The Higgs boson has an important role in the theoretical formulation of the standard model of fundamental interactions. Symmetry breaking of the vacuum via the Higgs field allows the gauge bosons of the weak interaction and all fermions to acquire mass in a way that preserves gauge-invariance, and thus renormalizablility. The Standard Model can accommodate an arbitrary number of Higgs fields with appropriate charge assignments. To explore the effects of multiple Higgs particles, the SU(2)-multi-Higgs model is studied using lattice simulations, a non-perturbative technique in which the fields are placed on a discrete space-time lattice. The formalism and methods of lattice field theory are discussed in detail. Standard results for the SU(2)-Higgs model are reproduced via Monte Carlo simulations, in particular the single-Higgs phase structure, which has a region of analytic connection between the symmetric and Higgs phases. The phase structure of the SU(2)-multi-Higgs model is explored for the case of N >= 2 identical Higgs fields. There is no remaining region of analytic connection between the phases, at least when interactions between different Higgs flavours are omitted. An explanation of this result in terms of enhancement from overlapping phase transitions is explored for N = 2 by introducing an asymmetry in the hopping parameters of the Higgs fields.

This dissertation presents investigations on dynamics of discrete-time quantum walk and some of its applications. Quantum walks has been exploited as an useful tool for quantum algorithms in quantum computing. Beyond quantum computational purposes, it has been used to explain and control the dynamics in various physical systems. In order to use the quantum walk to its fullest potential, it is important to know and optimize the properties purely due to quantum dynamics and in presence of noise. Various studies of its dynamics in the absence and presence of noise have been reported. We propose new approaches to optimize the dynamics, discuss symmetries and effect of noise on the quantum walk. Making use of its properties, we propose the use of quantum walk as an efficient new tool for various applications in physical systems and quantum information processing. In the first and second part of this dissertation, we discuss evolution process of the quantum walks, propose and demonstrate the optimization of discrete-time quantum walk using quantum coin operation from SU(2) group and discuss some of its properties. We investigate symmetry operations and environmental effects on dynamics of the walk on a line and an $n-$cycle highlighting the interplay between noise and topology. Using the properties and behavior of quantum walk discussed in part two, in part three we propose the application of quantum walk to realize quantum phase transition in optical lattice, that is to efficiently control and redistribute ultracold atoms in optical lattice. We also discuss the implementation scheme. Another application we consider is creation of spatial entanglement using quantum walk on a quantum many body system.

This dissertation presents investigations on dynamics of discrete-time quantum walk and some of its applications. Quantum walks has been exploited as an useful tool for quantum algorithms in quantum computing. Beyond quantum computational purposes, it has been used to explain and control the dynamics in various physical systems. In order to use the quantum walk to its fullest potential, it is important to know and optimize the properties purely due to quantum dynamics and in presence of noise. Various studies of its dynamics in the absence and presence of noise have been reported. We propose new approaches to optimize the dynamics, discuss symmetries and effect of noise on the quantum walk. Making use of its properties, we propose the use of quantum walk as an efficient new tool for various applications in physical systems and quantum information processing. In the first and second part of this dissertation, we discuss evolution process of the quantum walks, propose and demonstrate the optimization of discrete-time quantum walk using quantum coin operation from SU(2) group and discuss some of its properties. We investigate symmetry operations and environmental effects on dynamics of the walk on a line and an $n-$cycle highlighting the interplay between noise and topology. Using the properties and behavior of quantum walk discussed in part two, in part three we propose the application of quantum walk to realize quantum phase transition in optical lattice, that is to efficiently control and redistribute ultracold atoms in optical lattice. We also discuss the implementation scheme. Another application we consider is creation of spatial entanglement using quantum walk on a quantum many body system.

Anisotropic molecules confined on a spherical or other curved surface can display coupled positional and orientational orderings, which make possible applications in physics, chemistry, biology, and material science. Therefore, controlling the order of such system has attracted much attention recently. Several distinct conformations of rod-like or chain-like molecules confined on a spherical surface have been predicted, including states such as tennis-ball, rectangle, and cut-and-rotate splay. These conformations have four +1/2 defects and are suggested to dominate over the splay conformation that has two +1 defects. For the purpose of investigating the conformations of 2-fold anisotropic molecules confined on the spherical surface, the author of this thesis utilizes the Onsager model to study the system of rigid rods and conducts Monte Carlo simulations on the bead-bond model to research the system of semiflexible polymer chains. At low surface coverage density, no particular pattern of the molecules would form. However, coupled positional and orientational ordering begins to emerge beyond a transition density. On the basis of the numerical solutions of the Onsager model of rigid rods, the splay conformation is shown to be the only stable state. On the other hand, Monte Carlo simulations on a polymer system indicate that the ordered state always accompanies the tennis-ball symmetry. With comparison to the continuous isotropic-nematic transition of a fluid of hard rods embedded in a flat two-dimensional space, the disorder-order transition for both the system of rigid rods and the system of polymer chains confined on the spherical surface has first-order phase-transition characteristics.

The Higgs boson has an important role in the theoretical formulation of the standard model of fundamental interactions. Symmetry breaking of the vacuum via the Higgs field allows the gauge bosons of the weak interaction and all fermions to acquire mass in a way that preserves gauge-invariance, and thus renormalizablility. The Standard Model can accommodate an arbitrary number of Higgs fields with appropriate charge assignments. To explore the effects of multiple Higgs particles, the SU(2)-multi-Higgs model is studied using lattice simulations, a non-perturbative technique in which the fields are placed on a discrete space-time lattice. The formalism and methods of lattice field theory are discussed in detail. Standard results for the SU(2)-Higgs model are reproduced via Monte Carlo simulations, in particular the single-Higgs phase structure, which has a region of analytic connection between the symmetric and Higgs phases. The phase structure of the SU(2)-multi-Higgs model is explored for the case of N >= 2 identical Higgs fields. There is no remaining region of analytic connection between the phases, at least when interactions between different Higgs flavours are omitted. An explanation of this result in terms of enhancement from overlapping phase transitions is explored for N = 2 by introducing an asymmetry in the hopping parameters of the Higgs fields.

Relaxor ferroelectric PZN-xPT and PMN-xPT single crystals exhibit extraordinary electromechanical properties. They are under development for applications in sensors, actuators and transducers. The polarization switching and phase transition behavior of PZN-4.5%PT and PMN-32%PT single crystals under external loading has been investigated. Experimental investigation elucidates the polarization switching and phase transition behavior of relaxor ferroelectric crystals at different orientation cuts under combined temperature, electric field and stress loading. These crystals exhibit strong orientation dependence of electromechanical properties, and the applied fields all affect the poling and phase states of the crystals. Based on experimental investigation, crystal variant modeling was developed to compute the piezoelectric properties of multi-domain crystals at different orientation cuts from a set of properties for the single domain. Thermodynamics and work-energy analysis of field induced phase transitions in these single crystals sheds light on the phase transition mechanism of ferroelectric crystals. Fracture behavior of relaxor single crystals under non-uniform electric fields at a partial electrode edge has also been measured and analyzed.

This thesis focuses on the analysis of Bardeen-Cooper-Schrieffer (BCS) to Bose-Einstein condensation (BEC) evolution in ultracold superfluid Fermi gases when the interaction between atoms is varied. The tuning of attractive interactions permits the ground state of the system to evolve from a weak fermion attraction BCS limit of loosely bound and largely overlapping Cooper pairs to a strong fermion attraction limit of tightly bound small bosonic molecules which undergo BEC. This evolution is accompanied by anomalous behavior of many superfluid properties, and reveals several quantum phase transitions. This thesis has two parts: In the first part, I analyze zero and nonzero orbital angular momentum pairing effects, and show that a quantum phase transition occurs for nonzero angular momentum pairing, unlike the $s$-wave case where the BCS to BEC evolution is just a crossover. In the second part, I analyze two-species fermion mixtures with mass and population imbalance in continuum, trap and lattice models. In contrast with the crossover physics found in the mass and population balanced mixtures, I demonstrate the existence of phase transitions between normal and superfluid phases, as well as phase separation between superfluid (paired) and normal (excess) fermions in imbalanced mixtures as a function of scattering parameter and mass and population imbalance.

This study gives our calculations for the temperature-pressure and temperature-concentration phase diagrams using the mean field models applied to ammonium halides (NH4Cl, ND4Cl), ammonium sulfate ((NH4)2SO4/H2O), lithium potassium rubidium sulfate (LiK1-xRbxSO4), potassium pyrosulfate-potassium hydrogensulfate (K2S2O7-KHSO4), cholestanyl myristate-cholesteryl myristate (CnM-CrM), cholestanyl myristate-cholesteryl oleate (CnM-CO), benzene (C6H6) and ice. The phase line equations are derived from the free energies expanded in terms of the order parameters and they are fitted to the experimental data. Some thermodynamic quantities are calculated close to phase transitions in these crystalline systems. We also calculate the specific heat CV using the Raman frequency shifts for NH4Br on the basis of an Ising model close to the lambda-phase transition. A linear relationship is obtained between the specific heat CP and the frequency shifts (1/v)(dv/dT)P near the lambda-point in NH4Br.

We examine various models of soft matter, and one model of quasicrystals, focusing on abrupt changes as density is varied. We consider in detail two models, one of granular matter and another of confined wires, showing that the models become ordered as density is increased, with crystalline order observed in the former and nematic order observed in the latter. We associate the phenomenon of random close packing with the onset of crystalline order in our granular model, and we conjecture that crumpled wires should exhibit a nematic transition with increasing compaction. We also consider two other models of granular matter: one which describes dilatancy onset as a second order phase transition, and one which describes random loose packing as a precise, well- defined density. Finally, we examine an equilibrium model of quasicrystals with a first order phase transition to a solid phase without any crystalline order. / text

The knowledge of physicochemical properties of organic compounds becomes increasingly important. In this study, we developed UPPER (Unified Physical Property Estimation Relationships), a comprehensive model for the estimation of 20 physicochemical properties of organic compounds. UPPER is a system of thermodynamically sound relationships that relate the various phase-transition properties to one another, which includes transition heats, transition entropies, transition temperatures, molar volume, vapor pressure, solubilities and partition coefficients in different solvents and etc. UPPER integrates group contributions with the molecular geometric factors that affect transition entropies. All of the predictions are directly based on molecular structure. As a result, the proposed model provides a simple and accurate prediction of the properties studied. UPPER is designed to predict industrially, environmentally and pharmaceutically relevant physicochemical properties of organic compounds. It also can be an aid for the efficient design and synthesis of compounds with optimal physicochemical properties.