Root-zone soil moisture (RZSM) is an important variable when forecasting plant growth, determining water availability during drought, and understanding evapotranspiration as a flux. However, current methods indirectly estimate RZSM using data assimilation, which requires time-series data to make model-based predictions. This is because direct measurement requires a lower frequency signal, typically P-band and below (<500MHz), to reach root zone depths and, in turn, necessitates a larger antenna to be deployed in space, which is often unfeasible. A new remote sensing technique known as Signals of Opportunity (SoOp) reutilizes transmitted communication signals to perform microwave remote sensing. This means that SoOp platforms need not include a transmitter, but rather rely on passive radar technology to make measurements. This thesis details the development of a UAS-based P-band SoOp receiver instrument. This platform will be used to progress the state-of-art in techniques for direct measurement of RZSM.

No description available.

Evapotranspiration (ET) is a significant hydrological process. It can be studied and estimated using remote sensing based methods at multiple spatial and temporal scales. Most commonly and widely used remote sensing based methods to estimate actual evapotranspiration (AET) are a) methods based on energy balance equations, b) vegetation coefficient based method and c) contextual methods. These three methods require reflectance and land surface temperature (LST) data measured at optical and thermal portion of the electromagnetic spectrum. However, these data are available only for clear sky conditions and fail to be retrieved under overcast conditions creating gaps in the data, which result in discontinuous of AET product. Moreover, energy balance equation based methods and evaporative fraction (EF) based contextual methods are difficult to apply over overcast conditions. In this context, vegetation coefficient based (Tasumi et al., 2005; Allen et al., 2005) and microwave remote sensing based methods can be applied under cloudy sky conditions (Sun et al., 2012), since microwave radiations can penetrate through clouds, but these data are available at coarse resolution. In the vegetation coefficient method temporal upscaling can be avoided. Therefore in this research vegetation coefficient based method is employed over Cauvery basin to estimate daily AET for clear and cloudy sky conditions. Required critical variables for this method such as reference evapotranspiration (ETo) and vegetation coefficients are obtained using LST and optical vegetation indices for all sky conditions. In this study, all sky conditions refer to both clear and cloudy sky conditions. Most important variable for estimation of ETo using radiation and temperature based models is air temperature (Ta). In this study, for better accuracy of Ta, two satellite based approaches namely, Temperature Vegetation Index (TVX) and Advance Statistical Approaches (ASA) were evaluated. In the TVX approach, in addition to traditional Normalized Difference Vegetation Index (NDVI), other vegetation indices such as Enhanced Vegetation Index (EVI) and Global Vegetation Moisture Index (GVMI) were also examined. In case of ASA, bootstrap technique was used to generate calibration and validation samples and Levenberg Marquardt algorithm was used to find the solution of the models. The better of the Ta results obtained out of these two approaches were employed in the ETo models and are referred as Ta based ETo models. Instead of Ta, processed LST data obtained directly from the satellite (Aqua/Moderate Resolution Imaging Spectroradiometer (MODIS)) was applied in the ETo models and these are referred as LST based ETo models. These Ta and LST based Hargreaves-Samani (H-S), Makkink (Makk) and Penman Monteith Temperature (PMT) models were evaluated by comparing with the FAO56 PM model. Additionally, simple LST based equation (SLBE) proposed by Rivas et al. (2004) was also examined. Required solar radiation (Rs) data for ETo estimation was obtained from Kalpana1/VHRR satellite data. Results implied that, Ta based PMT model performed better than the Ta based H-S, Makk and SLBE with less RMSE, MAPE and MBE values for all land cover classes and for various climatic regions for clear sky conditions. LST based H-S, PMT, Makk and Ta based Makkink advection models predominantly overestimated ETo for the study region. In the case of TVX approach, to estimate maximum Ta (Tmax), GVMI performed better than NDVI and EVI. Nevertheless, TVX approach poorly estimated Tmax in comparison with statistical approach. ASA performed better for both Tmax and minimum Ta. This study demonstrates the applicability of satellite based Ta and ETo models by considering very few variables for clear sky conditions. Spatially distributed vegetation coefficients (Kv) data with high temporal resolution is another important variable in vegetation coefficient method for daily AET estimation and also it is in demand for crop condition assessment, irrigation scheduling, etc. But available Kv models application hinders because of two main reasons i.e 1) Spectral reflectance based Kv accounts only for transpiration factor but not evaporation, which fails to account for total AET. 2) Required optical spectral reflectances are available only during clear sky conditions, which creates gaps in the Kv data. Hence there is a necessity of a model which accounts for both transpiration and evaporation factors and also gap filling method, which produces accurate continuous quantification of Kv values. Therefore, different combinations of EVI, GVMI and temperature vegetation dryness index (TVDI) have been employed in linear and non linear regression techniques to obtain best model. This best Kv model had been compared with Guershman et al. (2009) Kv model. To fill the gaps in the data, initially, temporal fitting of Kv values have been examined using Savitsky-Goley (SG) filter for three years of data (2012 to 2014), but this fails when sufficient high quality Kv values were unavailable. In this regard, three gap filling techniques namely regression, Artificial Neural Networks (ANNs) and interpolation techniques have been analyzed. Microwave polarization difference index (MPDI) has been employed in ANN technique to estimate Kv values under cloudy sky conditions. The results revealed that the combination of GVMI and TVDI using linear regression technique performed better than other combinations and also yielded better results than Guershman et al. (2009) Kv model. Furthermore, the results indicated that SG filter can be used for temporal fitting and for filling the gaps, regression technique can be used as it performed better than other techniques for Berambadi station. Land Surface Temperature (LST) with high spatiotemporal resolution is required in the estimation of ETo to obtain AET. MODIS is one of the most commonly used sensors owing to its high spatial and temporal availability over the globe, but is incapable of providing LST data under cloudy conditions, resulting in gaps in the data. In contrast, microwave measurements have a capability to penetrate under clouds. The current study proposes a methodology by exploring this property to predict high spatiotemporal resolution LST under cloudy conditions during daytime and night time without employing in-situ LST measurements. To achieve this, ANN based models were employed for different land cover classes, utilizing MPDI at finer resolution with ancillary data. MPDI was derived using resampled (from 0.250 to 1 km) brightness temperatures (Tb) at 36.5 GHz channel of dual polarization from Advance Microwave Scanning Radiometer (AMSR)-Earth Observing System and AMSR2 sensors. The proposed methodology was quantitatively evaluated through three performance measures namely correlation coefficient (r), Nash Sutcliffe Efficiency (NSE) and Root Mean Square Error (RMSE). Results revealed that during daytime, AMSR-E(AMSR2) derived LST under clear sky conditions corresponds well with MODIS LST resulting in values of r ranging from 0.76(0.78) to 0.90(0.96), RMSE from 1.76(1.86) K to 4.34(4.00) K and NSE from 0.58(0.61) to 0.81(0.90) for different land cover classes. For night time, r values ranged from 0.76(0.56) to 0.87(0.90), RMSE from 1.71(1.70) K to 2.43(2.12) K and NSE from 0.43 (0.28) to 0.80(0.81) for different land cover classes. RMSE values found between predicted LST and MODIS LST during daytime under clear sky conditions were within acceptable limits. Under cloudy conditions, results of microwave derived LST were evaluated with Ta which indicated that the approach performed well with RMSE values lesser than the results obtained under clear sky conditions for land cover classes for both day and nighttimes. These predicted LSTs can be applied for the estimation of soil moisture in hydrological studies, in climate studies, ecology, urban climate and environmental studies, etc. AET was estimated for all sky conditions using vegetation coefficient method. Essential parameter ETo under cloudy conditions was estimated using LST and Ta based PMT and H-S models and required solar radiation (Rs) in these two models estimated using equation proposed by Samani (2000). In this equation it was found that the differences between LSTmax or Tmax and LSTmin or Tmin could able to capture the variations due to cloudy sky conditions and hence can be used for estimating ETo under cloudy sky conditions. Results revealed that the estimated Rs correlated well with observed Rs for Berambadi station under cloudy conditions for the year 2013. PMT based ETo values were corresponded with observed ETo under cloudy sky condition. The difference between LST and Ta was less during cloudy conditions, therefore LST or Ta can be used as the only input in temperature based PMT model to estimate ETo. AET estimated correlated well with the observed AET values for clear and cloudy sky conditions. In addition, AET estimated using vegetation coefficient method was compared with two source energy balance (TSEB) method developed by Nishida et al. (2003) under clear sky conditions. It was found that the improved vegetation coefficient method performed better than the TSEB method for Berambadi station. Other microwave vegetation indices such as Microwave Vegetation Indices (MVIs) and Emissivity Difference Vegetation Index (EDVI) are available in literature. Therefore in this study, MVIs are used to predict LST under cloudy conditions using proposed methodology to check whether the MVIs could yield better LST values. Results showed that MPDI performed better than MVIs to predict LST under cloudy sky conditions. Furthermore, MPDI obtained using dual polarizations of 37 GHz channel Tb has advantage of having fine spatial resolution compared to MVIs, as it requires Tb of 19 GHz in addition to Tb of 37 GHz channel which is of coarse resolution and therefore uncertainties resulting from re-sampling technique can be minimized. x

Oceanic microwave remote sensing provides the data necessary for the estimation of significant geophysical parameters such as the near-surface vector wind. To obtain accurate estimates, a precise understanding of the measurements is critical. This work clarifies and quantifies specific uncertainties in the scattered power measured by an active radar instrument. While there are many sources of uncertainty in remote sensing measurements, this work concentrates on three significant, yet largely unstudied effects. With a theoretical derivation of the backscatter from an ocean-like surface, results from this dissertation demonstrate that the backscatter decays with surface roughness with two distinct modes of behavior, affected by the size of the footprint. A technique is developed and scatterometer data analyzed to quantify the variability of spaceborne backscatter measurements for given wind conditions; the impact on wind retrieval is described in terms of bias and the Cramer-Rao lower bound. The probability density function of modified periodogram averages (a spectral estimation technique) is derived in generality and for the specific case of power estimates made by the NASA scatterometer. The impact on wind retrieval is quantified.

The Ku band microwave remote sensor, SeaWinds, was developed at the National Aeronautics and Space Administration (NASA) Jet Propulsion Laboratory (JPL). Two identical SeaWinds instruments were launched into space. The first was flown onboard NASA QuikSCAT satellite which has been orbiting the Earth since June 1999, and the second instrument flew onboard the Japanese Advanced Earth Observing Satellite II (ADEOS-II) from December 2002 till October 2003 when an irrecoverable solar panel failure caused a premature end to the ADEOS-II satellite mission. SeaWinds operates at a frequency of 13.4 GHz, and was originally designed to measure the speed and direction of the ocean surface wind vector by relating the normalized radar backscatter measurements to the near surface wind vector through a geophysical model function (GMF). In addition to the backscatter measurement capability, SeaWinds simultaneously measures the polarized radiometric emission from the surface and atmosphere, utilizing a ground signal processing algorithm known as the QuikSCAT / SeaWinds Radiometer (QRad / SRad). This dissertation presents the development and validation of a mathematical inversion algorithm that combines the simultaneous active radar backscatter and the passive microwave brightness temperatures observed by the SeaWinds sensor to retrieve the oceanic rainfall. The retrieval algorithm is statistically based, and has been developed using collocated measurements from SeaWinds, the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) rain rates, and Numerical Weather Prediction (NWP) wind fields from the National Centers for Environmental Prediction (NCEP). The oceanic rain is retrieved on a spacecraft wind vector cell (WVC) measurement grid that has a spatial resolution of 25 km. To evaluate the accuracy of the retrievals, examples of the passive-only, as well as the combined active / passive rain estimates from SeaWinds are presented, and comparisons are made with the standard TRMM rain data products. Results demonstrate that SeaWinds rain measurements are in good agreement with the independent microwave rain observations obtained from TMI. Further, by applying a threshold on the retrieved rain rates, SeaWinds rain estimates can be utilized as a rain flag. In order to evaluate the performance of the SeaWinds flag, comparisons are made with the Impact based Multidimensional Histogram (IMUDH) rain flag developed by JPL. Results emphasize the powerful rain detection capabilities of the SeaWinds retrieval algorithm. Due to its broad swath coverage, SeaWinds affords additional independent sampling of the oceanic rainfall, which may contribute to the future NASA's Precipitation Measurement Mission (PMM) objectives of improving the global sampling of oceanic rain within 3 hour windows. Also, since SeaWinds is the only sensor onboard QuikSCAT, the SeaWinds rain estimates can be used to improve the flagging of rain-contaminated oceanic wind vector retrievals. The passive-only rainfall retrieval algorithm (QRad / SRad) has been implemented by JPL as part of the level 2B (L2B) science data product, and can be obtained from the Physical Oceanography Distributed Data Archive (PO.DAAC).

A better understanding of the water and energy cycles at climate scale in the Third Pole Environment is essential for assessing and understanding the causes of changes in the cryosphere and hydrosphere in relation to changes of plateau atmosphere in the Asian monsoon system and for predicting the possible changes in water resources in South and East Asia. This paper reports the following results: (1) A platform of in situ observation stations is briefly described for quantifying the interactions in hydrosphere-pedosphere-atmosphere-cryosphere-biosphere over the Tibetan Plateau. (2) A multiyear in situ L-Band microwave radiometry of land surface processes is used to develop a new microwave radiative transfer modeling system. This new system improves the modeling of brightness temperature in both horizontal and vertical polarization. (3) A multiyear (2001–2018) monthly terrestrial actual evapotranspiration and its spatial distribution on the Tibetan Plateau is generated using the surface energy balance system (SEBS) forced by a combination of meteorological and satellite data. (4) A comparison of four large scale soil moisture products to in situ measurements is presented. (5) The trajectory of water vapor transport in the canyon area of Southeast Tibet in different seasons is analyzed, and (6) the vertical water vapor exchange between the upper troposphere and the lower stratosphere in different seasons is presented.

Good estimates of soil hydraulic parameters and their distribution in a catchment is essential for crop and hydrological models. Measurements of soil properties by experimental methods are expensive and often time consuming, and in order to account for spatial variability of these parameters in the catchment, it becomes necessary to conduct large number of measurements. Estimation of soil parameters by inverse modelling using observations on either surface soil moisture or crop variables has been successfully attempted in many studies, but difficulties to estimate root zone properties arise for heterogeneous layered soils. Although extensive soil data is becoming more and more available at various scales in the form of digital soil maps there is still a large gap between this available information and the input parameters needed for hydrological models. Inverse modeling has been extensively used but the spatial variability of the parameters and insufficient data sets restrict its applicability at the catchment scale. Use of remote sensed soil moisture data to estimate soil properties using the inverse modeling approach received attention in recent years but yielded only an estimate of the surface soil properties. However, in multilayered and heterogeneous soil systems the estimation of soil properties of different layers yielded poor results due to uncertainties in simulating root zone soil moisture from remote sensed surface soil moisture. Surface soil properties can be estimated by inverse approach using surface soil moisture data retrieved from remote sensing data. Since soil moisture retrieved from remote sensing is representative of the top 5 cm only, inversion of models using surface soil moisture cannot give good estimates of soil properties of deeper layers. Crop variables like biomass and leaf area index are sensitive to the deeper layer soil properties. The main focus of this study is to develop a methodology of estimation of root zone soil hydraulic properties in heterogeneous soils by crop model based inversion techniques. Further the usefulness of the radar soil moisture and leaf area index in retrieving soil hydraulic properties using the develop approach is be tested in different soil and crop combinations. A brief introduction about the soil hydraulic properties and their importance in agro-hydrological model is discussed in Chapter 1. Soil water retention parameters are explained in detail in this chapter. A detailed review of the literature is presented in chapter 2 to establish the state of art on the following: (i) estimation of soil hydraulic properties, (ii) role of crop models in estimating soil hydraulic properties, (iii) retrieval of surface soil moisture using water cloud model from SAR data, (iv) retrieval of leaf area index from SAR (synthetic aperture radar) data and (v) modeling of root zone soil moisture and potential recharge. The thesis proposes a methodology for estimating the root zone soil hydraulic properties viz. field capacity, wilting point and soil thickness. To test the methodology developed in this thesis for estimating the soil hydraulic properties and their uncertainty, three synthetic experiments were conducted by inversion of STICS (Simulateur mulTIdiscplinaire pour les Cultures Standard) model for maize crop using the GLUE (Generalized Likelihood Uncertainty Estimation) approach. The estimability of soil hydraulic properties in a layer-wise heterogeneous soil was examined with several sets of likelihood combinations, using leaf area index, surface soil moisture and above ground biomass. The robustness of the approach is tested with parameter estimation (model inversion) in two different meteorological conditions. The details of the numerical experiments and the several likelihood and meteorological cases examined are given in Chapter 3. The likelihood combination of leaf area index and surface soil moisture provided consistently good estimates of soil hydraulic properties for all soil types and different meteorological cases. Relatively wet year provided better estimates of soil hydraulic properties as compared with a dry year. To validate the approach of estimating root zone soil properties and to test the applicability of the approach in several crops and soil types, field measurements were carried out in the Berambadi experimental watershed located in the Kabini river basin in south India. The profile soil measurements were made for every 10 cm upto 1 m depth. Maize, Marigold, Sunflower, Sorghum and Turmeric crops were monitored during the four year period from 2010 to 2013. Crop growth parameters viz. leaf area index, above ground biomass, yield, phenological stages and crop management activities were measured/monitored at 10 day frequency for all the five crops in the study area. The details of the field experiments performed, the data collected and the results of the model inversion using the ground measured data are given in Chapter 4. The likelihood combination of leaf area index and surface soil moisture provided consistently lower root mean square error (1.45 to 2.63 g/g) and uncertainty in the estimation of soil hydraulic properties for all soil crop and meteorological cases. The uncertainty in the estimation of soil hydraulic properties was lower in the likelihood combination of leaf area index and soil moisture. Estimability of depth of root zone showed sensitivity to the rooting depth. Estimating root zone soil properties at field plot scale using SAR data (incidence angle 24o, wave length 5.3 GHz) of RADARSAT-2 is presented in the Chapter 5. In the first step, an approach of estimating leaf area index from radar vegetation index using the parametric growth curve of leaf area index and the retrieval of soil moisture using water cloud model are given in Chapter 5. The parameters of the growth curve and the leaf area index are generated using a time series of RADARSAT-2 for two years 2010-2011 and 2011-12 for the crops (maize, marigold, sunflower, sorghum and turmeric) considered in this study. The surface soil moisture is retrieved using the water cloud model, which is calibrated using the ground measured values of leaf area index and surface soil moisture for different soils and crops in the study area. The calibration and validation of LAI and water cloud models are discussed in this Chapter. Eventually, the retrieved leaf area index and surface soil moisture from RADARSAT-2 data were used to estimate the soil hydraulic properties and their uncertainty in a similar manner as discussed in Chapter 4 for various crop and soil plots and the results are presented in Chapter 5. The mean and uncertainty in the estimation of soil hydraulic properties using inversion of remote sensing data provided results similar to the estimates from inversion of ground data. The estimates of soil hydraulic properties compared well (R2 of 0.7 to 0.80 and RMSE of 2.1 to 3.16 g/g) with the physically measured vales of the parameters. In Chapter 6, root zone soil moisture and potential recharge are modelled using the STICS model and the soil hydraulic parameters estimated using the RADARSAT-2 data. The potential recharge is highly sensitive to the water holding capacity of rooting zone. Variability in the root zone soil moisture for wet and dry years for different soil types on irrigated and non-irrigated crops were investigated. Potential recharge from different crop and soil types were compared. The uncertainty in the estimation of potential recharge due to uncertainty in the estimation of field capacity is quantified. The root zone soil moisture modeled by STICS showed good agreement with the measured root zone soil moisture in all crop and soil cases. This was tested for both dry and wet year and provides similar results. The temporal variability of root zone soil moisture was also modeled well by the STICS model; the model also predicted well the intra-soil variability of soil moisture of root zone. The results of the modeling of root zone soil moisture and potential recharge are presented in Chapter 6. At the end, in Chapter 7, the major conclusions drawn from the various chapters are summarized.

The knowledge of soil moisture is of pronounced importance in various applications e.g. flood control, agricultural production and effective water resources management. These applications require the knowledge of spatial and temporal variation of the soil moisture in the watershed. There are three approaches of estimating/measuring soil moisture namely,(i) in-situ measurements,(ii) remote sensing, and(iii) hydrological modelling. The in situ techniques of measurement provide relatively accurate information at point scale but are not feasible to gather in large numbers relevant for a watershed. The soil moisture can be simulated by hydrological models at the desired spatial and temporal resolution, but these simulations would often be affected by the uncertainties in the model physics, parameters, forcing, initial and boundary conditions. The remote sensing provides an alternative to retrieve the soil moisture of the surface (top few centimeters ) layer, but even this data is limited by the spatial or temporal resolution, which is satellite dependant. Hydrological models could be improved by assimilating remotely sensed soil moisture, which requires a retrieval algorithm. In order to develop a retrieval algorithm the satellite data need to be calibrated/validated with the in-situ ground measurements. The retrieval of surface soil moisture from microwave remote sensing is sensitive to surface conditions, and hence requires calibration/validation specific to a site/region. The improvement in the hydrological variables/fluxes is sensitive to the framework adopted during the assimilation of remotely sensed data. The main focus of the study was to assess the retrieval algorithm for the surface soil moisture from both active (ENVISAT,RADARSAT-2)and passive(AMSR-E) microwave satellites in a semi-arid tropical watershed of South India. Further, the usefulness of these retrieved remotely sensed products for the estimation of recharge was investigated by developing a coupled hydrological model and an assimilation framework. A brief introduction was made in Chapter 1 on the importance of surface soil moisture and evapotranspiration in hydrology, and the feasible options available for the retrieval from microwave remote sensing. A detailed review of the literature is presented in Chapter 2 to establish the state-of-the-art on the following:(i) retrieval algorithms for the surface soil moisture from active and passive microwave remote sensing,(ii) estimation of actual evapotranspiration from optical remote sensing(MODIS),(iii) coupled surface-ground water hydrological models,(iv) estimation of soil hydraulic properties with their uncertainties, and(v) assimilation framework specific to hydrological modelling. To calibrate/validate the retrieval algorithms and to test the coupled model and the assimilation framework developed, field measurements were carried out in the BerambadI experimental watershed located in the Kabini river basin. The surface soil moisture in 50 field plots, profile soil moisture up to 1m depth in 20 field plots, and ground water level in 200 bore wells were measured. Twelve images of ENVISAT, seven teen images of RADARSAT-2, along with AMSR-E and MODIS data were used. These data pertained to different durations during the period 2008 to 2011,the details of which are given in Chapter 3. The approach for the retrieval of surface soil moisture and the associated uncertainty from active and passive microwave remote sensing is given in Chapter 4. Surface soil moisture was retrieved for six vegetation classes using the linear regression model and copulas. Three types of copulas(Clayton, Frank and Gumbel) were investigated. It was found that the ensemble mean simulated using the linear regression model and three copulas was nearly same. The copulas were found to be superior than the linear regression model when comparing the distributions of the mean of the generated ensemble. Among the copulas it was observed that the Clayton copula performed better in the lower and middle ranges of backscatter coefficient, while the Gumbel and Frank copulas were found to be superior in the upper ranges of backscatter coefficients. The range of RMSE was approximatively 4cm3cm−3 indicating that the retrieval from ENVISAT/RADARSAT-2 was good. ACDF based approach was proposed to retrieve the surface soil moisture map for the watershed with a spatial resolution of 100m x 100m ( i.e one hectare). The map of the uncertainty in the retrieved surface soil moisture was also prepared using the Clayton copula. The AMSR-E surface soil moisture product was calibrated for the watershed during the period 2008 to 2011, using the map generated from the ENVISAT/RADARSAT data. They Clayton copula was used to generate the ensemble of the corrected AMSR-E surface soil moisture. The standard deviation of the generated ensemble varied from 0.01 to 0.03cm3cm−3 ,hence the derived surface soil moisture product for Berambadi was found to be good. In the Chapter 5, a one dimensional soil moisture model was developed based on the numerical solution of the Richards’ equation using finite difference method and inverse modeling was carried out using the Generalized Likelihood Uncertainty Estimation(GLUE) approach for estimating the soil hydraulic parameters of the van Genuchten(VG) model and their uncertainty. The parameters were estimated from the two field sites(Berambadi and Wailapally watershed in South India) and from laboratory evaporation experiment for the Wailapally site. It was found that the GLUE approach was able to provide good uncertainty bounds for the soil hydraulic parameters. The uncertainty in the estimates from the field experiment was found to be higher than from the laboratory evaporation experiment for both water retention and hydraulic conductivity curves. The saturated soil moisture(θs )and shape parameter (n) of VG model estimated from the laboratory evaporation and field experiment were found to be the same, and further more they showed a lower uncertainty from both the experiments. Moreover, the residual soil moisture (θr), inverse of capillary fringe thickness (α) and saturated hydraulic conductivity( KS) showed a relatively higher uncertainty. In the Berambadi watershed ,the inverse modeling was performed in three bare field plots, and it was found that field plots which had higher θs showed a relatively higher actual evapotranspiration (AET) and lower potential recharge. In Chapter 6, the retrieval of profile soil moisture up to 2m by assimilation of surface soil moisture was investigated by performing synthetic experiments on six soil types. The measured surface soil moisture over top 5cm depth was assimilated into the one dimensional soil moisture model to retrieve the profile soil moisture. Even though the assimilation of surface soil moisture helped in improving the profile soil moisture for the six soil types, the bias was observed. To reduce the bias, pseudo observations of profile soil moisture were generated and used in addition to the surface soil moisture in the assimilation altogether. These pseudo observations were generated using the linear relationship existing between the surface and profile soil moisture. A significant bias reduction was found to be feasible by using this method when pseudo observations beyond 75cm depth were used then there was no significant improvement. A coupled surface-ground water model was developed, which had 5 layers for the vadose zone and one layer for the ground water zone, in order to consider the major hydrological processes from ground surface to ground water table in a semi-arid watershed. The details of the coupled model were described in Chapter 7. The major aim of this model was to be able to use remotely sensed data of surface soil moisture and evapotranspiration to simulate recharge. The model was tested by applying in a lumped framework to the field data set in the Berambadi watershed for the year 2010 to 2011. The performance of the model was evaluated with the measured watershed average root zone soil moisture and ground water levels. The watershed average root zone soil moisture was obtained by averaging the field measurements from 20 plots and average ground water level was obtained by averaging the field measurement from 200 bore wells. In order to assimilate the AET into the coupled model, the daily AET at a spatial resolution of 1km was estimated from MODIS data. The AET was validated in one forested and four agricultural sites in the watershed. The validation was based on the comparison with AET simulated from water balance models. For agricultural plots the STICS (crop model) and for the forested site the COMFORT (hydrological) model were used. The AET from the MODIS showed a reasonably good match with both the forested and agricultural plots at the annual scale (for the crop model approximately 4-5 months). Model simulations were carried out with and without assimilating the remotely sensed data and the performance was evaluated. It was found that the assimilation helped in capturing the trends in deeper layer soil moisture and groundwater level. At the end, in Chapter 8 the major conclusions drawn from the various chapters are summarized.

No description available.

The effect of microwave radiation on the prepared 0.5Fe/ZSM-5 catalysts as a post-synthesis modification step was studied in the methanol-to-hydrocarbons process using the temperature-programmed surface reaction (TPSR) technique. This was achieved by preparing a series of 0.5Fe/ZSM-5 based catalysts under varying microwave power levels (0–700 W) and over a 10 s period, after iron impregnating the HZSM-5 zeolite (Si/Al = 30 and 80). Physicochemical properties were determined by XRD, SEM, BET, FT-IR, C3H9N-TPSR, and TGA techniques. It was found that microwave radiation induced few changes in the bulk properties of the 0.5Fe/ZSM-5 catalysts, but their surface and catalytic behavior were distinctly changed. Microwave radiation enhanced crystallinity and mesoporous growth, decreased coke and methane formation, decreased the concentration of Brønsted acidic sites, and decreased surface area and micropore volume as the microwave power level was increased from 0 to 700 W. From the TPSR profiles, it was observed that microwave radiation affects the peak intensities of the produced hydrocarbons. Application of microwave radiation shifted the desorption temperatures of the MTH process products over the HZSM-5(30) and HZSM-5(80) based catalysts to lower and higher values respectively. The MeOH-TPSR profiles showed that methanol was converted to DME and subsequently converted to aliphatic and aromatic hydrocarbons. It is reasonable to suggest that microwave radiation would be an essential post-synthesis modification step to mitigate coke formation and methane formation and increase catalyst activity and selectivity. / Chemical Engineering / M. Tech. (Chemical Engineering)