This investigation addresses the thermal characteristics of the major oceanic frontal systems in the Southern Ocean south of Africa based on data collected to a depth of 500 m on forty-three cruises during a fifteen year period. The width of the Agulhas Front has been shown to vary considerably in both its sea surface and sub-surface thermal manifestation as a result of mesoscale turbulence. Its mean sea surface width of 84 km has a standard deviation of 53 km, and the mean subsurface width of 37 km has a standard deviation of 33 km. The Agulhas Front. has been found to be a separate front north of the Subtropical Convergence in 56 % of the cruises investigated. It has only been observed from 18,2°E to 24,7°E, with a mean sea and subsurface temperature gradient across the Agulhas Front of 0,05 °C/km and 0, 13 °C/km respectively. It has a mean sea surface middle temperature of 17, 8° C and a mean subsurface middle temperature of 12,6° C. The mean sea and sub-surface geographic positions of the thermal expression of the Agulhas Front are 39,3° S; 22,7° E aild 39,1° S; 22,7° E. The Subtropical Convergence at surface has been found to be a single, broad frontal zone across the Central/South East Atlantic Ocean, that does not bifurcate. It has a mean sea surface middle temperature of ·14,3° C and a mean sub-surface middle temperature of 8,4° C. The mean sea and sub-surface temperature gradients across the Subtropical Convergence are O, 03 °C/km and O, 05 °C/km respectively. The mean sea and sub-surface geographic positions of the· thermal expression of the Subtropical Convergence are 41, 8° S; 21, 9° E and 41, 7° S; 22, 0° E. The Subtropical Convergence has a mean sea surface width of 146 km and a mean sub-surface width of 79 km. The Sub-antarctic Front is pressed northward from 45° S to 43° S by the Mid-Ocean Ridge in the South West Indian Ocean sector, after which it converges · with the Subtropical Convergence at approximately 60° E to form a united STC/SAF at subsurface. This united STC/SAF does not however form a "Crozet Front" by joining the Agulhas Front between 52° E and 65° E. It has a mean sea surface middle temperature of 4,4° C and a mean sub-surface middle temperature of 4,0° C. The mean sea and subsurface temperature gradients across the Sub-antarctic Front are 0,02 °C/km. The mean sea and sub-surface geographic positions of the thermal expression of the Sub-antarctic Front are 48,7° S; 18,9° E and 46,8° S; 19,9° E. The Sub-antarctic Front has a mean sea surface width of 73 km and a mean sub-surface width of 77 km. In 30 % of the sections investigated the- Antarctic Polar Front consisted of a primary and secondary front. The Antarctic Polar Front does not join the Sub-antarctic Front east of · 40° E at sub-surface and subsequently no quadruple front is formed. It has a mean sea surface middle temperature of 2, 1 ° C and a mean sub-surface middle temperature of 2,3° C. The mean sea and sub-surface temperature gradients across the Antarctic Polar Front are 0,01 °C/km and 0,02 °C/km respectively. The mean sea and sub-surface geographic position of the thermal expression of the Antarctic Polar Front are 52, 7° S; 14,9° E and 49,2° S; 20,8° E. The Antarctic Polar Front has a mean sea surface width of 66 km and a mean sub-surface width of 74 km.

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The control of atmospheric pollution in the urban environment has, in recent years, taken on important local, national and international significance. Legislation has been introduced in many countries to improve air quality in urban areas. Monitoring air pollution is an important part of understanding and improving air quality. Current standard methods of measuring air pollution only monitor at a single point in space which can lead to ambiguities when assessing air quality over an extended region, such as a city centre or a road intersection. Optical remote sensing techniques, such as long path Fourier transform absorption spectroscopy, overcome the limitations of point measurements by integrating over long paths and thus measuring the average ambient pollutant concentrations. A commercially available Fourier transform infrared (FTIR) spectrometer, together with custom built external optics has been used to make measurements of air pollution in Oxford city centre. It has been shown that it is possible to measure the concentrations of several pollutants simultaneously and in short measurement times. Issues relating to the performance of the spectrometer have been studied, their effects quantified and solutions proposed. Optimal estimation techniques have been applied to the analysis of the single beam spectra recorded by the FTIR spectrometer. This technique has previously only been applied to radiance and transmission spectra and so extensions were necessary. High resolution laboratory measurements of the absorption cross-sections of benzene and 1,3-butadiene have been made and the potential for detecting them in ambient urban air determined.

Over recent years geological, geochemical and geophysical surveys of mid-ocean ridges have revealed a significant degree of along-axis variability not only in seabed morphology, but also in crustal structure, particularly Numerous geophysical surveys of the Valu Fa Ridge, southwest Pacific, have mapped the extent of an axial mid-crustal reflector. This reflector has been interpreted as representing the top of a sill-like melt lens, comprising a high percentage of partial melt, lying at the top of a crustal magma chamber. In 1995, a controlled-source, wide-angle seismic dataset was acquired at the Valu Fa Ridge during RN Maurice Ewing cruise EW9512, to investigate the mid-deep crustal structure at this ridge, and particularly the crustal magma chamber associated with the melt lens beneath the ridge axis. The EW9512 acquisition geometry was primarily two-dimensional in design, and modelling of these 2-D profiles revealed the presence of an axial low velocity zone beneath the melt lens. This low velocity zone is thought to represent a region of crystal mush comprising a much lower percentage of partial melt than is present in the overlying melt lens. Similar structures have been modelled beneath a number of other mid-ocean ridges. The primary aim of this study was to build on this 2-D interpretation by taking advantage of three-dimensional ray coverage in the axial region in order to assess the along-axis continuity of the magmatic system, correlate this to any ridge segmentation apparent in the seabed morphology, and determine if ridge segmentation is related to the magma supply. The 3-D data were analysed using a tomographic inversion technique. The inversion results suggest that the axial low velocity zone may be segmented on a scale of 5-10 km, which correlates with the morphological segmentation of the ridge crest and is believed to reflect episodic magma supply with different ridge segments at different stages of a cycle of magmatic and amagmatic extension. However, three- dimensional ray coverage is not ideal owing to the dominantly 2-D acquisition geometry. Therefore a detailed assessment of data uncertainty and resolution was undertaken to enable a meaningful interpretation of the inversion results in terms of which features have a geological origin and which are artefacts of the inversion process. P-S mode converted arrivals arising from mid-crustal interfaces were also modelled in order to obtain improved geological constraints on the crustal structure than is possible from P-wave studies alone. This modelling indicates that the uppermost crust is pervaded by thin cracks. In addition, techniques were developed for modeling the polarisation of 5-wave arrivals with low signal strength. Application of these methods suggests that the thin cracks have a preferred orientation parallel to the ridge crest on-axis, and oblique to the ridge crest off-axis which is thought to reflect the pattern of southward propagation of the ridge system inferred from regional tectonic and bathymetric studies. Modelling of P-S mode converted arrivals arising from conversion at the top of the melt lens provided additional constraints on the properties of the melt lens. In conjunction with the 3-D tomographic results, this work suggests that the southernmost ridge segment in the study area has recently become magmatically active following a period of amagmatic extension suggested by its morphology, thus providing evidence for episodic melt supply at this ridge. As part of the suggestions for further work, a theoretical investigation of survey resolution was undertaken to test commonly adopted acquisition geometries with a view to optimising the design and cost-effectiveness of future 3-D controlled-source tomographic experiments.

Seismic reflection surveying is used to generate acoustic images of the water column. This technique employs conventional multi-channel equipment which is used to image the solid Earth. In the water column, acoustic impedance contrasts are produced by variations in temperature and, to some extent, salinity. Acoustic impulses generated by an array of airguns suspended behind a vessel are reflected from these contrasts and recorded on long cables of hydrophones that are towed below the sea-surface. In this way, two- and three-dimensional images of thermohaline circulation can be generated. Critically, these images have equal vertical and horizontal resolutions of \textit{O}(10)~m. Here, I describe, process, and analyse a calibrated two-dimensional seismic survey from the Bellingshausen Sea of the Southern Ocean and a three-dimensional seismic survey from the Brazil-Falkland Confluence located offshore Uruguay. First, the Bellingshausen survey was designed to image the thermohaline structure across the west Antarctic shelf where warm-core eddies are reported. Processed and calibrated seismic images reveal the detailed thermohaline structure of Circumpolar Deep Water. Many warm-core eddies are observed, which have diameters of 1--12~km and thicknesses of 100--200~m. Pre-stack analysis demonstrates that this eddy field is being advected onto the shelf at speeds of \textit{O}(0.1)~m~s$^{-1}$. An iterative inverse modelling procedure is used to convert reflectivity into temperature and salinity, which confirms that the eddies have anomalously warm centres (i.e. $\sim$1$^{\circ}$C). These results have significant implications for ice shelf melting. Secondly, the Uruguay survey is used to investigate a large-scale frontal system. Although this system has been studied using hydrographic methods, these studies either have limited spatial resolution or have restricted depth penetration. The three-dimensional seismic survey, which was acquired in a `racetrack' pattern, permits the volume to be interrogated. Since the frontal system migrates southwestwards at a speed of \textit{O}(10)~km~day$^{-1}$, this survey is time-lapse in nature. Processed images reveal a band of dipping reflections that extend to depths of $\sim$2000~m. These reflections represent the frontal interface between the Brazil and Falkland currents. Physical oceanographic properties are calculated for images that cross this front. On the warm side of the front, the water mass is characterised by flat and continuous reflectivity. On the cold side of the front, the water mass is characterised by deformed reflectivity on all scales. Pre-stack analysis suggests that near-surface flow at the frontal interface is convergent. Between 0.5 and 1~km depth, a substantial eddy that is 30~km long and 250~m thick is visible on the cold side of the front. Detailed mapping suggests that this eddy grew and decayed over a period of 6~days. Its observed scale and duration are inconsistent with analytical and numerical studies of intra-thermocline eddies. Nevertheless, its duration is consistent with scaling arguments of frictional spin-down. Spatial and temporal distributions of mixing rates (i.e. diapycnal diffusivities) are estimated by spectrally analysing vertical displacements of automatically tracked reflections. Both internal wave and turbulent regimes are identifiable. Recovered diapycnal diffusivities are of \textit{O}($10^{-6}$--$10^{-2.2}$)~m$^{2}$~s$^{-1}$, consistent with hydrographically determined estimates. Mixing is suppressed and enhanced on the warm and cold sides of the front, respectively. Seismic Oceanography has considerable potential to quantify aspects of thermohaline circulation on multiple scales.

As ocean ecosystems continue to deteriorate in the face of human induced pressures, marine management professionals are increasingly being urged to predict the impacts of various activities on ocean ecosystems. Many ecosystem interactions are still not adequately understood, so managers often turn to scientists to provide data and analysis on impacts resulting from specific actions. One important physical ocean process in need of more empirical data is microscale turbulence. Because it is responsible for mixing across isopycnal surfaces in stratified waters, turbulence is important in many physical, chemical and biological processes in the ocean. An elementary description of turbulence and mixing is presented along with a summary of the role of turbulence in marine ecosystems. In order to be of use to scientists, turbulence must be measured over large areas of the ocean. This paper presents a discussion of techniques for measuring turbulence. Measurements of turbulence are specialized and costly. A new microstructure data acqusition system was developed to acquire microstructure data eight times faster than present methods allow. The design details of the high-speed microstructure data acquisition system called MicroSoar are presented along with some preliminary data obtained from its deployment on actual cruises. / Graduation date: 1998

Thesis (Ph. D.)--University of Wyoming, 2006. / Title from PDF title page (viewed on Nov. 29, 2006). Includes bibliographical references (p. 202-203).