In this dissertation, we have examined mineral assemblages and geomorphologic features in the Sisyphi Planum region of Mars, as well as examined the mineral assemblage of palagonite in Iceland. Chapter 2 is focused on the mineral assemblages detected on possible glaciovolcanic edifices in the Sisyphi Planum region of Mars. Minerals were identified utilizing visible/near-infrared orbital spectra from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Analysis of eleven CRISM images located on the volcanic edifices revealed three distinct spectral classes in the region which are interpreted to be: gypsum-dominated, smectite-zeolite- iron oxide-dominated (possibly palagonite), and polyhydrated sulfate-dominated material. The possible palagonite detections on the volcanic edifices, the geomorphology of the region, and the analogous terrestrial mineralogy of subglacial eruptions strongly suggests the formation of these minerals during subglacial eruptions or associated hydrothermal systems. This implies that thick water ice sheets were present in this region in the late Noachian or early Hesperian, and that the subglacial hydrothermal systems could have supported habitable environments with excellent biosignature preservation potential. Chapter 3 is focused on evaluating the variability of the composition and crystallinity of palagonite on Earth in order to inform efforts to identify it on Mars. We hypothesized that variability in palagonite composition and crystallinity could occur due to differences in environmental conditions during formation. Palagonite samples were collected in Iceland at subglacial volcanic sites around Reykjavík in the Western Volcanic Zone, on the southern coast in the Eastern Volcanic Zone, and from the Herðubreið tuya and Askja volcano in the Northern Volcanic Zone. Visible/near-infrared reflectance spectroscopy, thermal-infrared emission spectroscopy, and quantitative XRD were used to assess the bulk mineralogy, crystallinity, and clay composition of all samples. Results show the sampled palagonites contain partially devitrified glass, unaltered glass, and secondary minerals including clay minerals, poorly crystalline ferric oxides, and zeolites. However, one sample (SCoast01) shows a vastly different mineral assemblage in all sample techniques, including well-crystalline Fe/Mg-clays as opposed to the poorly-crystalline Al-clays observed in our other samples. Based on previous studies of subaqueous palagonites and the location this sample was collected from, we hypothesize that the SCoast01 sample was formed in a submarine environment rather than subglacial. This suggests that it may be possible to differentiate submarine vs. subglacial palagonite on Earth based on composition and from remote sensing observations on Mars. Chapter 4 is a geomorphologic study of the Sisyphi Planum region of Mars where we identified and classified the tops of the Sisyphi Montes as well as geomorphologically mapped the Sisyphi Planum region. Here, we address an overarching question: What is the relationship between the Sisyphi Montes and the ice in this region? To do this, we identified 106 edifices in the region and classified them into five categories: 1) flat topped, 2) rounded tops, 3) sharp peaks, 4) cratered peaks, and 5) height less than 300 meters – a “catch-all” category for all features below the specified height, which exhibit less distinctive morphologies in MOLA topography. While many of the edifices could be sub-glacial in origin, we find that the only morphologic class that exhibits uniquely subglacial morphologies are the flat-topped edifices. These edifices are similar to terrestrial tuyas, which form when a subglacial volcano breaches an ice sheet and erupts a plateau of sub-aerial lavas. Based on the geomorphologic map and topographic data, we have shown that flat-topped edifices are all located outside of regions that we map as the Mantled Unit, which we infer to be related to the Dorsa Argentina Formation. The combination of the flat topped edifices and their location outside of the mapped ice-related regions strongly suggests that the ice in the region was once more extensive than what is currently observed. While this has been proposed in the past, it has not been documented how far the ice sheet could have extended. Here we show that the ice must have extended to at least as far as the flat topped edifices in the region. The combination of these chapters using both mineralogy and morphology suggest that the Sisyphi Planum region of Mars was subglacial in origin. <br><br>

Context. The Martian methane and water cycle are subject of ongoing research through simulation. Exchange with the subsurface has a potentially strong impact, but is often neglected. Aims. For methane, I determine if adsorption with an increased enthalpy can explain the observed seasonal variations and conflicting observations by the Trace Gas Orbiter and the Curiosity rover. For water, the impact of adsorption and ice formation in the subsurface on the global cycle is studied. A new way of initializing the soil, by running a decoupled subsurface model, is tested. Depths of stable subsurface ice and subsurface water distributions are studied. Methods. A General Circulation Model (GCM) is used with a purely diffusive subsurface model. For methane, different initial states, source scenarios, and decay times are tested. For water, a model without an active atmosphere is implemented to provide an initial state. The effect of the subsurface with this initial state on the full atmospheric water cycle is tested. Results. For methane, a strong influence on the global methane cycle is observed. Seasonal variations measured at Gale Crater are reproduced, but the conflicting observations cannot be explained by adsorption. For water, the new initialization can be used without completely disrupting the water cycle. It leads to a generally wetter atmosphere, in conflict with observations. Found ice table depths do not match well with observations, but ice profiles reproduce previous findings. Conclusion. Methane adsorption is able to partly explain observed variations, but cannot be the only process to influence methane abundances. The new initialization method for water works well in principle, but a more refined model is needed for more realistic results.

Over the past decade studies into the application of radiometrics for soil and regolith mapping have met with mixed response. While the use of radiometric data for regolith mapping has been generally well received, radiometric methods have not commonly been adopted to assist and improve soil mapping. This thesis contributes to the development of radiometric techniques as soil and regolith mapping tools by examining soil characteristics and radiometric response using non-standard radiometric methods. This is accomplished through the development of new data processing methodologies, which extracts additional information from standard radiometric data that is unattainable using standard processing methods, and development of a new interpretation approach to soil and regolith mapping employing the multispectral processed radiometric data. The new multispectral processing methodology resolves seven gamma ray peaks from standard 256-channel NaI radiometric data to produce new radiometric uranium ternary, thorium ternary and uranium ratio imagery. Changes in the gamma ray relationships, identified through the new imagery, identify changes in soil and/or environmental conditions that are absent or difficult to identify in the standard radiometric imagery. With the isolation of non-standard thorium channels 228 [superscript] Ac (900 keV) and 228 [superscript] Ac (1600 keV), case studies in this thesis demonstrate how the difference of 1.9 years (half-life) between thorium 228 [superscript] Ac and 232 [superscript] Th decay daughter products can be mapped through the interpretation of thorium energy using ternary imagery [red: 208 [superscript] Tl (1764 keV), green: 228 [superscript] Ac (900 keV), blue: 228 [superscript] Ac (1600 keV)]. Energy peak differences may be be linked to local variations in soil chemistry, soil movement, and water movement. / Additionally, through the isolation of non-standard uranium channels 214 [superscript] Bi (1120 keV) and 214 [superscript] Bi (1253 keV), preferential attenuation of lower energy gamma-rays from 214 [superscript] Bi decay events are exploited to map variations in soil density and/or porosity. These variations are illustrated through the interpretation of uranium energy using ternary imagery [red: 214 [superscript] Bi (1764 keV), green: 214 [superscript] Bi (1120 keV), blue: 214 [superscript] Bi (1253 keV)] and uranium peak energy ratio [214 [superscript] Bi 1120 keV / 214 [superscript] Bi 1764 keV] pseudo colour imagery. Case studies examined in this thesis explore the characteristics of 256-channel radiometric spectrum from different resolution datasets from different Western Australian soil types, provide recommendations for acquiring radiometric data for soil mapping in different agricultural environments, demonstrate how high resolution 256-channel radiometric data can be used to model soil properties in three-dimensions, and illustrate how three-dimension soil models can be used to separate surface waterlogging influences from rising groundwater induced waterlogging.

Construction of a 1:250,000 scale regolith-landform map of the Cobar area of central New South Wales (NSW) Australia, demonstrates the presence of a wide range of previously undescribed regolith materials, landforms and landscape features in the region. The map covers the east-west extent of the Cobar Basin, extends to the west onto the Darling River Floodplain, and east onto rocks of the Girilambone Group. The mapping area is centred on the Cobar township and covers -14,730 krn2 between 303113 and 446113 E and 6483184 and 6586183 N (AGO 66, MGA Zone 55). 48 regolithlandform units have been identified, including both transported (alluvial, colluvial, aeolian, lacustrine) and in situ materials. A range of siliceous, ferruginous and calcareous indurated materials are also present. Four major drainage types have been identified based on lithological, sedimentological and topographic differences in alluvial materials. The 4 drainage types include: 1) modern drainage; 2) maghemite and quartzose gravels elevated 1-2 m relative to the modern drainage; 3) higher topographically inverted, and at least partly silicified, gravels; and, 4) sediments of Cretaceous origin. Multiple phases of drainage stability and instability from the Cretaceous to the present are indicated within the sediments. Breaching of drainage divides and increased dissection of the modern drainage, especially to the south of Cobar, indicate possible tectonic movement across a major regolith-landform boundary in the southern map area. Colluvial materials are more widespread to the north of Cobar reflecting the increased landscape dissection to the south. Colluvial fans are preserved adjacent to major rangefronts. Aeolian and lacustrine materials include longitudinal dunefields of the Darling River floodplain, source bordering dunes, and small lunettes associated with the Barnato Lakes system. Regolith-landform mapping at Cobar has been used to assess the applicability of previously developed landscape evolution models of the Cobar Block and surrounding region, and to develop a new landscape evolution model for the region. The new landscape evolution model of Cobar indicates minimal deposition of Cretaceous sediments, succeeded by high-energy early Tertiary fluvial regimes across the Cobar landscape. Weathering and sediment deposition continued into the Miocene, coupled with deep valley incision on the Cobar Block associated with early Oligocene regression. By the close of the Miocene, the Cobar Block had eroded to predominantly bedrock terrain and widespread filling of previously incised valleys occurred. A decrease in erosion and fluvial activity led to the formation of the modern drainage during the Pliocene-early Quaternary, followed by the formation of alluvial, aeolian and lacustrine deposits in the later Quaternary. Regionally, Eromanga Basin sediments were not extensive over the Cobar Block, and low rates of erosion are recorded at Cobar from the Cretaceous to the present. Former northerly drainage did exist in this area in the Cretaceous, but was limited in distribution. By at least the Early Tertiary the Cobar area was a structural high and drainage systems of the region had assumed their current configuration. These findings do not support interpretations of AFTT data of significant cover and subsequent stripping over the Cobar Block in the Early Tertiary. Evidence of landscape evolution from the Cretaceous to the present suggests that the Cobar landscape has been responding to changes in the primary landscape forming factors of lithology, climate and to a lesser degree, tectonics. Variations in the these three primary landscape forming factors have contributed to ongoing weathering, relatively continuous deposition, and periods of relative stability and instability, particularly in response to climatic and baselevel fluctuations, within a dynamically evolving landscape throughout the entire Tertiary. Former landscape evolution models of peneplanation and pediplanation, based on correlation of palaeosurfaces including duricrusts, a deep weathering profile developed during extended planation in the Early Tertiary, and tectonism during the late Tertiary in the Cobar area, are not supported by evidence preserved in regolith-landform features at Cobar.

Landholders in the Booberoi to Quandialla (B-Q) Transect area, located in central west NSW, have been concerned about an emerging dryland salinity problem since the late 1990�s (Wooldridge 2002, pers. comm. Muller 2002, pers. comm.) with borehole information and electromagnetic induction investigations supporting anecdotal observations. The presence of indicator vegetation, waterlogging of soils and salinisation of land are becoming increasingly prevalent, with two well-documented sites including �Strathairlie� near Quandialla, and �Back Creek� near West Wyalong. The B-Q Transect area lies within the Bland Creek Catchment, a broad open plain of subdued topography and restricted drainage receiving sediments from elevated rises located to the west, south and east. Significant deposits of transported alluvial materials have in-filled the catchment to depths in excess of 160 m and have posed a particular impediment to regional-scale mineral exploration. Stream flow across the alluvial plains and low angle alluvial fans is intermittent with most of the flow being diverted into groundwater storage or lost to evaporation. Rarely do streams flow into Lake Cowal to the north. A partial electromagnetic (EM) induction survey coupled with a long term bore and piezometer network monitoring program have been implemented by the Department of Infrastructure, Planning and Natural Resources (DIPNR � formerly Department of Land and Water Conservation) Central West NSW Salt Group. These programs allow for initial, broad-scale evaluation of the magnitude and spatial distribution of the salinity problem but fail to pinpoint remaining sites at risk as well as the mechanisms of salt emplacement. As part of an approach to assist with hazard mitigation and land management, two regolith-landform maps are being compiled using 1:20,000 scales in the Back Creek and Quandialla areas. A third, more regional regolith-landform map at 1:50,000 scale (Holzapfel & Moore 2003a, b & c) provides context for the more detailed mapping areas. The new regolith-landform maps will aid in interpretation of existing geophysical techniques, help piece together the three-dimensional characteristics of the Bland Creek catchment, aid in the development of a shallow fluid flow and palaeotopographic model and assist land managers in formulating land management units (LMU�s). The three-dimensional integration of regolith-landform mapping, electromagnetic studies, bore information and other geophysical methods is critical in determining the interaction, distribution and movement of groundwater in the Bland Creek Catchment as buried palaeochannels represent preferred fluid pathways. The distribution of these palaeochannels has implications for future dryland salinity outbreaks, the remediation of current outbreaks and mineral exploration closer to the well-known Wyalong Goldfield (Lawrie et al., 1999). The western quarter of the B-Q Transect area partially overlaps with the recently completed GILMORE Project (Lawrie et al., 2003a,b & c), a multi-disciplinary study, coordinated by Geoscience Australia (GA) and the Bureau of Rural Sciences (BRS). Regolith-landform information in addition to gamma-ray spectrometry, magnetics, airborne electromagnetics and a digital elevation model acquired by the GILMORE Project have been incorporated into regolith-landform maps over the B-Q Transect. The incorporation of these datasets has helped not only extend the usefulness of the GILMORE Project data but provide a consistent, regolith-landform coverage for the broader Bland Creek Catchment. Regolith-landform mapping has been successful in highlighting major recharge zones for local and intermediate flow systems. The mechanisms for dryland salinity at two well-known sites have also been determined. Increasing salt stores are occurring through evaporation of intermittent floodwaters sourced from floodplains, back plains and broad meandering existing creek systems and recharging partially exposed palaeochannels intersecting the surface. Due to the shallow nature of these partially exposed palaeochannels, evaporation further concentrates the salt load in the soil profile. It is unknown if mapped shallow palaeochannels further away from current drainage systems are affected by rising salt loads. Regolith-landform mapping highlights two additional risk factors common to the 1:50,000 and 1:20,000 scale B-Q Transect mapping areas including widespread waterlogging of soils and wind erosion. Due to the subdued topography, features such as gilgai, fences and roads are having an effect on drainage modification. Wind erosion was also observed to play a major role within the B-Q Transect with significant loss of topsoil creating hardened clay surfaces resistant to water infiltration and significant redistributed deposits of aeolian materials. Interpretation of regolith-landform mapping against geophysical datasets and drill hole data show considerable lateral and vertical variation of regolith units. This variation of regolith distribution with depth does not reduce the effectiveness of using regolithlandform mapping as a valued management tool. The subdued relief coupled with the complex interplay between recharge zones, discharge zones and surficial drainage networks over the B-Q Transect still requires a detailed knowledge of surface regolithlandform characteristics whilst reinforcing the need for a multidisciplinary approach to gain a 3D perspective. Catchment analysis has been performed on drainage systems within the Bland Creek Catchment and has helped explain the strong effect different catchments have had on sediment supply to the Bland Basin. Catchment analysis results have been used in basic calculations of salt loads in the Bland Creek Catchment. An estimated 18,780 Tonnes/yr of salt enter the Bland Creek catchment and as stream flow out of the Bland Creek Catchment is intermittent, salt stores are increasing in the upper margins of the soil profile and groundwater reserves. Reconstruction of the palaeotopography of the B-Q Transect has been made possible using a mutli-disciplinary approach incorporating information from regolith-landform mapping, drill hole information, gamma-ray spectrometry and GILMORE Project datasets. The production of large-scale regolith-landform mapping, the development of a shallow fluid flow model and reconstruction of palaeotopography builds on and contributes to knowledge of the Bland Creek Catchment allowing for detailed farmscale and paddock-scale land management decisions.

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

A suite of lightning strike glasses and unmelted starting materials has been studied by electron microscope and Mossbauer spectroscopy to determine Fe oxidation states. Nine of eleven samples are reduced compared to the starting materials; four of the glasses contain Fe0. Only one sample contained evidence of reduction by carbon, and the results support the reduction of Fe as intrinsic to the rapid, high temperature processing during lightning strikes.A thermodynamic modeling code is used to model the formation of moldavite tektites and the reduction of Fe from sediments around the Ries crater. During isentropic cooling from a strong shock, Fe3+ is reduced to Fe2+ at all modeled conditions. The best matches to an average moldavite composition and the compositions of the Bohemian and Bohemian:Radomilice sub-strewn fields occur with a mixture of surface and subsurface sands along a 4500 J/kg-K isentropic cooling path, consistent with an asteroid impact. The Lusatian and Moravian sub-strewn fields are better represented by starting materials of entirely surface sands, consistent with the uppermost layers of surface material having traveled the farthest from the impact.The thermodynamic code is also used to investigate the formation of lunar regolith agglutinates and reduction of Fe to Fe0. Forming Fe0 requires assuming Fe0 is miscible in silicate liquid at elevated temperatures and pressures. When Fe0 is included in the liquid solution, it is stable at modeled conditions. Simple separation of liquid from vapor is not sufficient to reproduce agglutinate glass. When the vapor phase is allowed to partially redeposit and some Fe0 is directly condensed from vapor, the resulting liquid better reproduces mare agglutinate glasses. This model cannot reproduce highland agglutinate glass, because the Al concentration remains too high in the liquid. The best match to mare glass is produced using the <10 µm fraction of the mare soil along the 8000 J/kg-K cooling isentrope at 100 bars, 4370 K with 95% vapor redeposition and 50% of the Fe(g) directly condensed as Fe0. The reduced fulgurite samples and the results of the impact models suggest that Fe reduction is intrinsic to the rapid, high temperature processing of silicates.

Thesis (Ph.D.)--University of Wollongong, 2005. / Typescript. Disc in back pocket contains appendix 11. Includes bibliographical references.

abstract: Planetary surface studies across a range of spatial scales are key to interpreting modern and ancient operative processes and to meeting strategic mission objectives for robotic planetary science exploration. At the meter-scale and below, planetary regolith conducts heat at a rate that depends on the physical properties of the regolith particles, such as particle size, sorting, composition, and shape. Radiometric temperature measurements thus provide the means to determine regolith properties and rock abundance from afar. However, heat conduction through a matrix of irregular particles is a complicated physical system that is strongly influenced by temperature and atmospheric gas pressure. A series of new regolith thermal conductivity experiments were conducted under realistic planetary surface pressure and temperature conditions. A new model is put forth to describe the radiative, solid, and gaseous conduction terms of regolith on Earth, Mars, and airless bodies. These results will be used to infer particle size distribution from temperature measurements of the primitive asteroid Bennu to aid in OSIRIS-REx sampling site selection. Moving up in scale, fluvial processes are extremely influential in shaping Earth's surface and likely played an influential role on ancient Mars. Amphitheater-headed canyons are found on both planets, but conditions necessary for their development have been debated for many years. A spatial analysis of canyon form distribution with respect to local stratigraphy at the Escalante River and on Tarantula Mesa, Utah, indicates that canyon distribution is most closely related to variations in local rock strata, rather than groundwater spring intensity or climate variations. This implies that amphitheater-headed canyons are not simple markers of groundwater seepage erosion or megaflooding. Finally, at the largest scale, volcanism has significantly altered the surface characteristics of Earth and Mars. A field campaign was conducted in Hawaii to investigate the December 1974 Kilauea lava flow, where it was found that lava coils formed in an analogous manner to those found in Athabasca Valles, Mars. The location and size of the coils may be used as indicators of local effusion rate, viscosity, and crustal thickness. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2018

Thema der vorliegenden Arbeit ist die Identifikation, Differenzierung und Bewertung von vorhandenen Schwermetallreservoirs im Hangbereich historischer Erzbergbaugebiete im Nordpfälzer Bergland und dem Spessart. Dazu wurden auf Grundlage von 115 Bodenprofilen entlang von 14 Hangsequenzen die holozäne Umweltgeschichte, die Verbreitung und Struktur sowie ausgewählte ökologische Eigenschaften der quartären Hangsedimente erstmalig integrativ analysiert. Besondere Beachtung fanden hierbei die Schwermetallgehalte der quartären Hangsedimente und ihr immanentes Gefährdungspotential, das für die Untersuchungsgebiete zum ersten mal auf Grundlage der aktuellen rechtlichen Grundlagen bestimmt wurde. Die Auflösung einer hochauflösenden Boden- und Sedimentaufnahme mit exemplarischer Beprobung ermöglichte die Analyse vieler Details, Merkmale und Eigenschaften der Sedimente und Bodenbildungen dieser (stark) gestörten Standorte im Mittelgebirgsbereich.