Multilayered iron electrodeposits composed of alternating layers of coarse-grained iron (grain size: 1.87 μm; (110) texture; hardness: 177 VHN) and fine-grained iron (grain size: 132 nm; (211) texture; hardness: 502 VHN), with layer thicknesses ranging from ~0.2-7 μm were successfully synthesized. The average hardness of the multilayered electrodeposits increased from 234 VHN to 408 VHN with decreasing layer thickness, consistent with a Hall-Petch type behaviour. In three-point bending tests, they failed in a macroscopically brittle manner although local ductility was observed in certain layers. Fractography analysis has shown that strain incompatibility between alternating layers contributes to the brittle nature of these materials. This study has demonstrated the possibility of applying a multilayered structure design to tailor the microstructure and mechanical properties of electrodeposited iron.

Multilayered iron electrodeposits composed of alternating layers of coarse-grained iron (grain size: 1.87 μm; (110) texture; hardness: 177 VHN) and fine-grained iron (grain size: 132 nm; (211) texture; hardness: 502 VHN), with layer thicknesses ranging from ~0.2-7 μm were successfully synthesized. The average hardness of the multilayered electrodeposits increased from 234 VHN to 408 VHN with decreasing layer thickness, consistent with a Hall-Petch type behaviour. In three-point bending tests, they failed in a macroscopically brittle manner although local ductility was observed in certain layers. Fractography analysis has shown that strain incompatibility between alternating layers contributes to the brittle nature of these materials. This study has demonstrated the possibility of applying a multilayered structure design to tailor the microstructure and mechanical properties of electrodeposited iron.

We introduce supplemental methods for the finite-difference time-domain (FDTD) analysis of planar multilayered media. The invariance is allowed to be disturbed by any imperfection, provided that these imperfections are local and therefore can be contained within an FDTD simulation grid. We specifically investigate two FDTD methods that were not previously developed for general multilayered media: the near-field-to-far-field transform (NFFFT) and the total-field/scattered-field (TF/SF) boundary (or the plane-wave injector). The NFFFT uses the FDTD output on a virtual surface surrounding the local imperfections and calculates the radiated field. The plane wave injector builds an incident plane wave inside a certain boundary (TF/SF boundary) while allowing any scattered fields created by the imperfections inside the boundary to exit the boundary with complete transparency. The NFFFT is applicable for any lossless multilayered medium, while the plane-wave injector is applicable for any lossy multilayered medium. After developing the respective theories and giving simple examples, we apply the NFFFT and the plane-wave injector to a series of problems. These problems are divided into two main groups. In the first group, we consider plane-wave scattering problems involving perfectly-conducting objects buried in multilayered media. In the second group, we consider problems that involve radiating structures in multilayered media. Specifically, we investigate the reciprocity of antennas radiating in the presence of an ungrounded dielectric slab using the methods developed in this study. Finally, we present our previous work on an entirely different subject, namely, the theoretical analysis of the input admittance of a prolate-spheroidal monopole fed by a coaxial line through a ground plane.

In the present study, we propose a computational model for the linear and nonlinear analysis of shell structures. We consider a tensor-based finite element formulation which describes the mathematical shell model in a natural and simple way by using curvilinear coordinates. To avoid membrane and shear locking we develop a family of high-order elements with Lagrangian interpolations. The approach is first applied to linear deformations based on a novel and consistent third-order shear deformation shell theory for bending of composite shells. No simplification other than the assumption of linear elastic material is made in the computation of stress resultants and material stiffness coefficients. They are integrated numerically without any approximation in the shifter. Therefore, the formulation is valid for thin and thick shells. A conforming high-order element was derived with 0 C continuity across the element boundaries. Next, we extend the formulation for the geometrically nonlinear analysis of multilayered composites and functionally graded shells. Again, Lagrangian elements with high-order interpolation polynomials are employed. The flexibility of these elements mitigates any locking problems. A first-order shell theory with seven parameters is derived with exact nonlinear deformations and under the framework of the Lagrangian description. This approach takes into account thickness changes and, therefore, 3D constitutive equations are utilized. Finally, extensive numerical simulations and comparisons of the present results with those found in the literature for typical benchmark problems involving isotropic and laminated composites, as well as functionally graded shells, are found to be excellent and show the validity of the developed finite element model. Moreover, the simplicity of this approach makes it attractive for future applications in different topics of research, such as contact mechanics, damage propagation and viscoelastic behavior of shells.

Thesis (Ph. D.)--University of California, San Diego, 2003. / Vita. Includes bibliographical references.

The mirrors used in high energy laser systems have at least two requirements that are uncommon in optical engineering: the reflectance of such mirrors must be very high (> 0.999), and the level of aberrations introduced by the mirrors is desired to be very low, typically λ/50 peak at 3.8 μ. The first requirement can be met by using multilayer thin film coatings, but such coatings can themselves produce aberrations in an optical system. One possible effect in multilayers is that such coatings produce an optical phase change on reflection that varies with angle of incidence and polarization of the illuminating beam. On a strongly curved mirror, such as an f/1.5 parabola used as a collimator, these effects may be appreciable for some coatings (e.g., λ/13 for a broadband all-dielectric reflector), but for an enhanced silver coating the effects are small, typically λ/400 of error that is almost entirely in the form of a small focus shift. If this same parabola is tested at its center of curvature, the coating-caused aberration due to angle of incidence effects are nearly zero (e.g., λ/50,000 for the broadband reflector that gave λ/13 when the parabola was used as a collimator). The wavefront errors due to coating nonuniformities are usually more important than angle of incidence effects. The simplest type of coating nonuniformity to analyze is a proportional error, i.e., an error where the ratios of the thicknesses of the layers are fixed but the thin film stack varies in total thickness across a surface. For a six-layer enhanced reflector for use at 3.8 μ, a 1% thickness error produces an approximate λ/100 wavefront error. At visible wavelengths, however, the aberration produced by such a coating error can be very different because of the optical interference nature of the coating. Means may be developed to estimate the performance of such an infrared reflector from measurements at visible wavelengths. If the errors produced by the coating are to be distinguished from those existing in the test due to misalignment or gravitational flexure of a large mirror, two or more wavelengths must be chosen. There are ambiguities in such a test that may be resolved by choice of an appropriate coating design or by using enough wavelengths in the visible, and both means have been studied. A technique was found where the infrared wavefront can be determined for a coating with proportional thickness errors if the coating prescription is known: interferograms of the mirror are made at three visible wavelengths, and the IR wavefront error due to the coating error is determined in a way that is insensitive to any errors caused by distortion of the substrate or even fairly large misalignments in the optical test of a mirror's figure.

No description available.

No description available.

A synthetic analog of a spider silk protein (M4) was studied. Langmuir films were made and an inflexion in the isotherm indicated conformational changes upon compression. Deposition onto solid substrates was most successful using a hydrophobic substrate and the Langmuir-Schaeffer method. AFM was used to image the surface, which was mesh like and did not show any indication of order. / Gold nanoparticles were produced in the presence of the protein and protein solutions were added to read made nanoparticles for the purpose of displacing the weak ligands present. CD measurements were performed on the protein solutions to study its conformation. Nanoparticle size information was obtained from TEM images. DLS was used to determine if the protein was affected by the addition of the gold nanoparticles. Precipitation of the protein was shown not to affect the nanoparticles.

Fresh-cut watermelon is appreciated for its taste, flavor, and juiciness. However, there are challenges in maintaining the freshness since fresh-cut processing of fruits promotes faster deterioration. Our objective was to determine the effectiveness of multilayered antimicrobial edible coating on the shelf-life of fresh-cut watermelon while keeping its original attributes for longer, without affecting its sensory properties. A set of solutions containing sodium alginate (0.5, 1, 2% w/w), beta-cyclodextrin, trans-cinnamaldehyde (antimicrobial agent), pectin, and calcium lactate were used as coating systems for fresh-cut watermelon cylinders. The samples were coated by the layer-by-layer dipping technique and stored at 4 degrees C for 15 days. Results were analyzed individually for each quality attribute evaluated, and the best concentration among the solutions to improve each attribute was found. Watermelon quality was measured in terms of texture, color, juice leakage (weight loss), oBrix, and pH. Microbiological analysis consisted of total coliforms, yeasts and molds, aerobics, and psychrotrophs. A consumer test was carried out (~ 40 panelists) to support the objective quality data. Panelists scored the samples using a 9-point hedonic scale. Uncoated samples served as controls. Quality tests were conducted at days 1, 3, 7, 12, and 15 of storage. Sensory tests showed high acceptance (P < 0.05) of the coated samples when compared to the controls. Quality attributes, particularly texture (firmness) and juice leakage (weight loss) were enhanced (P < 0.05) by the coating. Microbiological analysis demonstrated that alginate-based edible coating has a huge effect against microbial growth. 1% sodium alginate coating provided better preservation in terms of quality parameters, microbiological growth, and sensory acceptance. These results indicate that different ratios between solutions present a significant variation for each quality attribute measured in this study; and the thickness of the coating as well as the amount of antimicrobial are critical for shelf-life extension of fresh-cut watermelon. Hence, application of an alginate based multilayered edible coating has tremendous potential to enhance microbial quality and extend the shelf-life of fresh-cut watermelon.