This study describes tripper car operators’ exposure to coal tar pitch volatiles at an operation at Coal Distribution Steam Plant that involves the use of coal tar mix to feed as fuel the steam generating boilers. A cross-sectional task-based exposure assessment approached was used. The objectives of this study were to monitor tripper car operators’ exposures to coal tar pitch volatiles as benzene soluble fraction and to then compare the measured concentrations with the occupational exposure limit. The general aim of the study was to accumulate data about employee exposure to coal tar pitch volatiles in South African Petrochemical Refineries. A total of 56 samples was collected and analyzed for coal tar pitch volatiles – benzene soluble fraction. Of the 56 samples, 41 were personal samples collected on the breathing zones of the workers and 15 samples were field blank samples. The method used for the collection of the samples was the United States Department of Labor, Occupational Safety & Health Administration Method 58. In South Africa the available occupational exposure limit for coal tar pitch volatiles is the time weighted average occupational exposure limit – recommended limit for cyclohexane soluble fraction which is 0.14 mg/m3. For the evaluation of personal exposure to compare with the occupational exposure limit, the UK Health & Safety Executive Method for the Determination of Hazardous Substances (MDHS) 68 was adopted in the past to monitor workplace air. This method was since withdrawn by the Health & Safety Executive after research conducted by the Health & Safety Laboratory revealed that unacceptable variability were introduced into the method due to the small mass changes involved and the difficulty in accurately weighing the filters before and after the cyclohexane extraction. Due to the unavailability of a suitable and acceptable method to assess workers’ exposure to coal tar pitch volatiles – cyclohexane soluble fraction to compare to the South African occupational exposure limit, the Occupational Safety & Health Administration Method Number 58 was used during this study for the collection of the samples. This is a validated method. This method follows a similar approach as the MDHS 68 however benzene is used instead of cyclohexane during sample extraction. The Occupational Safety and Health Administration have the permissible exposure limit of 0.2 mg/m3 for coal tar pitch volatiles – benzene soluble fraction to use when assessing worker exposure. This limit was used during this study for assessing tripper car exposure to coal tar pitch volatiles. No coal tar pitch volatiles were detected on the samples collected during the study. The results revealed concentrations below detection limit of the test laboratory analytical method. The detection limit used thereof was 0.1 mg per sample. The tripper car operators were therefore exposed to coal tar pitch volatiles at concentrations that complied with the permissible exposure limit 0.2 mg/m3. The hypothesis of this study was that the tripper car operators at Coal Distribution Steam Plant are over exposed to coal tar pitch volatiles – benzene soluble fraction. This hypothesis is therefore rejected. Based on the results derived from this study it is recommended that further research studies be conducted specifically with focus on different methods of exposure assessment to workers exposed to coal tar pitch volatiles in South African Petrochemical Refinery Plants. - ii - Since the method used was limited to the particulate phase of the contaminant exposure, with the gaseous phase of exposure to coal tar pitch volatiles only looked at when the PEL is exceeded. A method that can measure both the gaseous and particulate phase of the contaminant must be investigated.

Due to the high complexity and various values essence, environmental issues need comprehensive and complete observation and analysis tools to find the resolving way. Current environmental management framework cannot provide comprehensive and whole picture of the environment issues because of research area and limited experiences on the cross field integration. This research integrated 3 environment-related frameworks ¡V Integrated Environmental Management framework (EM), Institution Analysis and Development framework (IAD), and Public Affair Management framework (PAM) - into a new integrated framework and use Kuokuang petrochemical plant event as the first case for theoretical identification. 3 original frameworks were analyzed, compared, recombined, and integrated into ¡§New Environmental Management framework (NEM)¡¨ which has the functions of describing the whole picture, building overall idea, underling problems textures and revealing key points of environment issues and supposed to be a new possible option for observing and analyzing environment issues. According to NEM framework, Kuokuang petrochemical plant event was analyzed step by step, such as data interpreting, problems textures filtering and key points revealing. The 4 most important key points affect the development and results of the Kuokuang petrochemical plant event were: development and changing of civil society, limitation and breakthrough of government institutions, conflict and reconciling of the values judgment, and impact and influence of internet.