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No description available.

Membrane biofilm reactors (MBfR) utilize membrane fibers for bubble-less transfer of gas by diffusion and provide a surface for biofilm development. Nitrogen removal was attempted using MBfR in various configurations - nitrification, denitrification and consecutive nitrification and denitrification. Effects of loading rate and dissolved oxygen on nitrification performance were primarily investigated in a stand-alone nitrifying MBfR. Specific nitrification rate increased linearly with specific loading rate, up to the load of 3.5 g N/m²d. Beyond that load, substrate diffusion limitation inhibited further increase of specific nitrification rate. 100% oxygen utilization was achievable under limited oxygen supply condition. Effects of mineral precipitation, dissolved oxygen and temperature on hydrogenotrophic denitrification were investigated in a stand-alone denitrifying MBfR. Mineral precipitation, caused by intended pH control, caused the deterioration of denitrification performance by inhibiting the diffusion of hydrogen and nitrate. Operating reactor in various dissolved oxygen conditions showed that the denitrification performance was not affected by dissolved oxygen in MBfR. Optimum temperature of the hydrogenotrophic denitrification system was around 28°C. Total nitrogen removal in a two-step MBfR system incorporating sequential nitrification and hydrogen-driven autotrophic denitrification was investigated in order to achieve nitrogen removal by autotrophic bacteria alone. Long-term stable operation, which proved difficult in previous studies due to excessive biofilm accumulation in autotrophic denitrification systems, was attempted by biofilm control. Nitrification performance was very stable throughout the experimental periods over 200 days. Performance of autotrophic denitrification was maintained stably throughout the experimental periods, however biofilm control by nitrogen sparging was required for process stability. Biofilm thickness was also stably maintained at an average of 270 µm by the gas sparging biofilm control. According to the cost analysis of denitrifying MBfR, hydrogenotrophic denitrification can be an economical tertiary treatment option compared to conventional denitrifying filter although its economic feasibility highly depends on the cost of hydrogen gas. Although this study was conducted in a lab-scale, the findings from this study can be a valuable stepping stone for larger scale application and open the door for system modifications in future.

In a lead-cooled fast reactor (LFR), small bubbles (in the order of one mm or less) may enter the coolant from a leaking steam generator. If such a leakage is undetected the small bubbles may eventually coalesce into a larger bubble in local stagnation zones under the active core. If such a bubble or void releases and passes through the core, it could drive the reactor into prompt criticality. It is therefore desirable to be able to detect the initial stages of such void formation. In this thesis, a methodology to detect such leaks is presented together with a study on void-induced reactivity effects in various LFR's. The methodology developed is based on information from two fission chambers positioned radially outside the core. The fissile content of the fission chambers consist either of 235U or 242Pu making them sensitive to different parts of the neutron spectrum. It is shown that the information from the fission chambers can be used to obtain an early indication of the presence of a small leak within typically a month. Furthermore, it is shown that for all but the smallest LFR’s, prompt criticality due to voids passing the core cannot be excluded. One conclusion is that the methodology may form an attractive complement to the general monitoring system of future LFR’s but, as is noted, it has potential for further developments.

In this work a cooling system connected to a reactor pressure vessel has been studied using the CFD method for the purpose of investigating the strengths and shortcomings of using CFD as a tool in similar fluid flow problems within nuclear power plants. The cooling system is used to transport water of 288K (15°C) into a nuclear reactor vessel filled with water of about 555K (282°C) during certain operating scenarios. After the system has been used, the warm water inside the vessel will be carried into the cooling system by buoyancy forces. It was of interest to investigate how quickly the warm water moves into the cooling system and how the temperature field of the water changes over time. Using the open source CFD code OpenFOAM 2.3.x and the LES turbulence modelling method, a certain operating scenario of the cooling system was simulated. A simplified computational domain was created to represent the geometries of the downcomer region within the reactor pressure vessel and the pipe structure of the cooling system. Boundary conditions and other domain properties were chosen and motivated to represent the real scenario as good as possible. For the geometry, four computational grids of different sizes and design were generated. Three of these were generated using the ANSA pre-processing tool, and they all have the same general structure only with different cell sizes. The fourth grid was made by the OpenFOAM application snappyHexMesh, which automatically creates the volume mesh with little user input. It was found that for the case at hand, the different computational grids produced roughly the same results despite the number of cells ranging from 0,14M to 3,2M. A major difference between the simulations was the maximum size of the time steps which ranged from 0,3ms for the finest ANSA mesh to 2ms for the snappy mesh, a difference which has a large impact on the total time consumption of the simulations. Furthermore, a comparison of the CFD results was made with those of a simpler 1D thermal hydraulic code, Relap5. The difference in time consumption between the two analyses were of course large and it was found that although the CFD analysis provided more detailed information about the flow field, the cheaper 1D analysis managed to capture the important phenomena for this particular case. However, it cannot be guaranteed that the 1D analysis is sufficient for all similar flow scenarios as it may not always be able to sufficiently capture phenomena such as thermal shocks and sharp temperature gradients in the fluid. Regardless of whether the CFD method or a simpler analysis is used, conservativeness in the flow simulation results needs to be ensured. If the simplifications introduced in the computational models cannot be proved to always give conservative results, the final simulation results need to be modified to ensure conservativeness although no such modifications were made in this work.

Recent work by Yasseri and Rahnema has introduced a consistent spatial homogenization (CSH) method completely in transport theory. The CSH method can very accurately reproduce the heterogeneous flux shape and eigenvalue of a reactor, but at high computational cost. Other recent works for homogenization in diffusion or quasi-diffusion theory are accurate for problems with low heterogeneity, such as PWRs, but are not proven for more heterogeneous reactors such as BWRs or GCRs. To address these issues, a consistent hybrid diffusion-transport spatial homogenization (CHSH) method is developed as an extension of the CSH method that uses conventional flux weighted homogenized cross sections to calculate the heterogeneous solution. The whole-core homogenized transport calculation step of the CSH method has been replaced with a whole- core homogenized diffusion calculation. A whole-core diffusion calculation is a reasonable replacement for transport because the homogenization procedure tends to smear out transport effects at the core level. The CHSH solution procedure is to solve a core-level homogenized diffusion equation with the auxiliary source term and then to apply an on-the-fly transport-based re-homogenization at the assembly level to correct the homogenized and auxiliary cross sections. The method has been derived in general geometry with continuous energy, and it is implemented and tested in fine group, 1-D slab geometry on controlled and uncontrolled BWR and HTTR benchmark problems. The method converges to within 2% mean relative error for all four configurations tested and has computational efficiency 2 to 4 times faster than the reference calculation.

Passive treatment systems for mine water pollution remediation require no chemical or energy inputs, and should only incur limited maintenance costs if properly constructed. This thesis investigates two such passive treatment systems that have been installed at sites in County Durham, UK. The overall objectives of the investigation were to improve understanding of the operation of passive systems in order to produce more accurate design guidelines, and to develop a new passive treatment option to complement existing technologies. To put the research into context the causes, impacts and extent of mine water pollution in the UK and overseas are outlined. In addition a detailed and up-to-date review of passive treatment research and development is provided, which highlights areas in which further research is required. At Quaking Houses, County Durham, a full-scale compost wetland has been constructed to treat an acidic and metal-rich discharge from the spoil heap of an abandoned coal mine. Over the 27 month study period the discharge had pH >_ 4, and mean iron, manganese and aluminium concentrations of 5.4 mg/L, 3.6 mg/L and 6.2 mg/L respectively. The unique design and construction of the 440 m2 wetland is described. An examination of the performance of the wetland illustrates that it has yielded significant improvements in water quality since its construction. Mean reductions in acidity, iron and aluminium concentrations are all around 50%. Bacterial sulphate reduction may be an important contaminant removal mechanism, but its proportional significance is unclear. Comparison of the system at Quaking Houses with other wetlands reveals that the mean reduction in acidity in terms of mass removal per unit area (5.01 g/m2/d) is comparatively low. However, it is shown that comparing wetland performance on this basis may be misleading where influent contaminant concentrations are relatively low, because contaminant removal is demonstrably influent concentrationdependent. A first-order removal assessment method of performance may be more appropriate, and on this basis the Quaking Houses wetland performs well when compared to systems in the USA. An algorithm for predicting wetland effluent iron concentrations is derived using a linear multiple regression technique. Time series analysis strongly suggests that some effluent water quality variables (and therefore wetland performance measures) are significantly affected by seasonal climate changes. In particular aluminium and acidity removal rates rise with increasing air temperature. This implies that to meet the same effluent water quality targets passive treatment systems in cold climate locations may need to be larger than equivalent systems in warmer climates. At Kimblesworth, also in County Durham, a pilot-scale passive treatment system has been operated for 4 months. The Kimblesworth discharge is a net-alkaline pumped mine water containing up to 2 mg/L iron and up to 1 mg/L manganese. The novel system at this site was designed to rapidly remove iron by oxidation and accretion of iron to high surface area media. The monitoring programme has revealed the system to be very efficient. Iron concentrations are consistently reduced to < 0.5 mg/L, and removal rates are an order of magnitude greater than in wetland systems. Furthermore, lithium tracer tests reveal that the residence time of water in the reactors is just 5- 10 minutes. The results of this research suggest that the technology could be applied at full-scale. The compost wetland at Quaking Houses and the new reactor at Kimblesworth may well complement each other. The Quaking Houses system generates alkalinity and removes metal contaminants, but effluent water still contains marginally elevated concentrations of iron (mean 2.4 mg/L). The Kimblesworth system is shown to be very effective at rapidly removing low concentrations of iron, and thus could conceivably be used as a polishing unit following a compost wetland such as that at Quaking Houses. Alternatively high surface area media reactors such as those at Kimblesworth could be used to treat discharges in topographically difficult locations, where the installation of a wetland is not feasible.

An integrated NOx adsorption-reduction process has been proposed in this study for the treatment of flue gases under lean-burn conditions by decoupling the adsorption and reduction into two different zones. The hypothesis has then been validated in a novel internal circulating fluidized bed. The adsorption and reaction performance of Fe/ZSM-5 for the selective catalytic reduction (SCR) of NOx with propylene was investigated in a fixed bed reactor. The fine Fe/ZSM-5(Albemarle) catalyst showed reasonable NOx adsorption capacity, and the adsorption performance of the catalyst was closely related to the particle size and other catalyst properties. Fe/ZSM-5 catalyst was sensitive to the reaction temperature and space velocity, and exhibited acceptable activity when O₂ concentration was controlled at a low level. Water in the flue gas was found to slightly enhance the reactivity of Fe/ZSM-5(Albemarle), while the presence of CO₂ showed little effect. SO₂ severely inhibited the reactivity of Fe/ZSM-5(Albemarle), and the deactivated catalyst could be only partially regenerated. Configurations of the reactor influenced the hydrodynamic performance significantly in a cold model internal circulating fluidized bed (ICFB) reactor. For all configurations investigated, the high gas bypass ratio from the annulus to draft tube (RAD) and low draft tube to annulus gas bypass ratio (RDA) were observed, with the highest RDA associated with the conical distributor which showed the flexible and stable operation over a wide range of gas velocities. Solids circulation rates increased with the increase of gas velocities both in the annulus and the draft tube. Gas bypass was also studied in a hot model ICFB reactor. The results showed that the orientation of perforated holes on the conical distributor could be adjusted to reduce RAD and/or enhance RDA. Coarse Fe/ZSM-5(PUC) and fine Fe/ZSM-5(Albemarle) catalysts were used in an ICFB and a conventional bubbling fluidized bed to test the NOx reduction performance. Coarse Fe/ZSM-5(PUC) catalyst showed poor catalytic activity, while fine Fe/ZSM-5(Albemarle) catalyst exhibited promising NOx reduction performance and strong inhibiting ability to the negative impact of excessive O₂ in the ICFB reactor, proving that the adsorption-reduction two-zone reactor is effective for the NOx removal from oxygen-rich combustion flue gases.

Thesis (Ph.D.) -- McMaster University, 1998. / Includes bibliographical references (p. 185-197). Also available via World Wide Web.

Thesis (Ph. D.)--University of Adelaide, Dept. of Chemical Engineering, 1963. / [Typewritten]. A thesis submitted for the degree of Doctor of Philosophy in the Faculty of Engineering of the University of Adelaide. Includes bibliographical references.