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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

<i>COHERENT QUANTUM CONTROL AND QUANTUM </i><i>SIMULATION OF CHEMICAL REACTIONS</i>

Sumit Suresh Kale (17743605) 18 March 2024 (has links)
<p dir="ltr">This thesis explores the intersection of quantum interference, entanglement, and quantum algorithms in the context of chemical reactions. The initial exploration delves into the constructive quantum interference in the photoassociation reaction of a 87Rb Bose Einstein condensate (BEC), where a coherent superposition of multiple bare spin states is achieved and it’s impact on photo-association (PA) was studied. Employing a quantum processor, the study illustrates that interferences can function as a resource for coherent control in photochemical reactions, presenting a universally applicable framework relevant to a spectrum of ultracold chemical reactions. The subsequent inquiry scrutinizes the entanglement dynamics between the spin and momentum degrees of freedom in an optically confined BEC of 87Rb atoms, induced by Raman and RF fields. Significantly, this study unveils substantial spin momentum entanglement under specific experimental conditions, indicating potential applications in the realm of quantum information processing. Finally, the third study advances a quantum algorithm for the computation of scattering matrix elements in chemical reactions, adeptly navigating the complexities of quantum interactions. This algorithm, rooted in the time-dependent method and Möller operator formulation, is applied to scenarios such as 1D semi-infinite square well potentials and co-linear hydrogen exchange reactions, showcasing its potential to enhance our comprehension of intricate quantum interactions within chemical systems.</p>

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