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Local structure and dynamics of complex fluidsCarmer, James Lee 15 January 2014 (has links)
There is a well-known connection between the structure and dynamics that is present in molecular and colloidal systems. Using this connection as a guide we are able to design interparticle potentials that optimizes the diffusivity of a single particle.
While structure-dynamic correlations provide the insight that diffusion could be enhanced, the effect of this enhancement on the dynamics of neighboring particles is more difficult to quantify.
A novel method for calculating position-dependent dynamics is introduced that can be easily implemented into existing simulation protocols. The computational requirements are very low compared to existing methods and this technique can also be applied to a wide variety of systems, including experiments where particle trajectories can be determined.
Using this method, the position-dependent diffusivity of solvent particles in the vicinity of a tracer particle can be measured.
This information allows for determination of the microscopic changes that take place as a result of the optimization discussed above.
To study the effect of a non-continuum solvent, we design a system that eliminates inhomogeneous structuring near an interface. Hydrodynamic theory can predict the position-dependent diffusivity of a sphere in continuum solvent. Comparing these systems not only highlights the difference in position-dependent dynamics for continuum and non-continuum solvents, but is a starting point to study what happens to dynamics when structure is reintroduced.
This allows us to answer many other questions about the relationships between structure and dynamics. While these connections have been studied extensively for average properties, they have not been explored for their position-dependent counterparts. For bulk fluids, the insertion probability and two-body excess entropy has proven useful for predicting average dynamic properties. We develop expressions for the position-dependent versions of both of these quantities. We show that when using the appropriate reference state the position-dependent diffusivity can be qualitatively related to the insertion probability. / text
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An analysis of the roles of district offices in Hong Kong's district administration systemFong, Kai-kit., 方啓杰. January 1999 (has links)
published_or_final_version / Public Administration / Master / Master of Public Administration
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An evaluation of the work of the Southern District BoardCheng, Wai-fung, Winnie., 鄭慧鳳. January 1985 (has links)
published_or_final_version / Public Administration / Master / Master of Social Sciences
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An analysis of district administration: its implications upon administrative & political development in HongKongLui, Sui-keung, Tommy., 呂瑞強. January 1985 (has links)
published_or_final_version / Urban Studies / Master / Master of Social Sciences
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A scientific method of measuring the effectiveness of local governmentWalcutt, James Charles, 1948- January 1975 (has links)
No description available.
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Twelve MARTA station designs as perceived, felt and used by the laymanIseman, Jodi Hamor 12 1900 (has links)
No description available.
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Localised splitting criteria for classification and regression treesA.Bremner@murdoch.edu.au, Alexandra Bremner January 2004 (has links)
This thesis presents a modification of existing entropy-based splitting criteria for classification and regression trees. Trees are typically grown using splitting criteria that choose optimal splits without taking future splits into account. This thesis examines localised splitting criteria that are based on local averaging in regression trees or local proportions in classification trees. The use of a localised criterion is motivated by the fact that future splits result in leaves that contain local observations, and hence local deviances provide a better approximation of the deviance of the fully grown tree. While most recent research has focussed on tree-averaging techniques that are aimed at taking a moderately successful splitting criterion and improving its predictive power, this thesis concentrates on improving the splitting criterion.
Use of a localised splitting criterion captures local structures and enables later splits to capitalise on the placement of earlier splits when growing a tree. Using the localised splitting criterion results in much simpler trees for pure interaction data (data with no main effects) and can produce trees with fewer errors and lower residual mean deviances than those produced using a global splitting criterion when applied to real data sets with strong interaction effects.
The superiority of the localised splitting criterion can persist when multiple trees are grown and averaged using simple methods. Although a single tree grown using the localised splitting criterion can outperform tree averaging using the global criterion, generally improvements in predictive performance are achieved by utilising the localised splitting criterion's property of detecting local discontinuities and averaging over sets of trees grown by placing splits where the deviance is locally minimal. Predictive performance improves further when the degree of localisation of the splitting criterion is randomly selected and weighted randomisation is used with locally minimal deviances to produce sets of trees to average over. Although state of the art methods quickly average very large numbers of trees, thus making the performance of the splitting criterion less critical, predictive performance when the localised criterion is used in bagging indicates that different splitting methods warrant investigation.
The localised splitting criterion is most useful for growing one tree or a small number of trees to examine structure in the data. Structurally different trees can be obtained by simply splitting the data where the localised splitting criterion is locally optimal.
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The role of indigenous governance system(s) in sustainable development : case of Moshupa Village, Botswana /Moatlhaping, Segametsi Oreeditse S. January 2007 (has links)
Thesis (MPhil)--University of Stellenbosch, 2007. / Bibliography. Also available via the Internet.
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Bus transit equity among demographic groups considering monetary and travel time costsMedellin, Leonel. January 1900 (has links)
Thesis (Ph. D.)--West Virginia University, 2007. / Title from document title page. Document formatted into pages; contains vi, 84 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 70-73).
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Factors influencing voting behavior in support of rapid transit in Seattle and Atlanta.Hetrick, Virginia R. January 1974 (has links)
Thesis (Ph. D.)--University of Washington. / Bibliography: l. 206-225.
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