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Synthesis and characterization of Pt/modified MWNT as electrocatalyst for applications in high temperature PEMFC'sΟρφανίδη, Αλίν 14 February 2012 (has links)
A new approach towards the development of electrocatalytic layers for use in high temperature polymer electrolyte membrane fuel cells is reported. Modified carbon nanotubes were used as the support. The aim was to achieve a uniform distribution of polar groups, which can interact with phosphoric acid, on the surface of the modified carbon support. Multi-wall carbon nanotubes were selected due to their unique properties regarding electronic conductivity and specific surface area. They were surface modified introducing pyridine based groups on the side walls which are known to interact with phosphoric acid. The different supports were thoroughly characterized by means of relevant techniques such as RAMAN,XPS and TGA. Platinum was deposited on the new carbon supports resulting in the newly synthesized catalysts,which were also thoroughly characterized by means of XRD,EDX,TEM and H2 Chemisorption. Stable and finely distributed Pt catalysts with nanoparticles size ranging between 2 and 4 nm were obtained using the chemically modified nanotubes as supports. Measurements of the catalytic activity towards oxygen reduction were also performed in order to evaluate the potential use of these materials as catalytic layers in PEMFCs. / -
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Synthesis and characterization of silver nanoparticles for photovoltaic applicationAdam, Razia Zulfikar January 2013 (has links)
Magister Scientiae - MSc / With an increase in the amount of harmful carbon emissions in the atmosphere as well as a decrease in the availability of fossil fuels, there is a relatively high demand for alternate energy devices. Solar cells have become an alternative option in aid of leading the way for clean energy; however these devices are relatively expensive and have an efficiency that is relatively low in comparison to that of fossil fuelled energy. As a result the cost of the solar cell needs to be reduced by reducing the amount of silicon used in order to compete with fossil fuelled devices; however this decrease would lead to a decrease in efficiency. In recent years silver nanoparticles have been extensively researched as a result of its extraordinary optical, electrical, catalytic, magnetic and antibacterial properties. As a result of these properties, the nanoparticles may be applied to many research areas such as photovoltaics, catalysis and medical fields. The optical properties of silver nanoparticles may thus be exploited in order to increase absorption and in turn the efficiency of the solar cell devices. This study focuses on the optimization of the polyol synthesis to possibly obtain uniformly dispersed silver nanoparticles. The silver nanoparticles would then be incorporated onto amorphous silicon thin films, deposited by hot wire chemical vapour deposition, by spraying a suspension of the silver nanoparticles onto the thin films. The silver nanoparticles were viii characterized by Ultra Violet Visible Spectroscopy (UV-VIS), High Resolution Transmission Electron Microscopy, X-ray Diffraction, and Thermogravimetric Analysis. The thin films with the incorporated silver nanoparticles were characterized by UV-VIS, and High Resolution Scanning Electron Microscopy. It was shown that silver nanoparticles with various morphologies were produced by the polyol synthesis and may be used to enhance light trapping of thin film
photovoltaic devices.
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Etude du mécanisme de la réaction d'oxydation de l'éthanol sur électrocatalyseurs à base de Pt, Rh, SnO2 sur support carboné en milieu acide / Mechanistic study of the ethanol oxidation reaction on carbon supported Pt-, Rh- and SnO2-based electrocatalysts in acidic mediumBach Delpeuch, Antoine 24 November 2014 (has links)
L'étude du mécanisme de la réaction d'oxydation de l'éthanol (EOR) a été réalisée sur des électrocatalyseurs bi- et tri-métalliques à base de Pt, Rh et SnO2 sur support carboné à l'aide de méthodes électrochimiques couplées (DEMS, in situ FTIR). Deux importantes problématiques de l'EOR ont été abordées: la déshydrogénation de la molécule d'éthanol et la cassure de sa liaison C-C.L'investigation de certains paramètres expérimentaux, comme l'épaisseur de la couche d'électrocatalyseur, a permis de démontrer q'une couche active épaisse conduit à une meilleure électrooxydation plus complète de l'éthanol en CO2, mais également que l'empoisonnement de l'électrocatalyseur par de très forts adsorbats advient dans l'épaisseur de couche active.Les performances de chaque électrocatalyseur ont été comparées entre elles et ont mis en évidence une meilleure sélectivité de l'EOR sur Pt-Rh-SnO2/C, ainsi que l'engendrement de courants plus élevés à bas potentiel à température ambiante. La tendance est amplifiée à température plus élevée (T = 60 °C). / The study of the ethanol oxidation reaction (EOR) mechanism was performed on carbon supported bi- and tri-metallic Pt-, Rh-, SnO2-based electrocatalysts via electrochemical coupled techniques (DEMS, in situ FTIR). Two of the most important issues related to the EOR have been broached: the dehydrogenation of the ethanol molecule and its C-C bond breaking.The investigation of some experimental parameters, such as the thickness of the electrocatalyst layer, enabled demonstrating the better complete ethanol electrooxidation into CO2 for large electrocatalysts layers, combined to the enhanced poisoning effect inside the catalyst layer by very strong adsorbates.The performances of each electrocatalyst were compared and evidenced an improved selectivity of the EOR on Pt-Rh-SnO2/C, as well as the generation of higher currents at low potential at room temperature. The tendency was amplified at elevated temperatures (T = 60 °C).
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Modification de nanotubes de TiO2 pour la production d’hydrogène par photodissociation de l’eau sous lumière solaire / Modification of TiO2 nanotubes for hydrogen production by water-splitting under solar lightGross, Pierre-Alexandre 21 November 2014 (has links)
Ce travail de thèse traite de la production d’hydrogène par le procédé de photoélectrocatalyse en utilisant une photoanode à base de nanotubes de TiO2 verticalement alignés. L’utilisation du TiO2 étant limité pour des applications solaires en raison de son large gap, il est nécessaire de le modifier. Deux approches sont proposées pour modifier les nanotubes de TiO2 et leur permettre d’absorber la lumière visible. La première est une modification chimique du TiO2 par co-dopage cationique-anionique (Ta-N) ou (Nb-N). Les cations sont insérés durant la croissance des nanotubes grâce à une approche inédite, et l’azote est inséré durant le traitement thermique. Ceci a pour effet la formation d’orbitales hybrides qui entraîne une réduction du gap et une activité sous lumière visible, tout en permettant une stabilité de la structure. La seconde approche consiste à déposer des nanoparticules d’Ag sur la surface des nanotubes de TiO2. Grâce au contrôle de la morphologie des nanoparticules d’Ag, leur résonnance plasmonique permet de stimuler l’absorption du TiO2 et ainsi d’augmenter son rendement à la fois sous lumière UV et sous lumière visible. / This work is about the production of hydrogen by photoelectrocatalysis using a vertically aligned TiO2 nanotubes based photoanode. Utilization of TiO2 for solar applications is limited due to its large band gap, it has to be modified. Two approaches are proposed for the modification of the TiO2 nanotubes to make them absorb visible light. The first one is the chemical modification of the TiO2 by (Ta-N) or (Nb-N) cationic-anionic co-doping. Cations are inserted during the growth of the nanotubes by a novel approach, and nitrogen is inserted during heat treatment. This leads to the formation of hybrid orbitals resulting in a band gap reduction and of activity under visible light. The second approach consists of the deposition of Ag nanoparticles on the surface of the TiO2 nanotubes. Thanks to the control of the morphology of the Ag nanoparticles, their plasmonic resonance can enhance the absorption of TiO2 and thus increase its activity both under UV and visible light.
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