This study provides one of the first accounts of the relationships between termites, termitaria and the pedolith, towards developing their application as a biogeochemical sampling medium for mineral exploration. Mapping regolith–landforms, termitaria, and the associated termitaria biogeochemistry show that termites are an integral control on the organisation of trace metals in the landscapes of northern Australia. In particular, termites are important for transporting geochemical signatures from depth, through the pedolith and to the ground surface. This occurs by way of bioturbative and constructional activities of the mound-building termites, which in this study included Nasutitermes triodiae, Amitermes vitiosus, Drepanotermes rubriceps, Tumulitermes hastilis and T. pastinator. Termitaria from these species are mappable regolith– landform attributes at the local scale; this highlights their specific preferences for colony sites, such as access to vegetation, drainage, and the availability of construction materials. The mound-building termites featured in this study are also soil modifiers, altering the pedolith terms of both structure and chemistry. Developing an understanding of these processes has helped to refine a model for pedolith development through biotic processes, which is applicable to subtropical and tropical climatic regions, where termites act as important ecosystem engineers. This research project fills a niche for new scientific investigation of deeper regolith profiles and associated terrains; it moves away from theories of shallow soil development overlying an abiotic deep regolith, towards understanding pedolith development as wholly biotically driven. For mineral explorers this means that ore-related elements, such as Au, As and Zn, are re-organised and moved towards the land surface in settings such as buried Au-deposits and mineralisation in the Tanami region, and Pine Creek Orogen. A key finding within the study of the application of this technique is that the fine, silt-clay (>79 μm) from termitaria is capable of accurately delineating the surficial expression of buried Au mineralisation. Termitaria can therefore provide an accessible surficial biogeochemical sampling media that can be used in mineral exploration programs / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1369217 / Thesis (Ph.D.) - University of Adelaide, School of Earth and Environmental Sciences, 2009

In this thesis, we study the influence of heterogeneous distribution of optical and thermal properties on asteroid surfaces onto the YORP effect. Modelling of the surface heterogeneities is done in three ways. In the first one, we create an impact crater with higher albedo regolith on a regolith-covered asteroid. In the second way, we suppose presence of higher albedo regolith on steep slopes (slope angle > 35◦ ) and in the third one, we state properties of bare rock (with different thermal parameters) in these areas. Then we evaluate the influence of torques caused by scattered or thermally emitted radiation on 200 asteroids based on different distribution of described parameters by means of statistics. We have found that the presence of heterogeneities caused by landslides on asteroid surfaces does not significantly affect the YORP effect with two exceptions: a slight inclination to decelerate the rotation in the case of landslides uncovering bare rock due to critical rotation and significant preference for deceleration in the configurations with uncovered higher albedo regolith on steep slopes. Our data suggest that the influence of heterogeneous distribution of optical properties caused by landslides on the value of typical acceleration time, so-called doubling time td, is 2 % and it does not exceed 5 % in the case...

Scientists have been well aware of the complexity of Martian and lunar regoliths. There are vast unexplored areas on both, the Moon and Mars, as well as uncertainties in our understanding of the physicochemical properties of their regoliths. Lunar and Martian regoliths differ from terrestrial soils in that they appear granular, but are expected to contain some cohesion. As such, cohesion in regolith poses challenges for future space operations, more specifically for landing, settlement, and mobility purposes. The ability to induce prescribed levels of cohesion in regolith simulants and reliably measure it would allow scientists to evaluate space technology limitations under different operational scenarios on Earth prior to a mission. Therefore, the objectives of this research were to (1) develop methods to induce prescribed levels of cohesion in dry granular media, and (2) evaluate accessible and reliable testing methods to measure cohesion. We developed and evaluated several methods to induce cohesion in two types of dry sand, F-75 silica sand and generic play sand. The methods to induce cohesion included play sand mixed with sugar-water, polymeric sand, and nanocellulose fibers, as well as F-75 sand mixed with polydimethylsiloxane, polyvinyl acetate, crystalline silica, agar, zero-valent iron, adhesive spray, and sand surface modification using a plasma gun. Each method was assessed for advantages and disadvantages, and laboratory specimens produced using the most promising methods were tested at different compositions and densities to measure cohesion. The laboratory methods used to measure the cohesion included direct shear test, simple direct shear test, and vertical cut test. The results from these tests were then compared to tensile strength tests, using a split box test. In addition, these tests were also performed on lunar simulants JSC-1A and GRC-3 at different densities. The direct shear apparatus was available, but the other three devices were fabricated as part of this work. Based on the research results, simple methods to potentially induce low levels of cohesion in dry granular media are suggested along with suitability of laboratory methods to measure the added cohesion.

Red-brown hardpan occurs extensively in Western Australia in the arid and semi-arid regions of the Murchison, Pilbara and Eastern Goldfields divisions, between longitudes 115ºE and 124ºE and latitudes 23ºs and 30ºs. It occupies an area of about 360,000 sq. km, two thirds of which occurs in the Yilgarn Craton. The purpose of this research is to map the distribution of red-brown hardpan in the Yilgarn Craton of Western Australia; study the relationship between landscape, soil texture and vegetation; investigate the physical characteristics, petrology, mineralogy, geochemistry and cementing agents; and thereby determine the processes invaded in forming red-brown hardpan. The relation of red-brown hardpan to gold is investigated and determined its implications in mineral exploration. The main case study areas were the Goldfields Gas Pipe Line, the Federal Open Pit Gold mines and the Menzies district in the Kalgoorlie-Menzies region of the Eastern Goldfields; areas in and around the Woolgorong Station in the Murchison Province and at the Wiluna Gold Mines in the Northeastern Goldfields. The findings and conclusions of this research are summarised below. Red-brown hardpan occurs at or near the land surface and may vary from less than one metre to more than 10 m thick. It is exclusively developed in colluvium and alluvium, showing varying stages of cementation ranging from weakly cemented through moderate to strongly cemented. In addition, calcrete and red-brown hardpan occurs together in many places, south of the Menzies line, and this distribution suggests that red-brown hardpan was once more extensive and has been subsequently replaced by carbonate to form calcareous red-brown hardpan and calcrete. Red- brown hardpan predominantly occurs in regions with Q50 mm annual rainfall. / In present-day higher rainfall (400 to 500 mm) regions, red-brown hardpan is being weathered. There is no relationship between the distribution of mulga (Acacia aneura) and red-brown hardpan. Red-brown hardpan is exclusively developed in colluvium containing a minimum of 20% quartz, 15% clays and 2% iron oxides. It is bright reddish brown to reddish brown, earthy, with a sandy loam texture, blocky structure and porous. Red-brown hardpan is hard (up to 12 MPa), being characterised by sub-horizontal laminations predominantly of uncemented kaolinite. Ped surfaces may be coated by Mn oxide and carbonate which may be precipitated along the laminations. The mineralogy of the cement is complex. Data from XRD, SEM, TEM, EFTEM, FTIR and NIR investigations show poorly-ordered kaolinite and opal-A as the main components. Illuvial multilayered argillaceous cutans containing silica and alumina in a ratio of 2:l form the cement. Secondary silica (SiO2-95%) coatings are common, mainly as opal-A, on ped surfaces and on the inner walls of voids and vughs. Etch pits are developed in these coatings and some of them are filled by kaolinitic clays. Selective dissolution experiments using acid ammonium oxalate show that oxalate- soluble amorphous and poorly ordered silica and alumina in red-brown hardpan have molar ratios of about 1.6 to 2 A1203:SiO2. / These results suggest that red-brown hardpans were formed where there was sufficient water during the wet season to dissolve alumina and silica, but insufficient to leach them. During the subsequent dry season, the dissolved alumina and silica was precipitated as poorly-ordered kaolinite and opal-A. Successive dissolution and precipitation led to fusion of poorly-ordered kaolinite and opal-A at a nanometre scale to progressively cement the colluvium. The age of the red-brown hardpans, estimated by paleomagnetic dating of hematite, is from Pleistocene to present. Based on the findings of this research, the red-brown hardpan is redefined and primarily classified on its degree of cementation as: (1) weakly cemented, (2) moderately cemented and (3) strongly cemented. It is further classified chemically into: (1) siliceous, (2) calcareous and (3) ferruginous. In the Yilgarn Craton, red-brown hardpan is believed to occur mainly north of the 'Menzies Line'. However, this study reveals the presence of red-brown hardpan 75- 150 km south of the Menzies Line and the new southern boundary is closer to latitude 29ºs. Geochemical investigation at the Federal Open Pit Gold mines, Broad Arrow, north of Kalgoorlie indicate that there are Au anomalies in red-brown hardpan. Gold concentration is up to 50 ppb against the background anomaly of 10 ppb. Sequential and partial extraction analyses show significant correlation of Au with Ag, Ca, Ce, Co, Mg, Mn and Ni. This suggests that the Au concentration in red-brown hardpan is due to: (a) mechanical dispersion due to reworking of Au-bearing clasts in the sediment and (b) hydromorphic dispersion from the underlying mineralisation. It can therefore be used as a useful sampling medium for gold exploration.

The aim of this research is to determine to what extent properties of the regolith may be inferred using only features easily measured from the surface. To address this research question, a set of regolith properties from Weipa, Queensland, Australia, are analysed. The set contains five variables, oxides of Aluminium, Iron, Silica and Titanium, as well as Depth to Ironstone. This last represents the depth of the layer from which the oxides are sampled.¶ The research question is addressed in two ways. First, locations where the properties are related to modern surface hydrology are assessed using spatially explicit analyses. This is done by comparing the results of spatial association statistics using geometric and watershed-based spatial samples. Second, correlations are sought for between the regolith properties and geomorphometric indices of land surface morphology and Landsat Thematic Mapper spectral response. This is done using spatially implicit Artificial Neural Networks (ANN) and spatially explicit Geographically Weighted Regression (GWR). The results indicate that the degree to which regolith properties are related to surface measurable features is limited and spatially variable.¶ Most locations in the Weipa landscape exhibit some degree of modern hydrological control of the oxide variables at lateral distances of 120 m. This control rarely extends beyond 300 m laterally, although such locations occupy distinct positions in the landscape. Conversely, there is an extensive part of the landscape where Depth to Ironstone is under hydrological control. This occupies most of the lower elevations in the study area. Depth to Ironstone represents the depth to the redox front where iron is precipitated, but may in some parts of the landscape control the distribution of the watertable by being impermeable.¶ For the correlation analyses, the highest correlations are found with those oxides most mobile in solution. The spatially local GWR results also consistently outperform the spatially global ANN results, commonly having accuracies 40% higher at the error tolerance used. Much of this can be attributed to the localized effects of landscape evolution. Comparison of the GWR results against the local sample mean indicate that there is a relationship between regolith properties and surface measurable features at 10-15% of sample locations for the oxide variables, and 22% for Depth to Ironstone.¶ The implications of these results are significant for anyone intending to generate spatial datasets of regolith properties. If there is a low spatial density of sample data, then the effects of landscape evolution can reduce the utility of any analysis results. Instead, spatially dense, direct measurements of subsurface regolith properties are needed. While these may not be a direct measurement of the property of interest, they may provide useful additional information by which these may be inferred.

The research contained within this thesis was directed at examining the spectral properties of regolith-dominated terrains using airborne and proximal hyperspectral instruments. The focus of the investigation was to identify the mineralogy of the regolith and determine if surficial materials were indicative of the underlying bedrock in the regolithdominated terrain of the eastern Olary Domain, South Australia. The research area was constrained to a 250 km2 area around the Cu-Au mineralisation of the White Dam Prosect. Integrated remote sensing, using airborne hyperspectral datasets (HyMap), Landsat imagery and gamma-ray spectroscopy data, was performed to map regolith-landforms and extract information on surficial materials. Detailed calibration of the HyMap dataset, using a modified model-based/empirical line calibration technique, was required prior to information extraction. The White Dam area was able to be divided into: alluvial regolith-dominated; in situ regolith-dominated; and bedrock-dominated terrains, based on mineralogical interpretations of the regolith, using the remotely sensed hyperspectral data. Alluvial regions were characterised by large abundances of vegetation and soils with a hematite-rich mineralogy. Highly weathered areas of in situ material were discriminated by the presence of goethite and kaolinite of various crystallinities, whereas the bedrock-dominated regions displayed white mica-/muscovite-rich mineralogy. Areas flanking bedrock exposures commonly consisted of shallow muscovite-rich soils containing regolith carbonate accumulations. Traditional mineral mapping processes were performed on the HyMap data and were able to extract endmembers of regolith and other surficial materials. The Mixture Tuned Matched Filter un-mixing process was successful at classifying regolith materials and minerals. Spectral indices performed on masked data were effective at identifying the key regolith mineralogical features of the HyMap imagery and proved less time consuming than un-mixing processes. Processed HyMap imagery was able to identify weathering halos, highlighted in mineralogical changes, around bedrock exposures. Proximal spectral measurements and XRD analyses of samples collected from the White Dam Prospect were used to create detailed mineralogical dispersion maps of the surface and costean sections. Regolith materials of the logged sections were found to correlate with the spectrally-derived mineral dispersion profiles. The HyLogger drill core scanning instrument was used to examine the mineralogy of the fresh bedrock, which contrasted with the weathering-derived near-surface regolith materials. The overall outcomes of the thesis showed that hyperspectral techniques were useful for charactering the mineralogy of surficial materials and mapping regolith-landforms. / Thesis (Ph.D.)--School of Earth & Environmental Sciences, 2004.

<p>The complex nature and composition of regolith cover in Southern Africa is a major challenge to geochemical mapping for concealed mineralization. Some of the setbacks to successful geochemical exploration may be ascribed to the use of various partial extraction techniques,without a profound understanding of the regolith components and their composition. This investigation therefore focuses on the use of hydroxylamine partial extraction geochemistry for geochemical mapping in regolith over two contrasting environments viz / aeolian sand-calcrete regolith over Au mineralization at Amalia Blue Dot Mine in South Africa and lateritic regolith covering the Ni-Cu deposit at Kabanga Main and Luhuma in Tanzania. Regolith samples from the above areas were sieved and extracted with hydroxylamine hydrochloride solution and analyzed for multi-element by AAS and ICP-MS techniques. A stepwise optimization of the hydroxylamine extraction technique of samples from both areas was carried out and incorporated into the analytical programme (in a pilot study). Results of hydroxylamine partial extraction generally gave better anomaly contrast and reflection of bedrock mineralization than the conventional aqua regia techniques that were previously used in the region. The results however show that lateritic regolith may be best extracted using 0.25M hydroxylamine while 0.1M concentration appears most suitable for extraction of aeolian-calcrete regolith. The above results are corroborated by principal component analysis of the analytical data that show various element associations, e.g. with Fe-Mn oxides while others possibly belong to the loosely adsorbed or exchangeable group. The&nbsp / gochemical maps in the pilot study areas at Amalia, Kabanga and Luhuma show elevated element contents or clusters of anomalies of diverse elements associated with Fe-Mn oxides. Geochemical mapping at Kabanga with deeply concealed mineralization however shows variability of subdued element patterns over mineralized areas. Geochemical signatures associated with hydroxylamine hydrochloride partial leach are therefore characterized by a lower geochemical background than that using conventional aqua regia leach. This study leads recommending for further investigations into partial extraction of the exchangeable group of elements, possibly using ammonium acetate.</p>

The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Title from PDF of title page (University of Missouri--Columbia, viewed on December 30, 2009). Thesis advisor: Dr. Eric Sandvol. Includes bibliographical references.

<p>The complex nature and composition of regolith cover in Southern Africa is a major challenge to geochemical mapping for concealed mineralization. Some of the setbacks to successful geochemical exploration may be ascribed to the use of various partial extraction techniques,without a profound understanding of the regolith components and their composition. This investigation therefore focuses on the use of hydroxylamine partial extraction geochemistry for geochemical mapping in regolith over two contrasting environments viz / aeolian sand-calcrete regolith over Au mineralization at Amalia Blue Dot Mine in South Africa and lateritic regolith covering the Ni-Cu deposit at Kabanga Main and Luhuma in Tanzania. Regolith samples from the above areas were sieved and extracted with hydroxylamine hydrochloride solution and analyzed for multi-element by AAS and ICP-MS techniques. A stepwise optimization of the hydroxylamine extraction technique of samples from both areas was carried out and incorporated into the analytical programme (in a pilot study). Results of hydroxylamine partial extraction generally gave better anomaly contrast and reflection of bedrock mineralization than the conventional aqua regia techniques that were previously used in the region. The results however show that lateritic regolith may be best extracted using 0.25M hydroxylamine while 0.1M concentration appears most suitable for extraction of aeolian-calcrete regolith. The above results are corroborated by principal component analysis of the analytical data that show various element associations, e.g. with Fe-Mn oxides while others possibly belong to the loosely adsorbed or exchangeable group. The&nbsp / gochemical maps in the pilot study areas at Amalia, Kabanga and Luhuma show elevated element contents or clusters of anomalies of diverse elements associated with Fe-Mn oxides. Geochemical mapping at Kabanga with deeply concealed mineralization however shows variability of subdued element patterns over mineralized areas. Geochemical signatures associated with hydroxylamine hydrochloride partial leach are therefore characterized by a lower geochemical background than that using conventional aqua regia leach. This study leads recommending for further investigations into partial extraction of the exchangeable group of elements, possibly using ammonium acetate.</p>

During the Paleoproterozoic Era (ca. 2.5 Ga to 1.6 Ga), Earth underwent dramatic changes to its tectonic and atmospheric parameters. These changes included: the formation and breakup of the supercontinent Nuna (Columbia) and the gradual rise in atmospheric oxygen levels. The gradual rise in atmospheric oxygen, referred to as the Great Oxidation Event (GOE), altered the behaviour of silicate mineral weathering, and permitted the formation of new types of economic uranium deposits. Beaverlodge Lake, Northwest Territories (NT), allows for the study of a weathering profile and uranium mineralization post GOE. At Beaverlodge Lake, NT, a regolith is preserved in a rhyodacitic porphyry of the ca. 1.93 Ga Hottah plutonic complex, which is unconformably overlain by the ca. 1.9 Ga quartz arenite of the Conjuror Bay Formation. Coincident with the unconformity is a past-producing uranium deposit (called the Tatie U deposit), which was mined out in the 1930s. Other uranium showings have been discovered at Beaverlodge Lake including the Bee showing. The initial purpose of this project was to examine the regolith through field, petrography, electron microprobe analysis (EMPA), whole-rock geochemistry, and mass balance calculations. The weathering profile shows an increase in Al2O3, Fe2O3T, K2O, P2O5, Ba, and Rb, a loss in SiO2, Na2O, MgO, and Sr, and constant and low abundance of CaO. Titanium remains constant in the weathering profile. Rare earth element (REE) analysis reveals remobilization of light REE (LREE) on a micrometer scale, but no cerium anomaly is preserved in the weathering profile. The weathering profile displays characteristics similar to other post GOE paleoweathering profiles developed on felsic parental material. The timing of uranium mineralization at Tatie and Bee was constrained by in-situ U-Pb uraninite dating by Secondary Ion Mass Spectrometer (SIMS), which yielded two variably discordant ages of 1370.2 ± 7.9 Ma and 407 ± 21 Ma. In addition, REE contents of uraninite were determined by in-situ Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). Results revealed two types of uraninite mineralization are preserved at Beaverlodge Lake and they consist of synmetamorphic at Bee and basement-hosted unconformity-type at Tatie similar to those in the Athabasca Basin. The ca. 1370 Ma uraninite (Tatie) is characterized by an asymmetric bell-shaped REE pattern centered on Tb to Er where LREEs are depleted compared to heavy REEs (HREE). The ca. 407 Ma uraninite at Bee has low La concentrations and a flat to slightly negative REE pattern. The Mesoproterozoic age is similar to a Pb loss age of ca. 1400 Ma found in the Athabasca Basin. The younger Devonian age may be related to meteoric fluids cycling and uranium remobilization during the Phanerozoic.