In the past, most research on soil mechanical properties was carried out for cohesionless soils in the fields of civil and geotechnical engineering. Little research has been carried out for mechanical properties of agricultural soil, which are essential for designing soil engaging tools in agriculture. In this study, unconsolidated undrained triaxial compression tests were performed to study the effects of moisture level and confining pressure on a sandy loam soil. The soil specimens tested had three moisture levels, and they were high (27-29% d.b.), medium (19-21% d.b.) and low (9-11% d.b.). The confining pressures used for the triaxial tests were 50, 100, and 150 kPa. Soil specimen was loaded at a strain rate of 1%/min. Measurements from the tests included stress-strain curve, shear strength, Young’s modulus, Poisson’s ratio, angle of internal friction, and cohesion. A model was developed using the Discrete Element Method (DEM) and computed by Particle Flow Code in three dimensions (PFC3D), a common DEM software. The model simulated the triaxial compression tests, and the model specimen was an assembly of 5-mm spherical particles which were defined by a set of micro parameters. During simulations, soil shear strength was monitored under different confining pressures. Through sensitivity analysis, it was found that most of the micro parameters affected the simulated soil shear strengths and the stress-strain behaviours. The most influential micro parameter was particle friction coefficient. This micro parameter was calibrated with the data from triaxial tests for different combinations of soil moisture levels and confining pressures. The calibrated particle friction coefficients varied from 0.2 to 1.0. The calibrations were done through matching the shear strengths between simulations and measurements, and the relative errors ranged between 0 and 6 %. / October 2015

The evaluation of the soil spatial variability using a fast, robust and cheap tool is one of the key steps towards the implementation of Precision Agriculture (PA) successfully. Soil organic carbon (OC), soil total nitrogen (TN) and soil moisture content (MC) are needed to be monitored for both agriculture and environmental applications. The literature has proven that visible and near infrared (vis-NIR) spectroscopy to be a quick, cheap and robust tool to acquire information about key soil properties simultaneously with relatively high accuracy. The on-line vis-NIR measurement accuracy depends largely on the quality of calibration models. In order to establish robust calibration models for OC, TN and MC valid for few selected European farms, several factors affecting model accuracy have been studied. Nonlinear calibration techniques, e.g. artificial neural network (ANN) combined with partial least squares regression (PLSR) has provided better calibration accuracy than the linear PLSR or principal component regression analysis (PCR) alone. It was also found that effects of sample concentration statistics, including the range or standard derivation and the number of samples used for model calibration are substantial, which should be taking into account carefully. Soil MC, texture and their interaction effects are other principle factors affecting the in situ and on-line vis-NIR measurement accuracy. This study confirmed that MC is the main negative effect, whereas soil clay content plays a positive role. The general calibration models developed for soil OC, TN and MC for farms in European were validated using a previously developed vis-NIR on-line measurement system equipped with a wider vis-NIR spectrophotometer (305 – 2200 nm) than the previous version. The validation results showed this wider range on-line vis-NIR system can acquire larger than 1500 data point per ha with a very good measurement accuracy for TN and OC and excellent accuracy for MC. The validation also showed that spiking few target field samples into the general calibration models is an effective and efficient approach for upgrading the implementation of the on-line vis-NIR sensor for measurement in new fields in the selected European farms.

No description available.

This thesis studied the influence of moisture content on the dynamic estimation of stiffness in wood of Pinus radiata D. Don. This is an important non-destructive measure for estimation of stiffness in standing trees, logs and lumber. Moisture content affects both acoustic velocity and density in the fundamental equation of dynamic MOE (DMOE = V²ρ, where V = acoustic velocity and ρ = density). Investigation included measurements with boards in the laboratory considering moisture contents below and above FSP as well as temperatures below and above 0°C. This also included field measurements of trees in contrasting climate sites and over different seasons including a long drought. Methods for measuring green density and moisture content and the patterns of variation of these parameters were also investigated. A secondary component of this thesis explored the wood quality and some mechanisms of tree response to water stress in two contrasting sites in terms or rainfall and water deficits in a region of Australia. The large increases in DMOE for frozen wood above the FSP (4.5 to 6 GPa) will limit the use of DMOE for grading logs in regions with freezing winters. Results from the experiment remeasuring young trees and the upper range of moisture content and temperatures above 0°C from the experiment with boards showed small to moderate variation in DMOE (0.1 to 1 GPa) which calls for further investigation on analytical procedures for adjustment of DMOE. Such procedures should consider that variations in acoustic velocity and density with changes in moisture content are not proportional and that there are counteracting effects between the two parameters. It remains to be investigated whether the typical variation (under normal climate conditions) in sapwood green density observed in our experiments has some implications for the use of DMOE. On the other hand, it is anticipated that the large differences along the stem and among stands in whole-section green density may bias DMOE measurements in logs for resource assessment. This also needs to be investigated. A comparison between acoustic velocity alone and DMOE for resource assessment under different scenarios is recommended. The study in two contrasting climate sites (high-altitude vs. warm-dry) in the Hume region of Forests NSW, Australia, including young (10-11 years) and mature trees (34 36 years) of radiata pine showed distinctive short and long-term responses of trees to cope with the water-limiting environment. In response to long-term water deficits the warm-dry site developed heartwood and thus reduced sapwood earlier and at faster rates than the high-altitude site. The onset of heartwood formation seemed to be triggered by some site threshold for water use as broadly indicated by the sapwood area/ha. The latter was consistently lower for the warm-dry site across the different stands. The warm-dry site also showed increased short-term responses to water stress and these were interpreted as seasonal mechanisms of the trees to cope with the limiting environment. The trees compensated for the lower available moisture and higher transpiration rates by lowering their saturation and disrupting water conduction at some points (cavitation). The inverse trends of cavitation spots and cavitation bands with height in the stem suggested the trees have different strategies to sacrifice conducting xylem depending on the position on the stem. Finally, it is suggested that saturation tended to fall to critical 'safe' levels as a result of water stress and this varied depending on age, site, and position in the stem. Significant decreases in DMOE and basic density were observed for the warm-dry site and were attributed to lower proportions of latewood due to lower rainfall for that site during the period of latewood formation. These showed no obvious association with any of the long-term water-stress traits (sapwood percentage and number of heartwood rings).

Percent Moisture Content (MC %) of wood is defined to be the weight of the moisture in the wood divided by the weight of the dry wood times 100%. Equilibrium Moisture Content (EMC), moisture content at environmental equilibrium is a very important metric affecting the performance of wood in many applications. For best performance in many applications, the goal is to maintain this value between 6% and 8%. EMC value is a function of the temperature and the relative humidity of the surrounding air of wood. It is very important to maintain this value while processing, storing or finishing the wood. This thesis develops a special purpose sensor and processor system to be implemented as a small hand-held device used to sense, calculate and display the value of EMC of wood depending on surrounding environmental conditions. Wood processing industry personnel would use the hand-held EMC calculating and display device to prevent many potential problems that can show significant affect on the performance of wood. The design of the EMC device requires the use of sensors to obtain the required inputs of temperature and relative humidity. In this thesis various market available sensors are compared and appropriate sensor is chosen for the design. The calculation of EMC requires many arithmetic operations with stringent precision requirements. Various arithmetic algorithms and systems are compared in terms of meeting required arithmetic functionality, precision requirements, and silicon implementation area and gate count, and a suitable choice is made. The resulting processor organization and design is coded in VHDL using the Xilinx ISE 6.2.03i tool set. The design is synthesized, validated via VHDL virtual prototype simulation, and implemented to a Xilinx Spartan2E FPGA for experimental hardware prototype testing and evaluation. It is tested over various ranges of temperature and relative humidity. Comparison of experimentally calculated EMC values with the theoretical values of EMC derived for corresponding temperature and relative humidity points resulted in validation of the EMC processor architecture, functional performance and arithmetic precision requirements.

Gas phase biofilters are used for controlling odors from animal facilities. Some characteristics can affect their performance and moisture content is one very important. A methodology for controlling and measuring moisture content is required to optimize these systems. An experiment was conducted to determine the appropriate placement of a set of soaker hoses 1.2 m in length for water application. It was found that the soaker hose installed in the lower region of the biofilter coupled with appropriate and timely application of water was able to minimize drying of the compost. Thermal conductance proved to be a reliable indicator for measuring the moisture content. Biofilters using the soaker hoses together with the thermal conductance as a media moisture sensor were able to maintain moisture content above 30% w.b. which provided sufficient water for microbial activity and ammonia abatement. A characterization of the ammonia and nitrous oxide concentrations was performed in order to compare the behavior of the gases when water was applied versus no water addition. These analyses revealed that the overall performance was not significantly different between treatments. But a more detailed assessment inside the biofilter media is performed; it is possible to identify different processes taking place.

Wood is used for many applications because of its excellent mechanical properties, relative abundance and as it is a renewable resource. However, its wider utilization as an engineering material is limited because it swells and shrinks upon moisture changes and is susceptible to degradation by microorganisms and/or insects. Chemical modifications of wood have been shown to improve dimensional stability, water repellence and/or durability, thus increasing potential service-life of wood materials. However current treatments are limited because it is difficult to introduce and fix such modifications deep inside the tissue and cell wall. Within the scope of this thesis, novel chemical modification methods of wood cell walls were developed to improve both dimensional stability and water repellence of wood material. These methods were partly inspired by the heartwood formation in living trees, a process, that for some species results in an insertion of hydrophobic chemical substances into the cell walls of already dead wood cells, In the first part of this thesis a chemistry to modify wood cell walls was used, which was inspired by the natural process of heartwood formation. Commercially available hydrophobic flavonoid molecules were effectively inserted in the cell walls of spruce, a softwood species with low natural durability, after a tosylation treatment to obtain “artificial heartwood”. Flavonoid inserted cell walls show a reduced moisture absorption, resulting in better dimensional stability, water repellency and increased hardness. This approach was quite different compared to established modifications which mainly address hydroxyl groups of cell wall polymers with hydrophilic substances. In the second part of the work in-situ styrene polymerization inside the tosylated cell walls was studied. It is known that there is a weak adhesion between hydrophobic polymers and hydrophilic cell wall components. The hydrophobic styrene monomers were inserted into the tosylated wood cell walls for further polymerization to form polystyrene in the cell walls, which increased the dimensional stability of the bulk wood material and reduced water uptake of the cell walls considerably when compared to controls. In the third part of the work, grafting of another hydrophobic and also biodegradable polymer, poly(ɛ-caprolactone) in the wood cell walls by ring opening polymerization of ɛ-caprolactone was studied at mild temperatures. Results indicated that polycaprolactone attached into the cell walls, caused permanent swelling of the cell walls up to 5%. Dimensional stability of the bulk wood material increased 40% and water absorption reduced more than 35%. A fully biodegradable and hydrophobized wood material was obtained with this method which reduces disposal problem of the modified wood materials and has improved properties to extend the material’s service-life. Starting from a bio-inspired approach which showed great promise as an alternative to standard cell wall modifications we showed the possibility of inserting hydrophobic molecules in the cell walls and supported this fact with in-situ styrene and ɛ-caprolactone polymerization into the cell walls. It was shown in this thesis that despite the extensive knowledge and long history of using wood as a material there is still room for novel chemical modifications which could have a high impact on improving wood properties. / Der nachwachsende Rohstoff Holz wird aufgrund seiner guten mechanischen Eigenschaften und der leichten Verfügbarkeit für viele Anwendungszwecke genutzt. Quellen und Schrumpfen bei Feuchtigkeitsänderungen des hygroskopischen Werkstoffs Holz limitieren jedoch die Einsatzmöglichkeiten. Ein weiteres Problem stellt der mitunter leichte Abbau – u.a. bei feuchtem Holz - durch Mikroorganismen und/oder Insekten dar. Durch chemische Modifizierungen können die Dimensionsstabilität, die Hydrophobizität und die Dauerhaftigkeit verbessert und damit die potentielle Lebensdauer des Werkstoffes erhöht werden. Dabei ist die dauerhafte Modifikation der Zellwand nur äußerst schwer realisierbar. Inspiriert von der Kernholzbildung in lebenden Bäumen, ein zellwandverändernder Prozess, der Jahre nach der Holzbildung erfolgt, wurden im Rahmen dieser Arbeit neue Ansätze zur chemischen Modifizierung der Zellwände entwickelt, um die Dimensionsstabilität und Hydrophobizität zu erhöhen. Der erste Teil der Arbeit ist stark vom Prozess der Kernholzbildung inspiriert, eine abgeleitete Chemie wurde verwendet, um die Zellwände von Fichte, einem Nadelholz von geringer natürlicher Dauerhaftigkeit, zu modifizieren. Kommerziell verfügbare hydrophobe Flavonoide wurden nach einem Tosylierungsschritt erfolgreich in die Zellwand eingebracht, um so „artifizielles Kernholz“ zu erzeugen. Die modifizierten Holzproben zeigten eine verringerte Wasseraufnahme, die zu erhöhter Dimensionsstabilität und Härte führte. Dieser Ansatz unterscheidet sich grundlegend von bereits etablierten Modifikationen, die hauptsächlich hypdrophile Substanzen an die Hydroxylgruppen der Zellwand anlagern. Der zweite Teil der Arbeit beschäftigt sich mit der Polymerisation von Styren in tosylierten Zellwänden. Es ist bekannt, dass es nur eine schwache Adhäsion zwischen den hydrophoben Polymeren und den hydrophilen Zellwandkomponenten gibt. Die hydrophoben Styren-Monomere wurden in die tosylierte Zellwand eingebracht und zu Polystyren polymerisiert. Wie bei der Modifikation mit Flavonoiden konnte eine erhöhte Dimensionsstabilität und reduzierte Wasseraufnahme der Zellwände beobachtet werden. Im dritten Teil der Arbeit wurde das biologisch abbaubare, hydrophobe poly(ɛ-caprolacton) in der Zellwand aufpolymerisiert. Die Ergebnisse deuten darauf hin, dass Polycaprolacton in der Zellwand gebunden ist und zu einer permanenten Quellung führt (bis zu 5 %). Die Dimensionsstabilität nahm um 40 % zu und die Wasseraufnahmerate konnte um mehr als 35 % reduziert werden. Mit dieser Methode kann nicht nur dimensionsstabileres Holz realisiert werden, auch biologische Abbaubarkeit und damit eine einfache Entsorgung sind gewährleistest.

For two fire seasons in Nordegg, Alberta, a system of in-stand weather stations were arranged along a north and south aligned valley and combined with collection of destructive fine fuel moisture content data in order to quantify variations due to differences in slope and aspect. South-facing sites were found to be slightly warmer (1.5°C), less humid (5%) and received on average 20% more solar radiation than the north-facing sites during the peak burning period of the day. Based on these weather observations a difference of 1 or 2 % moisture content between north and south sites was predicted using existing theoretical relationships. A corresponding difference in observed moisture content was not identified, due to the low transmittance recorded at the in-stand sites (<10% of open solar radiation measurements), variation amongst destructive samples and logistical limits on the number of replicates collected.

For two fire seasons in Nordegg, Alberta, a system of in-stand weather stations were arranged along a north and south aligned valley and combined with collection of destructive fine fuel moisture content data in order to quantify variations due to differences in slope and aspect. South-facing sites were found to be slightly warmer (1.5°C), less humid (5%) and received on average 20% more solar radiation than the north-facing sites during the peak burning period of the day. Based on these weather observations a difference of 1 or 2 % moisture content between north and south sites was predicted using existing theoretical relationships. A corresponding difference in observed moisture content was not identified, due to the low transmittance recorded at the in-stand sites (<10% of open solar radiation measurements), variation amongst destructive samples and logistical limits on the number of replicates collected.

In this study, the relationship between soil suction and shear strength parameters of compacted METU campus clay were investigated at different moisture contents. Soil samples were tested at optimum moisture content (i.e. w=20.8%), at dry side of optimum moisture content (i.e. w=14.8%, 16.8%, 18.8%) and at wet side of optimum moisture content (i.e. w=22.8%, 24.8%, 26.8%). Direct shear tests were performed to measure shear strength parameters (c&#039 / , &amp / #934 / &#039 / ) and soil suctions were measured by filter paper method after direct shear tests. These relationships were also investigated on soaked samples. The trends for suction, angle of internal friction and cohesion, which change on the dry side and wet side of optimum moisture content, were analyzed. The compacted METU campus clay gains granular soil fabric at the dry side of optimum moisture content. As moisture content increases, cohesion increases up to optimum moisture content and then decreases. But angle of internal friction decreases as moisture content increases. Soaking affects the samples more which are on the dry side of optimum moisture content. The soil suction (total suction and matric suction) affects the shear strength, and an increase in soil suction increases the shear strength.