentaire et pétrophysique de la Craie. Comme en Mer du Nord, les échantillons présentent une grande variabilité des propriétés pétrophysiques : porosités () de 6,1 à 46,5 %, perméabilités matricielles (K) très faibles (0,002 mD) jusqu’à des perméabilités atypiques et très fortes (470 mD, en l’absence de fractures) et des vitesses des ondes P sur échantillon saturé s'étalant selon une gamme très étendue (1,8 à 5,5 km.s-1). Cependant, l’origine de ces hétérogénéités est encore mal comprise. L'objectif de cette étude est donc de comprendre l’influence respective des facteurs contrôlant les propriétés pétrophysiques afin d'optimiser la modélisation de ce type de réservoir.Trois modèles sédimentaires ont ici été définis avec :(1) un modèle de rampes, subdivisé en modèle de rampe argileuse avec des porosités de 34,4 à 46,5 % et des valeurs de perméabilité de 0,02 à 3 mD, et en modèle de rampe carbonatée (mudstone à grainstone) avec des porosités de 26,1 à 46,5 % et des valeurs de perméabilité de 0,04 à 6 mD,(2) un modèle de contourite (mudstone à grainstone et micro-packstone) avec des porosités de 8,3 à 45,5 % et des valeurs de perméabilité de 0,05 à 477 mD,(3) un modèle de surface de hiatus (Soupground à Hardground) avec des porosités de 6 à 36,9 % et des valeurs de perméabilité de 0,002 à 36 mD.Une classification des microtextures, basée sur l’observation au MEB de quatre critères (contenu minéralogique, fraction biogénique, fraction micritique et fraction de ciment), est proposée. À partir de ces critères, deux groupes majeurs ont été définis avec les Pure chalk microtextures et Impure chalk microtextures. Le groupe des Pure chalk microtextures reflète l’intensité des modifications subies par la craie lors de la diagenèse (taux de diagenèse qu’elle soit précoce ou tardive). Une augmentation du taux de diagenèse induit une diminution de la porosité et une augmentation des vitesses de propagation des ondes acoustiques P. En effet, les transformations qui s’opèrent au cours de la diagenèse, d’une part, réduisent la taille des espaces intergranulaires et donc font diminuer la porosité, et d’autre part, renforcent les contacts entre grains, favorisant ainsi la propagation des ondes acoustiques. Pour le groupe des Impure chalk microtextures, la présence de particules insolubles dans la matrice n’affecte pas la porosité, mais diminue la perméabilité du fait de la réduction des tailles d’accès aux pores.Par conséquent, l’héritage sédimentaire et les transformations diagénétiques, qui affectent à différents degrés les faciès sédimentaires primaires, déterminent les propriétés réservoirs et sont donc la cause de la grande variabilité de ces dernières. De plus, la répartition spatiale de ces microtextures, dépendante des conditions de dépôt (e.g. climat, distance des côtes), et des modifications diagénétiques (précoces ou tardives), n’est pas aléatoire. À partir de l’extrapolation combinée des faciès et de l’empreinte diagénétique, il serait ainsi possible de visualiser la distribution des propriétés pétrophysiques sur les falaises, et donc de visualiser l'architecture des réservoirs dans la Craie. / Chalk is defined as a microporous reservoir rock. This formation is a prolific hydrocarbon-bearing reservoir in the North Sea and is one of the main aquifers in the Paris Basin. The heterogeneity of chalk in terms of petrophysical properties (both surface and subsurface) is illustrated by porosity ranging from 4 to 52 %, permeability from 0.01 to 100 mD, and P-wave velocity on water-saturated samples from 2.4 to 4.4 km.s-1 (Alam et al., 2011).In the study area (Normandie, France), taken as an outcrop analogue, 114 samples were collected (Cenomanian – Santonian). As in the North Sea fields, these samples show great petrophysical heterogeneity: total porosity () from 6.1 to 46.5 %, very low permeability (K; 0.002 mD) to atypical high permeability (477 mD; without fractures), and P-wave velocity on water-saturated samples ranging from 1.8 to 5.5 km.s-1. However, the origin(s) of this large variation in petrophysical parameters is poorly understood. Three sedimentary models are defined here for the chalk:(1) Ramp models, subdivided into argillaceous ramp model, with porosity from 34,4 to 46.5%, and permeability from 0.02 to 3 mD, and carbonate ramp model (mudstone to packstone), with porosity from 26.1 to 46.5%, and permeability from 0.04 to 6 mD,(2) Contourite model (mudstone to grainstone and micro-packstone), with porosity from 8.3 to 45.5%, and permeability from 0.05 to 477 mD,(3) Softground to Hardground model, with porosity from 6 to 36.9%, and permeability from 0.002 to 36 mD.Each model has specific distribution in the porosity-permeability plot.A microtexture classification of the chalk is proposed, based on SEM observation of four groups of criteria (mineralogical content, biogenic fraction, micritic fraction and cement fraction). From these criteria, two major groups are defined: Pure chalk microtexture and Impure chalk microtexture. The Pure chalk microtexture group reflects the intensity of chalk modification during diagenesis (rate of diagenesis, whether early stage or not). An increase in the diagenetic rate induces a decrease in porosity and an increase in P-wave velocity. Diagenetic transformation induces a decrease in pore-space size, with better grain contact, explaining the decrease in porosity and the improved propagation of acoustic P-wave velocity. For Impure chalk microtexture group, the presence of insoluble particles in the matrix does not affect porosity but decreases permeability, due to the reduction of pore-throat size.The complex relationships between depositional inheritance and diagenetic transformation lead to variability in chalk petrophysical parameters. Spatio-temporal distribution of depositional facies and associated diagenetic transformation is not random; it depends on sedimentological condition (e.g. climate and distance to shore) and imprint of diagenetic processes (early or late stage). By extrapolating from the combined data on facies and diagenesis, the petrophysical properties of the entire cliff section can be characterised, and used to describe the reservoir architecture of the Chalk.

Microtextures recorded on quartz sand grain surfaces provide evidence of past environment. Environmental processes, such as transport by glacial ice, create unique microtextures on sand grain surfaces that can be observed under high magnification with a scanning electron microscope. These microtextures and their proportions tend to be unique to environment type, allowing investigators to infer the environmental conditions to which sediments have been exposed, for example to distinguish sediments from fluvial versus mass-wasted environments. Microtextural evidence also allows inferences about the history of sediments of unknown origin. This thesis determines the qualitative and quantitative microtextural fingerprint of glacigenic quartz sand grains deposited by small tropical alpine glaciers in Costa Rica, and compares that fingerprint to the fingerprints of highland Dominican Republic sediments of uncertain genesis, to gauge whether those, individually or grouped, resemble the Costa Rican glacigenic samples. I selected 18 samples (9 each from Costa Rica and the Dominican Republic) and analyzed a minimum of 100 quartz sand grains per sample using a scanning electron microscope. My sample sizes were dictated by the scale of empirical 99% confidence intervals that would allow meaningful comparison of samples. Analysis using literature-recommended numbers of quartz sand grains would entail such large confidence intervals that practically any results would have been indistinguishable. I recorded the presence or absence of 25 microtextures on each grain, and calculated the percentage of each microtexture’s occurrence in the sample. The percentages constituted the sample’s microtextural fingerprint. As a whole, the Costa Rican fingerprints were very similar to each other, and so were the Dominican Republic fingerprints. Further comparison led me to conclude that the Dominican Republic samples are statistically indistinguishable from the Costa Rican glacierized samples. This thesis is part of a larger project establishing protocols for distinguishing glacigenic from non-glacigenic sediments, and testing for glacigenicity of sediments in Costa Rica, the Dominican Republic, and elsewhere. My results can be applied in other studies distinguishing tropical highland glacigenic and non-glacial samples. My contribution will hopefully contribute toward completion of the project’s goals, specifically determining the presence or absence of past glaciers in the Dominican Republic.

Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico / Uma dificuldade que acomete as empresas de construÃÃo pesada em relaÃÃo à seguranÃa viÃria à atingir valores mÃnimos de aderÃncia exigidos em campo para o revestimento de pavimentos. Valores mÃnimos de microtextura, ensaiados atravÃs do pÃndulo britÃnico, e faixas de macrotextura, ensaiadas pelo ensaio de mancha de areia, sÃo encontrados no Manual de RestauraÃÃo de Pavimentos AsfÃlticos do DNIT de 2006. Nas situaÃÃes onde esses parÃmetros ligados à aderÃncia sÃo controlados, o revestimento precisa ser reexecutado quando a micro e a macrotextura nÃo se aproximam do exigido pelas normas. Trata-se de um problema apenas observado durante a fase de construÃÃo, uma vez que nÃo se determina a aderÃncia em laboratÃrio, na fase de projeto. Pesquisas apontam que as mudanÃas nas propriedades dos agregados e na granulometria podem afetar a micro e a macrotextura da camada de rolamento. A fim de contribuir na questÃo da aderÃncia, buscando a previsÃo desse parÃmetro ainda indiretamente em laboratÃrio, objetivou-se desenvolver uma metodologia capaz de testar granulometrias para verificar o efeito das fraÃÃes dos materiais das peneiras nesta aderÃncia da superfÃcie do pavimento. A metodologia proposta consistiu em comparar a textura da massa asfÃltica compactada em campo e em laboratÃrio utilizando os ensaios de mancha de areia e de pÃndulo britÃnico. Objetivou-se, ainda, desenvolver um modelo capaz de predizer o valor de macrotextura da camada de rolamento atravÃs de granulometrias das misturas asfÃlticas estudadas. O modelo foi composto por dados de fraÃÃes retidas entre as peneiras nÂ40 e 3/8â. Os principais resultados obtidos levaram à conclusÃo de que a metodologia desenvolvida em laboratÃrio foi consistente no aspecto de microtextura entre campo e laboratÃrio. Em relaÃÃo ao modelo, houve uma correlaÃÃo considerada satisfatÃria, portanto, indicando o potencial da previsÃo da macrotextura ainda na fase de projeto a partir da granulometria a adotar. / A difficulty that affects pavement contractors regarding road safety is to achieve minimum values of surface friction required to the pavement in the field. Minimum values of microtexture tested through the British pendulum and ranges of macrotexture tested by the sand patch test are found in the DNIT Manual of Asphalt Pavements Restoration (2006). In situations where the friction parameters are controlled, oftentimes the pavement needs to be reexecuted when the micro and macrotexture do not meet the required values. This is a problem only observed during the construction phase as friction is not determined indirectly in the laboratory during the design phase. Research indicates that changes in the properties of the aggregates and the particle size can affect the microtexture and macrotexture of the surface course. In order to contribute to the topic of friction, seeking the prediction of this parameter in the laboratory, this work aimed to develop a methodology capable of evaluating gradations and the effect of the sieve fractions of materials in the of pavement surface friction. The proposed methodology consisted in comparing the texture of the asphalt mixture compacted in laboratory, and field tests using sand patch and British pendulum. It also aimed to develop a model to predict the value of macrotexture of the surface course through the gradation of the asphalt mixtures studied. The model was composed by data of retained fractions in sieve #40 to 3/8". The main results obtained led to the conclusion that the methodology developed in the laboratory was consistent in the aspect of microtexture between field and laboratory. Regarding the model, there was a satisfactory correlation, indicating the potential of predicting macrotexture in the design phase from the mixture gradation.

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Yes / Inspired from the low wetting properties of Lotus leaves, the fabrication of dual micro/nano-scale topographies is of interest to many applications. In this research, superhydrophobic surfaces are fabricated by a process chain combining ultrashort pulsed laser texturing of steel inserts and injection moulding to produce textured polypropylene parts. This manufacturing route is very promising and could be economically viable for mass production of polymeric parts with superhydrophobic properties. However, surface damages, such as wear and abrasion phenomena, can be detrimental to the attractive wetting properties of replicated textured surfaces. Therefore, the final product lifespan is investigated by employing mechanical cleaning of textured polypropylene surfaces with multipurpose cloths following the ASTM D3450 standard. Secondly, the surface damage of replication masters after 350 injection moulding cycles with glass-fiber reinforced polypropylene, especially to intensify mould wear, was investigated. In both cases, the degradation of the dual-scale surface textures had a clear impact on surface topography of the replicas and thus on their wetting properties, too. / Europe Union H2020 research and innovation programme.