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Utilisation des systèmes 1,3-dicarbonyles (et de leurs équivalents) dans les réactions de couplage catalysées par la palladium Application à la synthèse se systèmes polycycliques /Hesse, Stéphanie. Kirsch, Gilbert. January 2008 (has links) (PDF)
Reproduction de : Thèse doctorat : Chimie moléculaire : Metz : 2002. / Titre provenant de l'écran-titre. Notes bibliographiques.
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An investigation of the desorption kinetics of hydrogen from the palladium (110) surfaceCarter, William Brent 05 1900 (has links)
No description available.
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High activity catalysts for carbon-carbon bond formationHazelwood, Samantha Louise January 2002 (has links)
No description available.
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Palladium-Catalyzed Synthesis and Transformation of OrganoboranesSebelius, Sara January 2006 (has links)
This thesis presents the development of new palladium-catalyzed transformations involving synthesis and application of allylborane reagents. In these reactions various palladium sources, including pincer complexes and commonly used catalysts were applied. A new transformation for allylation of aldehyde and imine substrates was devised using allyl acetates, diboronate reagents and catalytic amounts of Pd2(dba)3. By employment of commercially available chiral diboronates enantioenriched homoallyl alcohols could be obtained. We have also developed a palladium-catalyzed method for synthesis of functionalized allylboronic acids from vinyl cyclopropane, vinyl aziridine, allyl acetate and allyl alcohol substrates using diboronic acid as reagent. In this process a highly selective selenium based pincercomplex was used as catalyst. The resulting allylboronic acid products were converted to potassium trifluoro(allyl)borates or allylboronates. The functionalized allylboronic acids generated in the above procedure were employed as reagents in two synthetic transformations. One of these transformations involves a palladium(0)-catalyzed coupling reaction between allylboronic acids and aryl iodides. The reaction was regioselective for the branched allylic product, typically difficult to prepare in the absence of directing groups. We also developed another transformation for allylation of aldehydes with allyl alcohols via allylboronic acid intermediate. This procedure can be performed as a simple one-pot sequence affording homoallyl alcohols with excellent stereo- and regioselectivity.
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New aspects of palladium-catalysed carbon-carbon bond formation reactionsBoele, Maarten Dirk Karel. January 2002 (has links)
Proefschrift Universiteit van Amsterdam. / Met lit.opg. - Met samenvatting in het Nederlands.
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Reactions on surfaces with neural networksLorenz, Sönke. January 2001 (has links) (PDF)
Berlin, Techn. Univ., Diss., 2001.
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Wechselwirkung von Wasserstoff mit einer Pd(210)- und Ni(210)-OberflächeSchmidt, Pia Katharina. January 2001 (has links)
Berlin, Univ., Diss., 2001. / Dateiformat: zip, Dateien im PDF-Format. Computerdatei im Fernzugriff.
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Wechselwirkung von Wasserstoff mit einer Pd(210)- und Ni(210)-OberflächeSchmidt, Pia Katharina. January 2001 (has links)
Berlin, Univ., Diss., 2001. / Dateiformat: zip, Dateien im PDF-Format. Computerdatei im Fernzugriff.
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Study of reaction mechanisms on single crystal surfaces with scanning tunneling microscopy atomically resolved CO oxidation on Pd(111) and RuO2(110) /Kim, Sang Hoon. January 2003 (has links) (PDF)
Berlin, Humboldt-Univ., Diss., 2003. / Computerdatei im Fernzugriff.
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Study of reaction mechanisms on single crystal surfaces with scanning tunneling microscopy atomically resolved CO oxidation on Pd(111) and RuO2(110) /Kim, Sang Hoon. January 2003 (has links) (PDF)
Berlin, Humboldt-Univ., Diss., 2003. / Computerdatei im Fernzugriff.
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