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This study explores the possibility of utilizing bioleaching techniques for nickel extraction from a mixed sulfide ore deposit with high magnesium content. Due to the ultramafic nature of this material, well-studied bioleaching technologies, which rely on acidophilic bacteria, will lead to undesirable processing conditions. This is the first work that incorporates nitrate-dependent bacteria under pH 6.5 environments for bioleaching of base metals. Experiments with both defined bacterial strains and indigenous mixed bacterial cultures were conducted with nitrate as the electron acceptor and sulfide minerals as electron donors in a series of microcosm studies. Nitrate consumption, sulfate production, and Ni released into the aqueous phase were used to track the extent of oxidative sulfide mineral dissolution; taxonomic identification of the mixed culture community was performed using 16S rRNA gene sequencing. Nitrate-dependent microcosms that contained indigenous sulfur- and/or iron-oxidizing microorganisms were cultured, characterized, and provided a proof-of-concept basis for further bioleaching studies.

Stress corrosion cracking (SCC) from the external surface of a buried pipeline is a serious matter and can cause significant economic and environmental losses. Despite of many research works which have been done on the understanding of crack initiation and propagation mechanisms, these mechanisms are still being debated. This research studied the crack growth behaviour of different pipeline steels including two types of X65, one X52 and one X80 pipeline steels in near-neutral pH environments. Crack growth behaviour of all steels has been found to be consistent with that of true corrosion fatigue. Crack growth rates were correlated with (K)2Kmax/f0.1. It was revealed that cracking behaviour of pipeline steels in near neutral pH environments is material dependent. Highest crack growth rate was seen in the steel which highest amount of hydrogen atoms could be generated and stored in its microstructure to contribute in cracking procedure due to hydrogen embrittlement effect. / Materials Engineering