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The influence of anthropogenic activity on the natural environment is constantly changing. A series of major developments in human culture have resulted in a shifting nature of impact. Separating change attributable to humans and the change resulting from natural forcing is complex. This study investigates the degree of human impact during the onset of agriculture when humans were shifting from a hunter-gatherer lifestyle to herding livestock and the cultivation of plants. This cultural development is known as the Mesolithic-Neolithic Transition within Europe. In particular, this project focuses on the nature of environmental change in Cumbria in the British Isles during the mid-Holocene. This region exhibits strong contrasts in landscape from coastal lowlands to mountainous uplands. Cumbria also has a rich record of archaeological sites and environmental reconstructions, but existing datasets have not allowed for detailed comparisons of the different landscapes. Two contrasting sites (one upland, one lowland) were investigated to produce a high-resolution environmental reconstruction including: vegetation change, burning patterns, catchment erosion and climatic changes. A radiocarbon chronology was produced for each site investigated. This was used to re-address the archaeological record and in particular, determine the details of the impact of humans on the landscape. Key differences are highlighted in the nature of human impact during the late-Mesolithic and early-Neolithic in contrasting landscapes with different types of land-use. There is an estimated temporal offset of around 200 years between similar events occurring in lowland and upland landscapes. Climatic variability indicates only small fluctuations and is unlikely to account for the extent of vegetation modification on its own. It is clear Neolithic activity is far more intensive than Mesolithic activity, but importantly the scale of impact in the upland landscape is far more extensive than the archaeological evidence would suggest. Furthermore, the upland landscape appears to recover relatively quickly after clearance events, whilst in the lowland environment, the open vegetation landscape remains far more dominant.

A palaeolimnological study was carried out on a high-resolution, 7.62 m-long core (RU188-07) from northern Lake Rotorua, North Island. The core consists predominantly of olive diatomaceous ooze, laminated in places, and contains five tephras including Tarawera (1886 A.D.), Kaharoa (c. 1314 A.D.), Taupo (c. 233 A.D.) and Whakatane (c. 5500 cal. years B.P.). The core terminated in Whakatane Tephra giving the sediment a maximum age of 5530 60 cal. years B.P. An age model for the sediment was developed using tephrochronology. Radiocarbon dates obtained on the sediment returned ages too old because of contamination by old CO2 or CH4, or both. Investigations carried out on the core included spectrophotometric, sedimentological and geochemical analyses, and diatom identifications, which provided a number of proxies from which inferences were made about lake history, catchment development, and palaeoclimate since c. 5500 cal. years B.P. The laminations, evident only in the upper, post-Kaharoa Tephra part of the record, comprise alternations of thin, dark, detrital deposits and pale, relatively fine-grained diatom assemblages. Sediment geochemistry indicates that the Rotorua catchment has undergone several changes since c. 5500 cal. years B.P., alternating between periods of variable and stable environmental conditions. Following the Whakatane and Waimihia eruptions and up to approximately 3000 cal. years B.P., the catchment surrounding Lake Rotorua was rather unstable. Fluctuations in many of the proxies during this period are likely to be associated with a variable climate with periods of storminess, coinciding with the establishment of ENSO conditions in New Zealand. A notable feature of the record is two phases of stability, the first following the Taupo eruption (from c. 1700 cal. years B.P. to c. 630 cal. years B.P.) and the second from c. 580 cal. years B.P. to c. 300 cal. years B.P. The latest, most significant event in the catchment history of Lake Rotorua was the settlement by Polynesians. M.S. McGlone implied from pollen profiles (from Holden's Bay) that initial settlement took place around the time of the Kaharoa eruption (c. 630 cal years B.P.; c. 1314 A.D.), but the sediment chemistry and erosion profiles obtained here, from the northern part of Lake Rotorua, indicate that although there may have been some early clearing in the northern catchment for tracks or buildings, large-scale clearing in the area probably did not occur until considerably later, c. 300 cal. years B.P. Also contained within the sediments are three layers of reworked tephric material that probably originate from the transfer of coarse grained tephra from shallow to deeper water during large storms at c. 1300 cal. years B.P, c. 520 cal. years B.P, and c. 220 cal. years B.P. Each event coincides with storm events inferred from records from Lake Tutira in eastern North Island. Because of Lake Rotorua's inland position, these inferred storm events probably represent only the largest cyclonic events (e.g. ex-tropical cyclones).

Diatom analysis performed on sediment profiles from several localities provided information on past changes in the aquatic environment related to climatic and artificial shifts since the Last Glacial-Interglacial Transition. The practicality of diatom analysis from fish guts of three European fish species in palaeolimnological studies was tested.

This thesis presents the results of contemporary limnological and palaeolimnological investigations of a series of crater lakes in order to reconstruct the palaeoenvironmental history of western Uganda, East Africa. The research examines questions of spatial and temporal heterogeneity of climate changes in the context of growing human impacts on the landscape over the last millennium. Sediment records from two lakes, Nyamogusingiri and Kyasanduka within the Queen Elizabeth National Park (QENP) were investigated to look at the long term records of climate and environmental change (spanning the last c. 1000 years). Five shorter cores across a land-use gradient were retrieved to assess the impact of human activity on the palaeoenvironmental record over the last ~150 years. High-resolution (sub-decadal), multiproxy analyses of lake sediment cores based on diatoms, bulk geochemistry (C/N and δ13C) and sedimentary variables (loss-on-ignition, magnetic properties and physical properties) provide independent lines of evidence that allow the reconstruction of past climate and environmental changes. This multiproxy approach provides a powerful means to reconstruct past environments, whilst the multi-lake approach assists in the identification and separation of local (e.g. catchment-scale modifications and groundwater influences) and regional effects (e.g. climatic changes). The results of a modern limnological survey of 24 lakes were used in conjunction with diatom surface sediment samples (and corresponding water chemistry) from 64 lakes across a natural conductivity gradient in western Uganda (reflecting a regional climatic gradient of effective moisture) to explore factors controlling diatom distribution. The relationships between water chemistry and diatom distributions were explored using canonical correspondence analysis (CCA) and partial CCA. Variance partitioning indicated that conductivity accounted for a significant and independent portion of this variation. A transfer function was developed for conductivity (r2jack = 0.74). Prediction errors, estimated using jack-knifing, are low for the conductivity model (0.256 log units). The final model was applied to the core sediment data.This study highlights the potential for diatom-based quantitative palaeoenvironmental reconstructions from the crater lakes in western Uganda. Sedimentary archives from the Ugandan crater lakes can provide high-resolution, annual to sub-decadal records of environmental change. Whilst all of the lakes studied here demonstrate an individualistic response to external (e.g. climatic) drivers, the broad patterns observed in Uganda and across East Africa suggest that the crater lakes are indeed sensitive to climatic perturbations such as a dry Mediaeval Warm Period (MWP; AD 1000-1200) and a relatively drier climate during the main phase of the Little Ice Age (LIA; c. AD 1500-1800); though lake levels in western Uganda do fluctuate, with a high stand c. AD 1575-1600). The general trends support the hypothesis of an east to west (wet to dry) gradient across East Africa during the LIA, however, the relationship breaks down and is more complex towards the end of the LIA (c. AD 1700-1750) when the inferred changes in lake levels at Nyamogusingiri and Kyasanduka are synchronous with changes observed at Lakes Naivasha (Kenya) and Victoria and diverge from local lake level records (from Edward, Kasenda and Wandakara). Significant changes in the lake ecosystems have occurred over the last 50-75 years, with major shifts in diatom assemblages to benthic-dominated systems and an inferred increase in nutrient levels. These changes are coincident with large sediment influx to the lakes, perhaps as a result of increasing human activity within many of the lake catchments.

This thesis uses palaeolimnological records to reconstruct Holocene ontogeny trends from four lakes in south western Greenland. The research addresses four hypotheses investigating how Holocene lake ontogeny trends vary under different climatic settings, how long-term changes in ontogeny relate to periods of established climatic change in the region, the similarities between proxies within the lakes and between the lakes, and the role of vegetation in lake ontogeny. The study region occupies the widest ice-free area of south western Greenland and is characterised by a climatic gradient. The area inland and nearer to the ice-margin is arid, receives less precipitation and is warmer relative to the coastal areas. A paired lake approach, using lake records from two inland lakes and two coastal lakes, was adopted to examine the role of climatic setting upon lake development trajectories. Specifically, diatoms were used to reconstruct DI-alkalinity from the lakes using a DI-alkalinity model created from existing training sets in the region (WA Cla model, r2boot = 0.76, RMSEP = 0.28 log alkalinity units), sedimentary pigments to investigate trends in production and sedimentary parameters to reconstruct organic and minerogenic accumulation rates. All four lakes experienced comparable Holocene long-term ontogeny trajectories; maximum alkalinity in the first ~ 1000 cal. year BP of deglaciation followed by maximum production during the peak of Holocene Thermal Maximum (HTM) warming (~7000 -6000 cal. years BP). Following the HTM, all lakes demonstrated oligotrophication and a decline in pH. Vegetation development and catchment stabilisation at the end of the HTM may be important in determining the onset of oligotrophication in vegetated catchments. However, the impact of vegetation development on lake ontogeny cannot be isolated from the changes in the lakes associated with the colder and wetter climate which occurred at the end of the peak HTM warming. The timings of the large transitions in the ontogeny trajectories are comparable with established periods of Holocene climatic variability in the region; climate forcing drives ontogeny in these lakes. However, there are short-term differences between the lakes indicating that lakes have different thresholds of ecological change and may respond differently to the same climate forcing. It is concluded that ontogeny is driven by climate but lakes may respond differently to forcing depending on catchment specific characteristics which can filter out the climate signal or cause climate to influence the lake in a more direct way.

<p>This thesis presents palaeoenvironmental data from equatorial Africa covering two important time intervals; i) the warming period forming the Pleistocene/Holocene transition and ii) the last millennium. The Empakaai Crater, in northern Tanzania contains a lake from where sediment cores, spanning two time-slices 14.8-9.3 ka and 800-2000 AD, have been studied. Palaeoecological and palaeohydrological reconstruction is based on a multitude of proxies from the sediments, representing both catchment environment and the lakes aquatic ecosystem response. Between 14.8 and 10 ka the catchment vegetation and lake hydrology responded to both regional climate changes and local environment, but with different amplitude and frequency, reflecting temporal and spatial lags between the two systems. However, at c 10 ka both lake conditions and catchment vegetation showed drastic changes towards drier conditions. The record covering the last millennium reveals environmental changes related to climate and human activities. The catchment’s vegetation was affected by frequent fires, most probably human induced, while near shore vegetation responded to lake level fluctuation associated with rainfall variability. About 15 km from Empakaai Crater is an extensive abandoned irrigation system, the Engaruka complex, which was in active use between c 1400 AD and 1840 AD. By comparing a number of social and environmental factors potentially influencing the societal development at Engaruka it is shown that wet climate conditions have had positive effects on the societal development but also that dry climate conditions were not always disastrous to the society. The resemblance of the pollen taxa present is strong between the two time slices and pollen representing catchment conditions respond in similar manner in both records. The lake conditions are however very different between the two periods Thus the lake responds to both long and short term changes of variable amplitude, while the catchment vegetation seems to responds to high amplitude, low frequency changes.</p>

The Tibetan Plateau is the largest elevated landmass in the world and profoundly influences atmospheric circulation patterns such as the Asian monsoon system. Therefore this area has been increasingly in focus of palaeoenvironmental studies. This thesis evaluates the applicability of organic biomarkers for palaeolimnological purposes on the Tibetan Plateau with a focus on aquatic macrophyte-derived biomarkers. Submerged aquatic macrophytes have to be considered to significantly influence the sediment organic matter due to their high abundance in many Tibetan lakes. They can show highly 13C-enriched biomass because of their carbon metabolism and it is therefore crucial for the interpretation of δ13C values in sediment cores to understand to which extent aquatic macrophytes contribute to the isotopic signal of the sediments in Tibetan lakes and in which way variations can be explained in a palaeolimnological context. Additionally, the high abundance of macrophytes makes them interesting as potential recorders of lake water δD. Hydrogen isotope analysis of biomarkers is a rapidly evolving field to reconstruct past hydrological conditions and therefore of special relevance on the Tibetan Plateau due to the direct linkage between variations of monsoon intensity and changes in regional precipitation / evaporation balances. A set of surface sediment and aquatic macrophyte samples from the central and eastern Tibetan Plateau was analysed for composition as well as carbon and hydrogen isotopes of n-alkanes. It was shown how variable δ13C values of bulk organic matter and leaf lipids can be in submerged macrophytes even of a single species and how strongly these parameters are affected by them in corresponding sediments. The estimated contribution of the macrophytes by means of a binary isotopic model was calculated to be up to 60% (mean: 40%) to total organic carbon and up to 100% (mean: 66%) to mid-chain n-alkanes. Hydrogen isotopes of n-alkanes turned out to record δD of meteoric water of the summer precipitation. The apparent enrichment factor between water and n-alkanes was in range of previously reported ones (≈-130‰) at the most humid sites, but smaller (average: -86‰) at sites with a negative moisture budget. This indicates an influence of evaporation and evapotranspiration on δD of source water for aquatic and terrestrial plants. The offset between δD of mid- and long-chain n-alkanes was close to zero in most of the samples, suggesting that lake water as well as soil and leaf water are affected to a similar extent by those effects. To apply biomarkers in a palaeolimnological context, the aliphatic biomarker fraction of a sediment core from Lake Koucha (34.0° N; 97.2° E; eastern Tibetan Plateau) was analysed for concentrations, δ13C and δD values of compounds. Before ca. 8 cal ka BP, the lake was dominated by aquatic macrophyte-derived mid-chain n-alkanes, while after 6 cal ka BP high concentrations of a C20 highly branched isoprenoid compound indicate a predominance of phytoplankton. Those two principally different states of the lake were linked by a transition period with high abundances of microbial biomarkers. δ13C values were relatively constant for long-chain n-alkanes, while mid-chain n-alkanes showed variations between -23.5 to -12.6‰. Highest values were observed for the assumed period of maximum macrophyte growth during the late glacial and for the phytoplankton maximum during the middle and late Holocene. Therefore, the enriched values were interpreted to be caused by carbon limitation which in turn was induced by high macrophyte and primary productivity, respectively. Hydrogen isotope signatures of mid-chain n-alkanes have been shown to be able to track a previously deduced episode of reduced moisture availability between ca. 10 and 7 cal ka BP, indicated by a 20‰ shift towards higher δD values. Indications for cooler episodes at 6.0, 3.1 and 1.8 cal ka BP were gained from drops of biomarker concentrations, especially microbial-derived hopanoids, and from coincidental shifts towards lower δ13C values. Those episodes correspond well with cool events reported from other locations on the Tibetan Plateau as well as in the Northern Hemisphere. To conclude, the study of recent sediments and plants improved the understanding of factors affecting the composition and isotopic signatures of aliphatic biomarkers in sediments. Concentrations and isotopic signatures of the biomarkers in Lake Koucha could be interpreted in a palaeolimnological context and contribute to the knowledge about the history of the lake. Aquatic macrophyte-derived mid-chain n-alkanes were especially useful, due to their high abundance in many Tibetan Lakes and their ability to record major changes of lake productivity and palaeo-hydrological conditions. Therefore, they have the potential to contribute to a fuller understanding of past climate variability in this key region for atmospheric circulation systems. / Das tibetische Hochplateau ist die größte gehobene Landmasse der Erde und beeinflusst maßgeblich atmosphärische Zirkulationsmuster wie den Asiatischen Monsun. Um die Auswirkungen zukünftiger Schwankungen der Monsundynamik auf das regionale Klima besser einschätzen zu können, ist es wichtig, ein fundiertes Verständnis vergangener Klimaänderungen zu entwickeln. Daher ist das Tibetplateau in den letzten Jahren mehr und mehr in den Fokus paläoklimatischer Studien gerückt. Die große Anzahl an Seen in der Region bietet ein unerschöpfliches Klimaarchiv und viele Studien haben sich bereits mit Seesedimenten zur Klimarekonstruktion befasst. Dabei wurde in erster Linie auf biologische, sedimentologische und geochemische Parameter zurückgegriffen, wohingegen organische Biomarker bisher recht selten benutzt wurden. Die vorliegende Arbeit untersucht die Anwendbarkeit dieser potentiellen Klimaindikatoren auf dem Tibetplateau. Hierbei wurde ein Schwerpunkt auf die Analyse kutikularer Blattwachse von Wasserpflanzen gelegt, da diese wegen ihres starken Auftretens in tibetischen Seen einen erheblichen Beitrag zur organischen Substanz im Sediment leisten. Um den Einfluss von Wasserpflanzen auf das Sediment über einen weiten klimatischen Gradienten zu untersuchen, wurden Oberflächensedimente und Wasserpflanzen vom zentralen und östlichen Tibetplateau auf ihre Biomarkerzusammensetzung sowie auf ihre Kohlen- und Wasserstoffisotopensignatur untersucht. Dadurch wurde das Verständnis über beeinflussende Faktoren auf diese Parameter in Sedimenten vertieft. In einem Sedimentbohrkern des Koucha-Sees (östliches Tibetplateau) konnten diese Parameter dann im Hinblick auf Änderungen der Produktivität im See sowie der hydrologischen und klimatischen Bedingungen der letzten 15000 Jahre interpretiert werden. Es zeigte sich, dass der See bis 8000 Jahre vor Heute stark mit Wasserpflanzen bewachsen war, während die letzten 6000 Jahre Algen dominierten. Mit Hilfe von Wasserstoffisotopen wurden eine Zunahme des Monsuns und steigende Niederschläge zwischen 15000 und 10000 Jahren vor Heute sowie eine relativ trockene Periode zwischen 10000 und 7000 Jahren vor Heute rekonstruiert. Durch Kombination von Biomarkerkonzentrationen sowie deren Kohlenstoffisotopensignal wurden außerdem kurzzeitige Kälteperioden um ca. 6000, 3100 und 1800 Jahren vor Heute nachgewiesen, die vorher bereits in anderen Klimaarchiven in Tibet sowie auf der nördlichen Hemisphäre belegt wurden. Mit Hilfe von organischen Biomarkern konnte so ein detailliertes Bild über die Entwicklung des Koucha-Sees seit dem letzten Glazial gewonnen werden. Organische Biomarker haben sich somit als geeignet erwiesen, einen Beitrag zur Klimarekonstruktion auf dem Tibetplateau zu leisten.