Development of vacant lot Křížová. Relation to yard. Functional contents of street line and yard.

The aim of this thesis is to find new forms of housing for socially excluded inhabitants of the Czech Republic. The proposed set of two buildings is located in the street Kopečná in the district of Staré Brno. The buildings are placed in the immediate vicinity and their functions are independent of each other. The first building provides both acute and long-term assistance and temporary accommodation for homeless people. Inside this building is a low threshold day centre, night shelter and sheltered housing. There is a hierarchy of different levels of sheltered housing created by specific dispositions, which cover the wide diversity of needs of the target group. The second object is a residential building providing accommodation in the concept of "housing first" ("housing first"). Inside the building there are sheltered workshops (cafe, bakery and bicycle repair shop) provides the employability skills and social flats serves as a pre independent living.

Polymer-derived ceramics (PDCs) are exceptional ultra-high temperature and stable multifunctional class of materials that can be synthesized from a polymer precursor through thermal decomposition. The presented research focuses on 1-D nanofibers, 2-D films and 3-D bulk, carbon-rich silicon carbon nitride (SiCN) ceramics. 1-D nanofibers were prepared via electrospinning for light weight, flame retardant and conductive applications. The commercially available CerasetTM VL20, a liquid cyclosilazane pre-ceramic precursor, was mixed with polyacrylonitrile (PAN) in order to make the cyclosilazane electrospinnable. Carbon-rich PDC nanofibers were fabricated by electrospinning various ratios of PAN/cyclosilazane solutions followed by pyrolysis. Surface morphology of the electro spun nanofibers characterized by SEM show PDC nano?bers with diameters ranging from 100-300 nm. Also, thermal stability towards oxidation showed a 10% mass loss at 623°C. 2-D carbon/SiCN films were produced by drop-casting a mixture of PAN/cyclosilazane onto a glass slide followed by pyrolysis of the film. Samples ranging from 10:1 to 1:10 PAN:cyclosilazane were made by dissolving the solutes into DMF to produce solutions ranging from 1% to 12% by weight. Green, heat-stabilized, and pyrolyzed 8% films were examined with FTIR to monitor the change in chemical structure at each step of the ceramization. SEM shows that high PAN samples produced films with ceramic embedded spheroid components in a carbon matrix, while high cyclosilazane samples produced carbon embedded spheroid. Finally, this research focuses on the challenge of making fully dense, 3-D bulk PDCs materials. Here we present a composite of SiCN with reduced graphene oxide (rGO) aerogels as a route for fully dense bulk PDCs. Incorporation of the rGO aerogel matrix into the SiCN has its pros and cons. While it lowers the strength of the composite, it allows for fabrication of large bulk samples and an increase in the electrical conductivity of the PDC. The morphology, mechanical, electrical properties and thermal conductivity of graphene-SiCN composite with varying rGO aerogel loading (0.3-2.4%) is presented. The high temperature stability, high electrical conductivity and low thermal conductivity of these composites make them excellent candidates for thermoelectric applications. Generally, carbon-rich SiCN composites with improved thermal and electrical properties are of great importance to the aerospace and electronics industries due to their expected harsh operating environments.

Yes / The on-going COVID-19 pandemic caused by severe acute respiratory syndrome coronavirus 2 (SARS- CoV-2) has posed an extraordinary threat to global public health, wealth and well-being. As the carrier of human life and production, infrastructures need to be upgraded to mitigate and prevent the spread of viral diseases. Developing multifunctional/smart civil engineering materials to fight viruses is a promising approach to achieving this goal. In this perspective, the basic introduction on virus and its structure is provided. Then, the current design principles of antiviral materials and structures are examined. Subsequently, the possibility of developing active/passive antiviral civil engineering materials (including cementitious composites, ceramics, polymers and coatings) is proposed and envisaged. Finally, the future research needs and potential challenges to develop antiviral civil engineering materials are put forward. The proposed strategies to develop multifunctional/smart antiviral civil engineering materials will aid in the construction of smart infrastructures to prevent the spread viruses, thus improving human life and health as well as sustainability of human society. / The authors would like to thank the National Science Foundation of China (51978127, 52178188, and 51908103) and the Fundamental Research Funds for the Central Universities (DUT21RC(3)039) for providing funding to carry out this investigation.

Flexible foams have unique properties that make them well-suited to several engineering systems. They are often used in impact-related applications because of their superior energy absorption performance. Many multifunctional materials are also derived from flexible foams due to their high customizability, which allows them to satisfy a wide range of performance requirements. Though flexible foams have high potential in these and other classes of material applications, their success relies on the proper characterization of their complex behavior. This thesis promotes the application of flexible foams by characterizing their electromechanical response through both experimental and theoretical approaches. One study in this thesis theoretically determines material indices that minimize a foam's mass and cost while meeting particular energy absorption requirements. These novel indices are combined with a common Ashby approach to facilitate materials selection of energy-absorbing foam components. Another study uses a particular multifunctional nanocomposite foam to experimentally determine deviations in its voltage response while under a cyclic impacting regime; specifically, factors of transient effects, environmental conditions (humidity and temperature), and permanent material degradation are investigated. Results presented in this thesis promote the application of flexible foams to various forms of impact-absorbing sports equipment (specifically football helmet pads and gait-sensing shoe insoles), but are also useful in various other engineering designs.

The relevance of the topic of the thesis is due to the need to analyze and improve the efficiency of development projects in modern economic conditions. The master thesis includes an introduction, three chapters, conclusion, list of references and applications. The introduction substantiates the choice of the research topic, its relevance, formulates the goal and objectives of this work, identifies the subject and object of research, its theoretical foundations, identifies the scientific novelty. In the first chapter, the concept of a development project is considered, its features in the context of commercial and residential real estate are highlighted. The second chapter analyzes and evaluates the effectiveness of the development project of the multifunctional residential complex of the residential complex "Arbatsky". In the third chapter, a parking project was developed on the territory of the multifunctional residential complex of the residential complex “Arbatsky” to increase the efficiency of the development project as a whole. In conclusion, the main conclusions are formulated and the results of the research are summarized. / Актуальность темы диссертации обусловлена необходимостью анализа и повышения эффективности девелоперских проектов в современных экономических условиях. Магистерская диссертация включает в себя введение, три главы, заключение, список использованных источников и приложения. Во введении обоснован выбор темы исследования, ее актуальность, сформулированы цель и задачи данной работы, определены предмет и объект исследования, его теоретические основы, обозначена научная новизна. В первой главе рассмотрено понятие девелоперского проекта, выделены его особенности в разрезе коммерческой и жилой недвижимости. Во второй главе проведен анализ и дана оценка эффективности девелоперского проекта многофункционального жилого комплекса ЖК «Арбатский». В третьей главе был разработан проект парковки на территории многофункционального жилого комплекса ЖК «Арбатский» для повышения эффективности девелоперского проекта в целом. В заключении сформулированы основные выводы и обобщены результаты исследования.

京都大学 / 新制・論文博士 / 博士(農学) / 乙第13507号 / 論農博第2905号 / 新制||農||1095(附属図書館) / 学位論文||R4||N5407(農学部図書室) / (主査)准教授 沈 金虎, 教授 浅見 淳之, 教授 栗山 浩一 / 学位規則第4条第2項該当 / Doctor of Agricultural Science / Kyoto University / DFAM

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