Thesis advisor: Yvette Kuiper / 40Ar/39Ar single-grain total-fusion ages of muscovite and biotite and one 40Ar/39Ar furnace step-heating age of hornblende from the Tadmuck Brook Schist, Nashoba Formation, and Ball Hill mylonite zone are used to reconstruct the late tectonic and metamorphic history of the Nashoba terrane in eastern Massachusetts. The data fall into three age populations. Age population I (~376-330 Ma) is interpreted as cooling after a migmatization event in the Nashoba terrane, population II (~300 Ma) may be associated with normal movement on the Clinton-Newbury fault, and population III (~267 Ma) is possibly related to cooling of the Rocky Pond Granite. No younger Alleghanian overprint was observed. / Thesis (MS) — Boston College, 2012. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Intra-continental mountain belts typically form as a result of tectonic forces associated with distant plate collisions. In general, each mountain belt has a distinctive morphology and orogenic evolution that is highly dependent on the unique distribution and geometries of inherited structures and other crustal weaknesses. In this thesis, I have investigated the complex and irregular Cenozoic orogenic evolution of the Central Kyrgyz Tien Shan in Central Asia, which is presently one of the most active intra-continental mountain belts in the world. This work involved combining a broad array of datasets, including thermochronologic, magnetostratigraphic, sediment provenance and stable isotope data, to identify and date various changes in tectonic deformation, climate and surface processes. Many of these changes are linked and can ultimately be related to regional-scale processes that altered the orogenic evolution of the Central Kyrgyz Tien Shan. The Central Kyrgyz Tien Shan contains a sub-parallel series of structures that were reactivated in the late Cenozoic in response to the tectonic forces associated with the distant India-Eurasia collision. Over time, slip on the various reactivated structures created the succession of mountain ranges and intermontane basins which characterises the modern morphology of the region. In this thesis, new quantitative constraints on the exhumation histories of several mountain ranges have been obtained by using low temperature thermochronological data from 95 samples (zircon (U-Th)/He, apatite fission track and (U-Th)/He). Time-temperature histories derived by modelling the thermochronologic data of individual samples identify at least two stages of Cenozoic cooling in most of the region’s mountain ranges: (1) initially low cooling rates (<1°C/Myr) during the tectonic quiescent period and (2) increased cooling in the late Cenozoic, which occurred diachronously and with variable magnitude in different ranges. This second cooling stage is interpreted to represent increased erosion caused by active deformation, and in many of the sampled mountain ranges, provides the first available constraints on the timing of late Cenozoic deformation. New constraints on the timing of deformation have also been derived from the sedimentary record of intermontane basins. In the intermontane Issyk Kul basin, new magnetostratigraphic data from two sedimentary sections suggests that deposition of the first Cenozoic syn-tectonic sediments commenced at ~26 Ma. Zircon U-Pb provenance data, paleocurrent and conglomerate clast analysis reveals that these sediments were sourced from the Terskey Range to the south of the basin, suggesting that the onset of the late Cenozoic deformation occurred >26 Ma in that particular range. Elsewhere, growth strata relationships are used to identify syn-tecotnic deposition and constrain the timing of nearby deformation. Collectively, these new constraints obtained from thermochronologic and sedimentary data have allowed me to infer the spatiotemporal distribution of deformation in a transect through the Central Kyrgyz Tien Shan, and determine the order in which mountain ranges started deforming. These data suggest that deformation began in a few widely-spaced mountain ranges in the late Oligocene and early Miocene. Typically, these earlier mountain ranges are bounded on at least one side by a reactivated structure, which probably corresponds to the frictionally weakest and most suitably orientated inherited structures for accommodating the roughly north-south directed horizontal crustal shortening of the late Cenozoic. Moreover, tectonically-induced rock uplift in the Terskey Range, following the reactivation of the bounding structure before 26 Ma, likely caused significant surface uplift across the range, which in turn lead to enhanced orographic precipitation. These wetter conditions have been inferred from stable isotope data collected in the two magnetostratigraphically-dated sections in the Issyk Kul basin. Subsequently, in the late Miocene (~12‒5 Ma), more mountain ranges and inherited structures appear to have started actively deforming. Importantly, the onset of deformation at these locations in the late Miocene coincides with an increase in exhumation of ranges that had started deforming earlier in the late Oligocene‒early Miocene. Based on this observation, I have suggested that there must have been an overall increase in the rate of horizontal crustal shortening across the Central Kyrgyz Tien Shan, which likely relates to regional tectonic changes that affected much of Central Asia. Many of the mountain ranges that started deforming in the late Miocene were associated with out-of-sequence tectonic reactivation and initiation, which lead to the partitioning of larger intermontane basins. Moreover, within most of the intermontane basins in the Central Kyrgyz Tien Shan, this inferred late Miocene increase in horizontal crustal shortening occurs roughly at the same time as an increase in sedimentation rates and a significant change sediment composition. Therefore, I have suggested that the overall magnitude of deformational processes increased in the late Miocene, promoting more flexural subsidence in the intermontane basins of the Central Kyrgyz Tien Shan. / Intrakontinentale Gebirge sind typischerweise das Ergebnis tektonischer Kräfte, die auf entfernte Plattenkollisionen beruhen. Im Allgemeinen hat jedes Gebirge sein charakteristisches morphologisches Erscheinungsbild und seine eigene und einzigartige Entstehungsgeschichte, die zum Großteil von der Verteilung und der Geometrie vorgeprägter Strukturen und anderer Schwächzonen innerhalb der Erdkruste abhängt. In der vorliegenden Arbeit habe ich die komplexe känozoische Gebirgsbildung des zentral-kirgisischen Tian Shan Gebirges, eines der weltweit aktivsten intrakontinentalen Gebirge, untersucht. Diese Arbeit kombiniert verschiedenste Datensätze, darunter thermochronologische und magnetostratigraphische Daten, Sedimentprovenienzen und stabile Isotopenzusammensetzungen, um Änderungen der tektonischen Deformationsprozesse sowie Klima- und Oberflächenveränderungen zu erkennen und gegebenenfalls zu datieren. Viele dieser Veränderungen sind eng miteinander verknüpft und können letztendlich auf regionale Prozesse zurückgeführt werden, die die Entwicklung des zentral-kirgisischen Tian Shan beeinflussen. Das Tian Shan Gebirge besteht aus einer subparallelen Folge einzelner Gebirgsrücken und deren Strukturen, welche im späten Känozoikum als Reaktion auf die entfernt stattfindende Indo-Eurasische Kollision reaktiviert wurden. Im Laufe der Zeit haben Deformation und Versatz entlang dieser reaktivierten Strukturen eine Abfolge von individuellen Gebirgszügen und dazwischen liegenden Sedimentbecken geschaffen deren Morphologie prägend für die heutige Region ist. In dieser Arbeit wurden neue quantitative Altersbestimmungen zur Exhumationsgeschichte mehrerer Gebirgszüge durch thermochronologische Auswertungen an 95 Gesteinsproben durchgeführt (ZHe, AFT und AHe). Die aus Modellierungen einzelner thermochronologischer Datensätze gewonnenen Temperaturgeschichten lassen für die meisten untersuchten Gebirgszüge mindestens zwei Abschnitte känozoischer Abkühlung erkennen: (1) anfänglich niedrige Abkühlungsraten (<1°C/Myr) während einer tektonische Ruhephase und (2) stärkere Abkühlung im späten Känozoikum, die in den verschiedenen Gebirgsketten diachron und mit unterschiedlicher Intensität einsetzt. Diese zweite Abkühlungsphase kann durch einen Anstieg der Erosionsraten durch aktive Deformation interpretiert werden und stellt für viele der untersuchten Gebirgszüge die erste verfügbare Alterabschätzung spätkänozoischer Deformation dar. Neue Deformationsalter wurden weiterhin aus den Sedimenten intermontaner Becken gewonnen. Im intermontanen Issyk Kul Becken lassen neue magnetostratigraphische Daten zweier Sedimentabschnitte vermuten, dass die Ablagerung der ersten syntektonischen Sedimente im Känozoikum um ca. 26 Ma begann. Weiterhin zeigen Zirkon-Provenienzen, Paläoströmungsrichtungen sowie Klastenanalysen konglomeratischer Sedimente, dass diese Sedimente aus der Terskey Range südlich des Beckens stammen, was vermuten lässt, dass der Beginn der spätkänozoischen Deformation in diesem Teil des Gebirgszuges älter als 26 Ma ist. In anderen Bereichen wurden sedimentäre Wachstumsstrukturen zur Identifikation syntektonischer Ablagerung herangezogen, um somit den Zeitpunkt nahe gelegener Deformation zu bestimmen. Zusammengenommen haben meine Beobachtungen und Auswertungen ermöglicht, die räumlichen und zeitlichen Deformationsmuster quer durch das zentral-kirgisischen Tian Shan Gebirge zu erschließen um eine zeitliche Abfolge in der Entstehung und Entwicklung einzelner Gebirgszüge zu entwickeln. Meine Daten lassen vermuten, dass die Deformation in einigen wenigen, weit auseinander liegenden Bergketten im Spätoligozän bis Frühmiozän begann. Typischerweise sind diese frühen Gebirgsketten auf mindestens einer Seite an eine reaktivierte Struktur gebunden. Diese sind die wahrscheinlich schwächsten oder am besten orientierten Strukturen, um die annähernd Nord-Süd gerichtete Einengung im späten Känozoikum aufzunehmen. Darüber hinaus ist es sehr wahrscheinlich, dass die tektonische Gesteinshebung innerhalb der Terskey Range, entlang reaktivierter Störungen vor 26 Ma, eine signifikante Topographiezunahme zur Folge hatte. Dies führte höchstwahrscheinlich zur Ausbildung einer orographischen Barriere und der damit verbundenen Verstärkung der Regenfälle im Becken nördlich des Rückens. Diese Bedingungen konnten mithilfe stabiler Isotopenzusammensetzungen entlang der zwei magnetostratigraphisch datierten Sedimentprofile im Issyk Kul Becken nachgewiesen werden. Während des späten Miozäns (~12‒5 Ma) begann zeitnah die aktive Deformation und Heraushebung mehrerer neuer Gebirgsrücken. Wichtig dabei erscheint, dass der Zeitpunkt dieser spätmiozänen Deformation mit einem Exhumationsschub derer Gebirgszüge zusammenfällt, die schon viel früher (Spätoligozän bis Frühmiozän) mit der Deformation begannen. Aufgrund dieser Beobachtungen habe ich vorgeschlagen, dass es einen generellen Anstieg der Einengungsraten im Tian Shan gegeben haben muss, welcher auf regionale tektonische Veränderungen zurückzuführen ist die große Teile Zentralasiens betrafen. Viele der Gebirgsrücken, die initial im späten Miozän herausgehoben wurden, sind durch unsystematische, tektonische Prozesse der Reaktivierung und Initialisierung von Strukturen (out-of-sequence) entstanden, die zur Teilung vormals großer, zusammenhängender Sedimentbecken führte. Darüber hinaus weisen die meisten intermontanen Becken im zentral-kirgisischen Tian Shan, in etwa zur Zeit der beobachteten, verstärkten Einengung im Spätmiozän, ebenfalls erhöhte Sedimentationsraten und eine signifikante Änderung der Sedimentzusammensetzung. Daher vermute ich, dass die allgemeine Intensität der Deformation im Spätmiozän zunahm, was eine tektonische Absenkung (flexural subsidence) in den intermontane Becken des zentral-kirgisischen Tian Shan Gebirges zur Folge hatte.

Thesis (Ph. D.)--University of Alberta, 2010. / Title from pdf file main screen (viewed on June 28, 2010). A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Geophysics, Department of Physics, University of Alberta. Includes bibliographical references.

Scotland is one of the most valuable regions available for geologic study, as it has been a breeding ground for the discovery and development of many fundamental concepts from the earliest studies in the field through today. Scotland has traditionally been viewed, in a broad sense, as the amalgamation of two components: the eroded remnants of the Caledonide Orogen north of the Highland Boundary Fault (HBF), and the post-Caledonian Old Red Sandstone (ORS) to the south. Studies based in the Scottish Caledonides and the ORS have provided a host of concepts that we now deem fundamental, but much of that has been the byproduct of effort to understand how they were juxtaposed along the HBF. The metamorphosed strata of the Grampian Terrane (GT) lie against pillow basalts and minor sediments associated with the Highland Border Complex (HBC), and undeformed fluvial deposits of the ORS near the Highland Border. The incompatibility of lithologies, but also palaeontologic and radiometric ages, on either side of the fault was seemingly inexplicable, and coined the term “the Highland Border Paradox”. The Highland Border Paradox was used to describe the conflicting idea of continuity between the GT and HBC, despite incompatible lithologies and ages within the section. Several tectonic models have been suggested as a solution to the core of the issue, but a widely accepted solution has so far been elusive. The 40Ar/39Ar method is well-poised to investigate when the Scottish Caledonides were active, and when the ORS was deposited; each valuable in their own dimension but combined represent the best opportunity to understand the Highland Border Paradox to date. Two models exist: one which considers the Midland Valley Terrane (MVT; predominately ORS) to be relatively autochthonous relative to the northern terranes, and another that suggests the MVT is mostly allochthonous, or exotic. This dissertation is designed as a multi-pronged approach to offer an overarching understanding of the relationship between the Scottish Caledonides and the ORS, but with the intention that each chapter is a standalone contribution. We first investigate the relationship between the Grampian Terrane and the Old Red Sandstone by studying the contact that bounds them, which is along the Highland Boundary Fault. The base of the ORS is only reported to be exposed at five localities along the northern margin of the Midland Valley, but the basal unconformity is only found at Stonehaven. Outcrop exposure is not ideal in Scotland, such that the exposure of the contact between the GT and MVT is only exposed at those few localities, and physically tracing contacts between those localities is not possible. Chapter 1 is focused on exposure of the contact from the locality near Stonehaven, where we were surprised to find that no unconformity exists, and that the base of the ORS is a fault. A new age 40Ar/39Ar age of 438 Ma from biotite separated from a dike that crosscuts the Cowie Formation is over 20 Myr older than previous estimates, pushing the base of the ORS well into the Silurian. Fossils of Pneumodesmus Newmani found there, the earliest documented terrestrial and air-breathing fauna in the geologic record, must also be as old as 438 Ma. This pushes back both the timing of when air-breathing animals emerged from land, but also reinstates Stonehaven as the ideal locality to study the earliest life on land. This chapter was designed to be a manuscript for submission to Geology, or a similar journal, as it is a famous locality pertinent to a host of Caledonian studies, is commonly used for teaching, and has broad interest to the scientific community with respect to Pneumodesmus Newmani. Chapter 2 is focused on studying the physical contact between the GT and MVT at its other reported localities: Edzell (North Esk River), Callander, and Balmaha. Detailed field mapping and observations were made for each, also supplemented petrographic details from thin sections as needed. One of the most surprising findings is that, combined with observations from Stonehaven, the base of the ORS is either faulted or not exposed; there is effectively no evidence for a basal ORS unconformity. This releases the constraints that the ORS was deposited strictly after the Caledonian Orogeny, and that the ORS was deposited above the GT/HBC stack as we see it today. In addition, at each of these localities, we identify considerable evidence of faulting in the area between the GT and MVT; most affected is the intervening HBC. This is hard to reconcile with previous interpretations proposed for those localities by proponents of the autochthonous model, as it is based largely on proposed continuity at those localities. It is also difficult to reconcile with the suggestion, in that view, that the HBF only modestly displaces geology, and not responsible for the juxtaposition of the GT and MVT. Evidence at each locality for undeformed units directly juxtaposed with highly deformed rocks implies a significant amount of vertical displacement that has not previously been appreciated, in any previous account. A significant amount of vertical displacement is a characteristic of major strike-slip faults, yet previous strike-slip models for the HBF have invoked movements in a purely lateral sense. Chapter 3 aims to constraint when the GT, Northern Highland Terrane (NHT), and Hebridean Terrane (HT) were exhumed during the Caledonian Orogeny, with a particular focus on the southern region of the GT near the HBF. We employed single-step 40Ar/39Ar analysis of muscovite separated from bedrock exposed throughout the terranes north of the HBF, complementing a similar work by Dewey and Pankhurst (1970). Throughout all the terranes, these ages range from 500-420 Ma, with a concentration of ages ca. 470 Ma. Combined with previous data sets, the NHT appears to have had a younger exhumation, but if our dataset is considered alone that distinction is unclear. The second portion of Chapter 3 presents the results of step-heating 40Ar/39Ar analysis of muscovite separated from metamorphosed GT strata, sampled in transects spanning across the metamorphic zones of the GT. The purpose of the transects is to evaluate when the portion of the GT immediately against the MVT was active. The step-heating analyses range between 471-461 Ma at Stonehaven, 468-453 Ma at North Esk, and 459-447 Ma at Balmaha (combined with Callander). These ages indicate that the Caledonian Orogeny was active at least from ca. 471-447 Ma, whereas the Caledonian Orogeny was previously proposed to be unusually short (10 Myr). As these ages likely capture the latest stage of orogenesis, the actual duration is likely considerably longer, and this is also suggested by the wider range of single-step ages. It is also now difficult to envision a scenario in which the GT was a passive margin through Ordovician times, which is a widely accepted notion. Chapter 4 is designed to investigate the time at which the Midland Valley ORS was deposited, and where its sediments originated from. We obtained three ages from volcanic units interleaved throughout the ORS, including a result of 438 Ma near the base (from Stonehaven), a result of 431 Ma from the Lintrathen Porphyry near mid-section, and a result of 400 Ma at the top of the ORS near Oban. We sampled over ten volcanic units interleaved within the ORS, but most ultimately were unsuitable for age analysis. Despite only obtaining three ages, it is now clear that at least the onset of ORS sedimentation is significantly older than previous estimates, now as far back as 438 Ma, whereas it was previously considered to be mostly Devonian. Considering that the age from Lintrathen at midsection is only 6 Myr younger, and still Silurian, it is possible that a majority of the Midland Valley LORS is Silurian, and deposited within a much more narrow timeframe than previously suggested. The result of 399 Ma from Oban confirms the previous suspicion that the ORS near Oban is unrelated to the ORS in the Midland Valley. Detrital analyses from the Midland Valley ORS indicate a source that ranges in age from mainly 480-420 Ma, which effectively overlaps the Scottish source ages obtained in Chapter 3. This is at odds with a previous hypothesis that suggested the ORS was sourced from large river systems from Scandinavia (including the Western Gneiss Region), analogous to the Himalayan drainages today. In combination, the depositional ages (437 and 431 Ma) and range of detrital ages (480-420 Ma), suggest that the ORS was locally related to the Scottish Caledonides, rather than an exotic origin. So, while it is now clear that displacement along the HBF is more substantial than previously conceived, that displacement was not significant enough to isolate the ORS from a Scottish source.

Granulite-facies orthogneisses of the Mesoproterozoic Albany-Fraser Orogen from the locality of Bremer Bay, in southwestern Australia, record at least three phases of widespread, pervasive NW- and NE-trending bidirectional extension that alternate with shortening and/or shear related structures. Crustal extension occurred ca. 1180 Ma, based on SHRIMP U–Pb zircon geochronology of melts generated during deformation, which coincided with Stage II (1215-1140 Ma) of the Albany-Fraser Orogeny, a period of NW-directed contraction. Eight different deformation phases can be recognized in the Bremer Bay area: (1) formation of a pervasive migmatitic fabric, defined by alternating leucosomes and melanosomes, parallel to the main compositional layering, and axial planar to localized isoclinal folds of cm-wide melt bands; (2) first bidirectional extension phase, which formed cm-scale square boudins of mafic layers parallel to the main migmatitic fabric; (3) formation of open to isoclinal, upright to overturned, SW-plunging, NW-verging m-scale folds of early square and rectangular boudins and dominant migmatitic foliation; (4) renewed coeval NE- and NW-directed extension that produced intermediate (< 1 meter to a few meters) boudins of the migmatitic fabric and compositional layering; (5) formation of regional-scale, NW-verging, SW-plunging overturned folds of all previous structures; (6) third phase of bidirectional extension that formed large, decameter-scale boudins of the migmatitic fabric; (7) late folding phase that resulted in the formation of m-scale open to tight, SW-plunging, upright to moderately overturned, NW-verging folds; and (8) fracturing related to the intrusion of dominantly N-NW- and N-NE-trending intermediate and felsic few cm- to few dm-wide pegmatite veins. Melt generation was concurrent with all stages of deformation. The Albany-Fraser Orogen is reinterpreted as a diachronous orogen, resulting from the closure of the asymmetrically shaped ocean basin between the West Australian and Mawson cratons, which widens considerably from NE to SW along the length of the orogenic front. Subduction on the western side of the orogen was the driving force for NW-directed collision during Stage II of the orogeny. Slab breakoff and orogenic collapse following closure of an intracratonic ocean basin could account for the multiple phases of bidirectional extension, granulite facies metamorphism and pervasive partial melting throughout deformation. / text

Abstract Orogenic gold deposits from the Reefton goldfield in New Zealand hosted in Ordovician metasediments of the Greenland group have produce 67 tons of gold before 1951. The Blackwater mine in Waiuta account for about 1/3 of the gold production at Reefton prior 1951. The ore system at Blackwater consist of NE trending steeply dipping gold-bearing quartz veins (Birthday reef) occurring in faulted, sheared and folded alternating sequence of sandstone-mudstone metamorphosed to low greenschist facies and hydrothermally altered proximal to distal from the quartz vein. Host rock and ore forming fluids interaction resulted in a systematic change in the mineralogy and geochemistry of the wallrock developing a distinctive footprint of the ore system. The mineral assemblage subsequent to hydrothermal alteration is formed by quartz veining, chlorite, carbonates (minor calcite-dolomite-ankerite-siderite), albite, K-Mica and composite quartz-carbonate veining, carbonates spotting, pyrite, arsenopyrite, chalcopyrite, cobaltite, galena and in a lesser extent ullmannite, gersdorffite, pentlandite, millerite and sphalerite. Mass balance calculation based on geochemical data obtained by ultra-low detection analysis with a detection limit in part per trillion of Au, As and Sb provide new insight in the geochemical footprint of the ore system at Blackwater. A clear zone of roughly 40 meters (20 meters above and below the birthday reef) is enriched in Au, As and Sb up to respectively 6806%, 605% and 891% compared to the un-mineralised protolith. Furthermore, mass changes in K2O and Na2O indicate a consistent decrease in Na and increase in K in the vicinity of the Birthday reef reflecting the replacement of albite by K-mica. This is corroborated by pattern of alkali alteration index Na/Al for albite and 3K/Al for K-Mica showing similar trend. Carbonation and de/-hydration index also exhibits peaks in samples adjacent to the Birthday reef, though carbonation index is also influenced by carbonates content in the protolith or late carbonation that may not related to gold mineralisation. Using the indicators above-mentioned it is possible to define the mineralogical and geochemical “footprint” for the ore system in the host rock allowing to use this footprint as a tool for mineral exploration for orogenic gold deposits similar to Blackwater. Given that the geochemical footprint of orogenic gold deposit such as Blackwater is significantly wider than the economically viable part of the deposit defining the footprint of the ore system offers the potential for vectoring from sub-economic mineralisation towards higher-grade ore that is economically viable.

The Fäboliden gold deposit is an ore body in northern Sweden’s Bothnian Basin and has been the subject of studies and test mining since the early 2000s when the Gold Line, an area of anomalously high-Au glacial till in Northern Sweden, became a center of economic interest. The deposit is a hypozonal orogenic gold deposit that displays many characteristic features of ore bodies of this type, including the presence of compound sulfide grains composed of a core of löllingite surrounded by a rim of arsenopyrite, and an abundance of pyrrhotite throughout the deposit and surrounding alteration zone. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used to first map the distribution of trace elements in several of the arsenpyrite-löllingite grains, then to perform spot analyses of pyrrhotite grains in samples from across the distal and proximal alteration zones of the deposit. The maps of the trace elements in the compound löllingite-arsenopyrite grains show that: As and Au are found in greater abundance in the löllingite than in the arsenopyrite; Cu, Fe, S, and Ti are found in greater abundance in the arsenopyrite than in the löllingite; and Ag, Au, Bi, La, Mn, Pb, Sr, Ti and Tl are found in zones of secondary enrichment along fractures within the grains. Uranium and V may also be enriched along fractures, although this isn’t clear on all of the maps. Gold is an element of particular interest, because its distribution throughout the sulfide phases can be used to constrain the mechanism and relative timing of mineralization within the deposit. The presence of invisible gold within the löllingite, but not within the arsenopyrite, shows that gold is not incorporated into arsenopyrite at high temperatures and will instead be concentrated in the löllingite core of the composite grain and at the margin between the two sulfide phases as the löllingite is altered to arsenopyrite. Previous research on the Fäboliden gold deposit, including geothermometric analysis of vein-hosted graphite within fluid inclusions and garnet-biotite geothermometry as well as structural evidence provided by regional deformation, indicate that mineralization occurred post-peak metamorphism. The textures seen are therefore not conclusive of mineralization occurring syn- or pre-peak metamorphism, as has previously been proposed based on research of orogenic gold deposits in Western Australia. The spot analysis of pyrrhotite samples from across the deposit shows a distinct decrease in Ni and Co content in the proximal alteration zone, suggesting uptake of these elements by other minerals such as the löllingite and arsenopyrite. Multiple analyses performed on single grains show local variation, but are insufficient to establish the presence or determine the character of growth zonation within pyrrhotite.

Polyphase structural evolution of superstructure and infrastructure in orogenic zones Proterozoic basement rocks of the Teplá-Barrandian Unit (TBU) are affected by two main tectono-metamorphic events. The central and SW part of the TBU is a well-preserved relict of Cadomian episode. On the other hand, the western margin of the TBU shows superposition of polyphase early-varicsan deformation and metamorphism onto the pre- variscan fabric. The Střela river profile in the northern part of Teplá Crystalline Complex (TCC) exposes a continuous crustal section through western margin of the TBU from the low-grade phyllites (near biotite izograd) in the east to the high-grade rocks of kyanite zone at the contact with high-pressure Mariánské-Lázně Complex (MLC). Three main deformation events were distinguished in the studied area and the cross-section is interpreted as a fossil (devonian) suprastructure-infrastructure transition zone preserved in the carboniferous TBU superstructure. The oldest pre-variscan D1 phase produced flat-lying metamorphic foliation showing normal metamorphic zonation from the very low-grade in the upper part to at least garnet zone in the structurally lower part. Large scale upright folding of prevariscan foliation S1 occurred during early-variscan D2 event. Tight F2 folds were...

The Early Permian strata of the Hongliuhe Group, NW China, experienced a thin-skinned fold-and-thrust belt style of deformation that recorded the final stages of amalgamation of the Beishan orogenic collage, a part of the Central Asian Orogenic Belt. The Hongliuhe Group was syn-orogenically deposited on an undetermined foreland, with the Mazongshan arc terrane acting as the hinterland. In this study results from detailed mapping combined with a regional analysis elucidate involvement of a northward-dipping subduction system with the collision. Well-preserved fold-and-thrust belt style deformation mapped in the upper stratigraphy of the Hongliuhe Group exhibits dominantly south-southeast verging structure, including shear folding, low-angle thrust ramping, imbrication and duplexing. Restoration of a portion of a mapped outcrop-scale cross-section estimates the accommodation of a minimum of 24% shortening. Lower stratigraphy shows discrete, steeper, north-over-south dip-slip ductile shear zones that bound packages of less deformed Hongliuhe Group strata. Fault displacement is considered to have been prolonged enough to juxtapose basal formations in northerly hangingwalls against upper formations in southerly footwalls. Faulting is closely associated with the creation of large-scale brittle-ductile eye-fold structures that are postulated to be sheath folds. The most examined and mapped structure, 16km wide, is a synclinal structure with axes plunging steeply towards its center. The ellipticity of the exposed bedding traces increases towards the center of the eye-fold, implying a structural relationship with metamorphic shear zones. Except for large-scale folding, the bulk of its strata remain relatively undeformed and have preserved primary soft-sediment deformation structures indicating younging towards the center on both limbs of the synclinal structure. Stratigraphic reconstruction of the Hongliuhe Group that considers the significant faulting shows that the Group's basal conglomerates unconformably overlie a Late-Carboniferous volcanic assemblage. The clast lithotypes of the conglomeratic successions change from polymictic metamorphic rocks at the base to monomictic granitoid clasts mid-section, showing the gradual unroofing sequence of the provenance. The stratigraphic reconstruction shows a general fining upward sequence, transitioning from terrestrial to nearshore marine depositional environments that, and in conjunction with the conglomeratic successions, suggests that the tectonic setting for deposition of the Hongliuhe Group is a foreland basin. Considering the deformation styles reported in this study, the Hongliuhe Group is interpreted to be a foreland fold-and-thrust belt. Stratigraphic reconstruction of the Hongliuhe Group that considers the significant faulting shows that the Group’s basal conglomerates unconformably overlie a Late Carboniferous volcanic assemblage. The clast lithotypes of the conglomeratic successions change from polymictic metamorphic rocks at the base to monomictic granitoid mid-section, showing the gradual unroofing sequence of the provenance. The stratigraphic reconstruction shows a general fining upward sequence through nearshore depositional environments that, and in conjunction with the conglomeratic successions, give interpretation that the tectonic setting for deposition of the Hongliuhe Group is a foreland basin. Considering the deformation styles reported in this study the Hongliuhe Group is interpreted to be a foreland fold-and-thrust belt.

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy