ABSTRACT An evaluation of glass reinforced plastic pipe stub-flange behaviour during hydrostatic pressure testing is presented. Similar flanges made according to different manufacturing methods were analysed. Linear static analysis using MSC Patran / Nastran was performed to predict the critically loaded regions subjected to high stress concentrations. These regions were used for experimental strain gauge locations. Hydrostatic testing designed according to BS 5480 and ASTM F 37 was performed on assembled flange joints to initiate both leakage and ultimate material failure. Experimental strain results were compared to finite element numerical results at the selected locations. Fibre dominated failure characterised by cracks extending through the stub and matrix dominated failure characterised by interlaminar debonding were noticed. The need for further work analyzing GRP flanges subject to mechanical load and taking into account induced residual thermal stress effects is suggested.

In February 2007, the U.S. Department of Energy, BP Exploration (Alaska), Inc., and the U.S. Geological Survey conducted an extensive data collection effort at the "Mount Elbert #1" gas hydrates stratigraphic test well on the Alaska North Slope (ANS). The 22-day field program acquired significant gas hydrate-bearing reservoir data, including a full suite of open-hole well logs, over 500 feet of continuous core, and open-hole formation pressure response tests. Hole conditions, and therefore log data quality, were excellent due largely to the use of chilled oilbased drilling fluids. The logging program confirmed the existence of approximately 30 m of gashydrate saturated, fine-grained sand reservoir. Gas hydrate saturations were observed to range from 60% to 75% largely as a function of reservoir quality. Continuous wire-line coring operations (the first conducted on the ANS) achieved 85% recovery through 153 meters of section, providing more than 250 subsamples for analysis. The "Mount Elbert" data collection program culminated with open-hole tests of reservoir flow and pressure responses, as well as gas and water sample collection, using Schlumberger's Modular Formation Dynamics Tester (MDT) wireline tool. Four such tests, ranging from six to twelve hours duration, were conducted. This field program demonstrated the ability to safely and efficiently conduct a research-level openhole data acquisition program in shallow, sub-permafrost sediments. The program also demonstrated the soundness of the program's pre-drill gas hydrate characterization methods and increased confidence in gas hydrate resource assessment methodologies for the ANS.

The aim of this study is to determine the mechanical characteristics of the filament wound composite tubes working under internal pressure loads, generating data for further investigation with a view of estimating the remaining life cycle of the tubes during service. Data is generated experimentally by measuring the mechanical behavior like strains in hoop direction, maximum hoop stresses that are formed during internal pressure loading. Results have been used to identify and generate the necessary data to be adopted in the design applications. In order to determine these parameters, internal pressure tests are done on the filament wound composite tube specimens according to ASTM D 1599-99 standard. The test tubes are manufactured by wet filament winding method, employing two different fiber types, two different fiber tension settings and five different winding angle configurations. The internal pressure test results of these specimens are studied in order to determine the mechanical characteristics, and the effects of the production variables on the behavior of the tubes. Pressure tests revealed that the carbon fiber reinforced composite tubes exhibited a better burst performance compared to the glass fiber reinforced tubes, and the maximum burst performance is achieved at a winding angle configuration of [&plusmn / 54&deg / ]3[90&deg / ]1. In addition, the tension setting is found not to have a significant effect on the burst performance. The burst pressure data and the final failure modes are compared with the results of the ASME Boiler and Pressure Vessel Code laminate analysis, and it was observed that there is a good agreement between the laminate analysis results and the experimental data. The stress &ndash / strain behavior in hoop direction are also studied and hoop elastic constants are determined for the tubes.

No description available.

The long-term performance of stabilized polyolefins in different environments was studied with focus on antioxidant consumption and migration. Plaques of linear polyethylene (LPE) and branched polyethylene (BPE) were stabilized with Santonox® R (4,4'-Thiobis(6-tert-butyl-3-methylphenol)), Irganox® 1081 (2,2’-Thiobis(4-methyl-6-tertbutylphenol)), or Lowinox® 22M46 (2,2’-Methylenebis(6-tert-butyl-4-methylphenol)). The samples were aged in water and nitrogen at 75, 90 and 95°C. Antioxidant concentration profiles were obtained by oxidation induction time (OIT) measurements using differential scanning calorimetry (DSC). The very flat antioxidant concentration profiles of the plaques exposed to non-aqueous media indicated that the migration of antioxidant to the surrounding medium was controlled by the low evaporation rate at the sample boundary. The samples of BPE and Santonox R were also exposed to air and water saturated with air. The similarity of the antioxidant concentration profiles of Santonox R obtained after ageing in air and nitrogen suggested that the fraction of antioxidant oxidized is negligible in comparison with the loss of antioxidant by migration to the surrounding media. The loss of Santonox R in samples exposed to water saturated with air was faster than for the samples exposed to oxygen-free water. This was due to increased mass transport of the antioxidant from the polymer phase boundary to the water phase when oxygen was present. An unexpected higher migration rate from LPE than from BPE was proposed to be due to the low boundary loss rate in BPE, caused by the presence of a thin liquid-like (oligomeric) surface layer developed during ageing. A quantitative relationship was found between the boundary loss rate to water and the polarity of antioxidants. The antioxidant diffusivities were approximately equal in LPE and BPE, indicating that the constraining effect of the crystals on the non-crystalline fraction did not affect the antioxidant molecules. Results obtained by liquid chromatography of extracts confirmed that the gradual decrease in OIT with increasing ageing time was due to migration of antioxidant to the surrounding medium. Pipes of high-density polyethylene stabilized with hindered phenols and phosphites were exposed to chlorinated water at elevated temperatures. OIT showed that the stabilizing system was rapidly chemically consumed by the action of chlorinated water. Size exclusion chromatography and DSC showed extensive polymer degradation strictly confined to the immediate surface of the unprotected inner wall material and to the amorphous phase of the semicrystalline polymer. The rate of growth of the layer of highly degraded polymer was constant. Pipes of isotactic polybutene-1 were pressure-tested in chlorinated water at a controlled pH, and the lifetime was assessed as a function of temperature and chlorine content. The lifetime shortening in chlorinated water was significant even at relatively low chlorine contents, 0.5 ppm. A further increase of chlorine content led to only a moderate shortening of the lifetime. The temperature dependence of the lifetime data obeyed the Arrhenius law. The decrease of the antioxidant concentration was independent of the chlorine concentration in the range of 0.5-1.5 ppm. The time to reach depletion of the antioxidant system could be predicted by linear extrapolation. / QC 20101020

This project had two primary goals: (1) to explore opportunities to further a deep-ocean vehicle’s reach using alternative pressure spheres, and (2) to implement an existing deep-ocean vehicle (lander) in active scientific research. I gained a greater understanding of the limitations and design choices made for existing pressure spheres using Finite Element Analysis (FEA). My simplified FEA model predicted sphere failure for the existing 30% Fiber Glass 70% Nylon injection molded spheres at an external pressure of 3,954psi or 2,690m ocean-depth (only a 7.38% error compared to the tested minimum failure depth), so I determined it a valid model. I also explored alternative designs and materials that could be used for pressure spheres in deep-sea applications. Existing pressure sphere models filled with an incompressible fluid failed at 12,670psi or 8,621m ocean-depth - over three times the depth of the same sphere filled with air. Next, I varied the sphere thickness of existing spheres to determine its impact on depth rating. While the increased thickness did provide an increase in depth rating, there were diminishing returns as the sphere was made thicker. I deemed both of these design options infeasible for our application. To consider the use of laminated composite spheres, the addition of an equatorial ring was required to manufacture O-ring seals safely and reliably. A simple cylindrical equatorial ring model using a stainless-steel ring had a predicted failure at 3,017psi or 2,053m ocean-depth. While this model predicted failure at 637m shallower than the sphere without the ring, it was the only ring material tested to reach the rated depth for the existing pressure spheres (2km), so I concluded stainless-steel is the best ring material. A spherical stainless-steel equatorial ring design was then analyzed which predicted failure at 3,915psi or 2,664m ocean-depth – only 8.3% less than the original sphere with no ring. Because of its successful performance and near identical results to the original model, I determined a stainless-steel spherical equatorial ring is the best option for laminated composite sphere sealing. Finally, I analyzed three different kinds of laminated composite pressure spheres: two carbon fiber and one fiber glass. Each laminate was designed to be quasi-isotropic and as close to 0.8” thick as possible to keep it consistent with the original sphere design. The sphere made of 584 Carbon Fiber with a lay-up of: [[-45/45/0/90]6]s was found to predict failure at 10,000psi or 6,804m ocean-depth, more than 2.5 times that of the original sphere. Next, a model made of 282 Carbon Fiber with a lay-up of: [[-45/45/0/90]11]s predicted failure at 9,242psi or 6,289m ocean-depth – more than 2.3 times as deep as the original pressure spheres. Lastly, a sphere of 7781 Fiber Glass with a lay-up of: [[-45/45/0/90]11]s predicted failure at 6,630psi or 4,511m ocean-depth – about two-thirds the depth of the 584 Carbon Fiber composite, but more than 1.6 times the depth of the original sphere. While real-life applications of these materials would include design modifications and manufacturing imperfections which would lower their maximum depth rating, these results are highly encouraging and show that all three materials could be viable options for future production. Additionally, through partnership with Dr. Crow White and his marine science undergraduate students, I completed numerous deployments for a Before and After Controlled Impact (BACI) study on the area of the proposed windfarm off the coast of Morro Bay, CA. Many modifications were made to the existing lander which enabled it to successfully be implemented in these studies including a new bait containment unit, light color filters, a GPS tracking device, and a large vessel recovery device. A total of 5 pier deployments and 3 boat deployments were conducted by my team over the course of 6-months. Planning for these deployments included accounting for budgeting, weather, permitting, and multi-organizational logistics while working with both NOAA and the Cal Poly marine operations staff.