Thesis (M. Phil.)--University of Hong Kong, 2007. / Title proper from title frame. Also available in printed format.

Magnetic and geochemical properties of five late Holocene peat and loessial soil sections in SE Iceland have been studied. The aims were (i ) to establish a reliable tephrochronology for the sections, using geochemical analysis of tephra shards; (ii) to establish high resolution bulk sample records of mineral magnetic and geochemical properties; (iii) to test the ability of magnetic properties to correlate distal tephra layers; (iv) to assess the possible environmental significance of mineral magnetic time series and (v) to use records of loessial accumulation rates to assess human impact on the environment in SE Iceland. The work has been successful in establishing a reliable tephrostratigraphy for the studied sections. This was achieved using electron microprobe analyses (EMPA) of the geochemistry of tephra shards concentrated using a density separation technique. The results of detailed mineral magnetic measurements suggest that the main magnetic minerals in the tephras are probably ferrimagnetic minerals (e.g. magnetite) and canted anti ferromagnetic minerals (e.g. haematite), with abundant paramagnetic material also present. Cross plots of MrJMs vs. (Bo)c.l(Bo)c and Xfd% vs. XARM/SIRM indicate the main magnetic grain size in the tephras are pseudo-single domain (PSD) and multi domain (MD). The results indicate that the 'fingerprint' of both hysteresis and Curie temperature properties are insufficiently consistent within the tephra layers to provide an obviously sound basis for correlating tephra layers from one profile to the next. However, initial correlation of tephra layers was achieved, using all the measured magnetic parameters, by the use of the multivariate statistical measures of Similarity Coefficient (SC) and Euclidean Distance (ED). Tephra layer correlation was performed first time here using magnetic measurements. This demonstrates that magnetic techniques can potentially assist in the identification and correlation of distal tephra. Iceland offers a unique opportunity to study the role of humans in land degradation processes because of the late and well documented literature of settlements 1100 years ago. In this context, higher sedimentation rates in the upper part of two soils and one peat profile are interpreted as reflecting the effect of Landnam on deforestation and soil degradation.

published_or_final_version / abstract / Social Sciences / Master / Master of Philosophy

This thesis examines the extent to which geomorphological change in sub-arctic landscapes may be driven by rapid declines in population over timescales of decades to centuries. Demographic decline driven by disease in pastoral agricultural systems is expected to alter patterns of land use. Using a chronology with 20 visible dated tephra layers from AD 870 to present, 2625 tephra layers were identified in 200 sediment profiles. Rates of sediment accumulation dated by tephra provide a record of erosion in Skaftártunga, South Iceland. The scale of enquiry is that of individual landholdings (5–10 km2) over decades to centuries; in order to tackle questions of resilience and change within coupled socio-ecological systems larger and smaller spatial scales (regions of 400 km2 and individual sediment profiles) and longer and shorter temporal scales (2.6 ka and years to decades) are also considered. The novel application of photogrammetric techniques to recording stratigraphic sections increases the frequency of measurement from tens to hundreds per stratigraphic unit and the resolution from ±2.5 mm to ±1 mm. This technique improves the accuracy of representative measures of sediment accumulation and their use in measuring landscape change. Two little known 15th century AD Grímsvötn tephras are mapped and dated to AD 1432±5 and AD 1457± 5 using sediment accumulation rates. A period of landscape stability from AD 1389–1597 is consistent with reduced grazing pressure due to population declines of more than 30% after plague in AD 1402–1404 and AD 1494. Climatic deterioration from AD 1450-1500 does not increase erosion as much as expected; this may be due to decreased grazing pressure after population decline in the 15th century. Increased erosion from AD 935–1262 is related to woodland clearance and increases in sediment accumulation post AD 1625 are related to climatic cooling during the Little Ice age and the migration of erosion fronts into deep lowland sediments.

Tephrochronologies for three marine core sequences from the Adriatic Sea have been constructed. Two of the sequences, PRAD 1-2 and RF93-77, are located in the central Adriatic and the third, SA03-03, lies in the southern Adriatic. Isotopic and biostratigraphic records are available for all three sequences, features of which have been used as isochronous markers in the region. This project aimed to establish whether tephra layers provide (a) secure, independent isochronous tie-lines and (b) a robust methodology for testing correlations based on other methods. A total of 54 tephra layers have been identified within these sequences, of which only 8 are visible layers, the remainder being classified as cryptotephras. Geochemical characterisation of the ash layers has been undertaken using electron microprobe analysis and laser-ablation trace element methods. Geochemical correlation to the detailed tephra record from Lago Grande di Monticchio was performed using chemical element biplots and discriminant function analysis. Bayesian-based age models were generated for the three Adriatic records using available chronological information that are independent of assumptions of synchroneity between proxy marker events. These models allowed comparisons with tephra and palaeoenvironmental data from Lago Grande di Monticchio and other Mediterranean sites. The results support some assumptions of synchronous regional changes, but not others. The key outcomes are (a) the recognition of additional (non-visible) distal ash layers that enhance the potential for correlating marine and terrestrial records in the central Mediterranean; (b) volcanic ash records preserved in Lago Grande di Monticchio and in some localities proximal to volcanic sources appear to be incomplete; and (c) isotopic records in Adriatic sediment sequences reflect regional forcing factors more than local conditions.

A palaeolimnological study was carried out on a high-resolution, 7.62 m-long core (RU188-07) from northern Lake Rotorua, North Island. The core consists predominantly of olive diatomaceous ooze, laminated in places, and contains five tephras including Tarawera (1886 A.D.), Kaharoa (c. 1314 A.D.), Taupo (c. 233 A.D.) and Whakatane (c. 5500 cal. years B.P.). The core terminated in Whakatane Tephra giving the sediment a maximum age of 5530 60 cal. years B.P. An age model for the sediment was developed using tephrochronology. Radiocarbon dates obtained on the sediment returned ages too old because of contamination by old CO2 or CH4, or both. Investigations carried out on the core included spectrophotometric, sedimentological and geochemical analyses, and diatom identifications, which provided a number of proxies from which inferences were made about lake history, catchment development, and palaeoclimate since c. 5500 cal. years B.P. The laminations, evident only in the upper, post-Kaharoa Tephra part of the record, comprise alternations of thin, dark, detrital deposits and pale, relatively fine-grained diatom assemblages. Sediment geochemistry indicates that the Rotorua catchment has undergone several changes since c. 5500 cal. years B.P., alternating between periods of variable and stable environmental conditions. Following the Whakatane and Waimihia eruptions and up to approximately 3000 cal. years B.P., the catchment surrounding Lake Rotorua was rather unstable. Fluctuations in many of the proxies during this period are likely to be associated with a variable climate with periods of storminess, coinciding with the establishment of ENSO conditions in New Zealand. A notable feature of the record is two phases of stability, the first following the Taupo eruption (from c. 1700 cal. years B.P. to c. 630 cal. years B.P.) and the second from c. 580 cal. years B.P. to c. 300 cal. years B.P. The latest, most significant event in the catchment history of Lake Rotorua was the settlement by Polynesians. M.S. McGlone implied from pollen profiles (from Holden's Bay) that initial settlement took place around the time of the Kaharoa eruption (c. 630 cal years B.P.; c. 1314 A.D.), but the sediment chemistry and erosion profiles obtained here, from the northern part of Lake Rotorua, indicate that although there may have been some early clearing in the northern catchment for tracks or buildings, large-scale clearing in the area probably did not occur until considerably later, c. 300 cal. years B.P. Also contained within the sediments are three layers of reworked tephric material that probably originate from the transfer of coarse grained tephra from shallow to deeper water during large storms at c. 1300 cal. years B.P, c. 520 cal. years B.P, and c. 220 cal. years B.P. Each event coincides with storm events inferred from records from Lake Tutira in eastern North Island. Because of Lake Rotorua's inland position, these inferred storm events probably represent only the largest cyclonic events (e.g. ex-tropical cyclones).

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This study focuses on the late-Wisconsin Brooks Lake glaciation, lake-level fluctuations, and volcanic deposits in the lliarnna/Naknek/Brooks Lake area on the northern Alaska Peninsula, southwestern Alaska. The Brooks Lake glaciation consists of five stades, from youngest to oldest: Kvichak, Uiarnna, Newhalen, Iliuk, and Ukak. This thesis reassigns the type Mak Hill moraine to a pre-late-Wisconsin glaciation, and considers the moraine enclosing Naknek Lake an early-late-Wisconsin deposit correlative to either the Kvichak stade, lliarnna stade, or both. The presence in the Iliamna Lake valley, and the absence in the Naknek Lake valley of a two-fold earliest-late-Wisconsin Kvichak/Iliamna glacial sequence suggest that the two glacial systems responded differently to climate change, or glacier/bed dynamics due to differing ice sources and glacier configurations. Plant macrofossils dated at 26,155 ± 285 I4C yr BP afford a new maximum-limiting age on the type Kvichak moraine. Slope angles on the type Kvichak and Iliamna moraines are less steep (~11-15°) than on younger Newhalen, lliuk, and Ukak moraines (~18-20° ), indicating that a considerable length of time separated the Iliamna and Newhalen stades. Correlation of this time-stratigraphic marker with other better dated Alaskan glacial sequences suggests that the interstadial occurred -13-14 ka. Following late-Wisconsin de glaciation of the Iliamna and Naknek lake basins, lake levels lowered, creating a flight of wave-cut terraces. Horizontal terraces, formed during latest-Wisconsin/early-Holocene time, at ~40 m above Iliamna Lake, and ~15 and ~30 m above Naknek Lake, suggest that these shorelines are not tilted as a result of glacial isostatic rebound or regional tectonism. The most prominent terraces above both lakes lay about halfway between the highest terrace and present-day lake level. If these terraces are correlative, then this indicates some climate control on lake-level fluctuations. Electron-microprobe analysis of six late-Pleistocene tephra samples allows five samples to be correlated with latest-Pleistocene Lethe tephra, and extends the Lethe ash plume ~125 km westward, and ~150 km northwestward of its presumed source area. Analysis of four early-Holocene black tephras fails to support any correlations, suggesting that there are multiple black tephras in the area. Ash C, a tricolored ash, consists of more than one chemically distinct tephra, and there is little consistency between color zones of the ash at different sites.

Sediments in Lake C3, Ellesmere Island, Canada, contain annual laminations, providing a record of sediment accumulation for 1900+ years. Marine sediments are also present at base of cores, recording lake isolation following isostatic rebound of the Taconite Inlet region in the mid-Holocene. Beyond weak correlations with snowfall and summer temperature and precipitation, varve thickness comparisons with instrumental data were largely unsuccessful, likely due to turbidite-induced erosion. However, summer climate conditions are of key importance in varve thicknesses at many Arctic sites and we expect this to be true at Lake C3. Trends in the thickness record also correspond in approximate timing and response to large-scale climate events including the Little Ice Age (thin laminations) and the Medieval Warm Period (thick laminations). Long term trends and variability in the thickness record are also likely influenced by the weakening flow of the Taconite River following deglaciation as well as localized geomorphic events. Elemental profiles combined with varve thickness features identify anoxic periods resulting from ice-cover- or marine incursion- induced stratification. Through synthetic aperature radar imagery we verify the strong link between air temperature and ice-cover conditions during the summer. Modification to tephra isolation methods resulted in the successful extraction of cryptotephra. Shards are currently undergoing microprobe identification to identify volcanic source and eruption timing. Sediments at Lake C3 provide a high-resolution record of local and regional environmental change and add to the high-latitude network of reconstructions with the objective of placing current changes in a long-term context.