This research proposes the use of electric energy storage (EES) in conjunction with a power generation unit organic Rankine cycle system (PGU-ORC). The EES is used when available so that continuous operation of the PGU is not required. The potential of the PGU-ORC-EES system’s performance is evaluated in terms of operational cost, primary energy consumption (PEC), and carbon dioxide emissions (CDE) from simulations of a restaurant building in twelve U.S. locations with different climate conditions. The performance of the proposed system is compared to a conventional system. Results indicate that the EES addition to the PGU-ORC system is beneficial for most locations. Ratios between electricity and fuel cost, CDE conversion factors, and PEC conversion factors are used to estimate potential performance benefits. The effect of the EES size and the capital cost available are also analyzed.