Yes / Mechanochemical synthesis has the potential to change the way in which chemistry is conducted, particularly with regard to removing or dramatically reducing the need for solvents. Recently, it has been demonstrated that mechanochemistry can be carried out continuously and on large scale through the use of twin-screw extrusion (TSE). TSE has successfully been applied to the synthesis of cocrystals, metal organic frameworks (MOFs), deep eutectic solvents (DESs), metal complexes, and organic condensation reactions. However, while TSE provides a route for mechanochemical synthesis to be developed into a continuous, high-volume manufacturing process, little is currently understood about how to best optimize the various process parameters involved. Herein, we investigate the use of a batch mixer that has been previously used in polymer processing, to optimize mechanochemical reactions performed by extrusion. In particular, reactions between 8-hydroxyquinoline (Hq) and metal acetate salts of zinc or aluminum to give quinolinate complexes Znq2·AcOH and Alq3·AcOH, which are of interest for organic light-emitting diode (OLED) applications, have been investigated. The manner in which the progress of the reaction correlates with the machine torque, temperature, and specific mechanical energy (SME) imparted by the batch mixer has been elucidated. Significantly, this knowledge enabled optimization of the mechanochemical reactions by TSE through the key parameters of screw speed, feed rate, temperature, and particle size. / EPSRC (EP/L019655/1).

This work considers formulation of new classes of adaptive controllers for double-integrator type systems where the underlying system parameters are uncertain and the complete state-vector is not available for feedback. Given the parameter uncertainty within the system model, a "separation principle" cannot generally be invoked towards an observer geared towards reconstruction of the full state vector using only measured variables. In this report, controllers are designed for some important sub-classes of Euler-Lagrange type mechanical systems, where states are physically interpreted as position and velocity variables, and only the position part of the state vector is available as measured output. The typical approach to obtain velocity estimates using position interpolation (also known as dirty differentiation), is known to be strongly susceptible to measurement noise and therefore does not usually represent a robust option for feedback control implementation. The proposed control scheme achieves global asymptotic stability for system dynamics subject to the condition that velocity states appear within the governing dynamics in a linear fashion. This arguably restrictive condition is loosened for the special case of scalar system with friction non-linearity as is typical within hardware implementations. The objective is to study prototypical mechanical systems with non-linearity appearing in the velocity rate equations with the eventual applications envisioned towards the attitude control problem accounting for the gyroscopic non-linearity in the Euler rotational dynamics. Based on classical certainty equivalence approaches for adaptive control, one cannot readily deal with cross terms associated with parameter estimates and unmeasured states in the Lyapunov function derivative in order to make the Lyapunov function negative definite or negative semi-definite. However, employing a new approach, this obstacle is shown in this report to be circumvented for scalar systems. In order to generalize the methodology for higher-order dynamics, a filtered state approach is used. Specifically, an auxiliary variable is introduced which plays an important role in determining restrictions on the control parameters and analyzing the stability. The proposed approach helps to overcome the uniform detectability obstacle. Additionally, this work can be applied to uncertain linear systems where independent control inputs are applied on each of the velocity state dynamics. Lastly, the solution for the scalar is applied to the rotor speed control system and is extended to the case where Coulomb friction is considered in addition to viscous friction. Since a sign function can be approximated as a hyperbolic tangent, the tanh model is used for the Coulomb friction. A controller is developed with the assumption that the coefficients of these frictions are unknown. The proposed control is then verified with Educational Control Product Model 750 Control Moment Gyroscope, and the simulation and actual test results are compared. / text

Nesta tese de doutorado é proposta uma abordagem para estimar a velocidade angular de geradores síncronos conectados em um sistema elétrico de potência, a partir de sinais que podem ser facilmente mensurados, tais como a corrente e a tensão na barra do lado de alta tensão do transformador que conecta o gerador em análise ao restante do sistema. Uma vez que informações precisas sobre o comportamento dinâmico do sistema são de elevada importância para um controle efetivo do SEP, especialmente com o aumento da complexidade da rede, a abordagem proposta nesta tese fornece uma estimativa do sinal de velocidade que pode ser aplicada no estudo da estabilidade a pequenas perturbações para mitigar os problemas inerentes a presença das oscilações eletromecânicas mal amortecidas nos SEPs. A abordagem desenvolvida é composta por dois métodos sendo cada um deles aplicável dependendo das características do problema a ser resolvido e das informações disponíveis para tanto. No primeiro método, uma técnica de sensibilidade da trajetória é aplicada ao sinal de diferença entre a resposta obtida pelo modelo simulado e aquela fornecida por dados amostrados no sistema real emulado. A partir desse sinal de erro e das curvas de sensibilidade, a técnica possibilita calibrar os coeficientes de um modelo linear do SEP e, consequentemente, descrever de forma precisa a resposta da velocidade do gerador em análise. No segundo método, uma técnica de filtragem é utilizada (filtro de Kalman Unscented) a qual fornece uma estimativa adequada para a velocidade angular do rotor mesmo quando elevadas discrepâncias são observadas entre a saída do modelo simulado e a resposta amostrada no sistema real. Os resultados obtidos sobre diferentes sistemas testes evidenciam a eficiência da abordagem proposta. / In this thesis, an approach is proposed to estimate the rotor speed of synchronous generators connected to an electric power system (EPS), from signals that can be easily sampled by measuring equipment, such as current and voltage in high voltage side of the step-up transformer of the power plant. Accurate information about the dynamic behavior of system is essential for effective control and reliable operation of EPS, especially with the increasing complexity of the grid. Hence, the main aim of this work is to provide an estimate of the rotor speed signal that can be applied in the area of small-signal stability, in order to mitigate the detrimental effects of poorly damped electromechanical oscillations in EPSs. The developed approach is composed of two methods, where each of them is applicable depending on the characteristics of the problem to be solved and the available information. In the first method, a trajectory sensitivity technique is applied on the mismatch between the simulated output in the system linear model and the response of the real system. Using this error signal and the sensitivity curves, this method allows to identify and to calibrate some coefficients of the linear model and, consequently, to adequately describe the speed response of the generator under analysis. In this second method, a filtering technique is used, the Unscented Kalman Filter, which provides an adequate estimate for rotor speed even when high discrepancies are observed between the linear model and the sampled response of real system. The results obtained on test systems with different characteristics show the efficiency of the proposed approach.

Nesta tese de doutorado é proposta uma abordagem para estimar a velocidade angular de geradores síncronos conectados em um sistema elétrico de potência, a partir de sinais que podem ser facilmente mensurados, tais como a corrente e a tensão na barra do lado de alta tensão do transformador que conecta o gerador em análise ao restante do sistema. Uma vez que informações precisas sobre o comportamento dinâmico do sistema são de elevada importância para um controle efetivo do SEP, especialmente com o aumento da complexidade da rede, a abordagem proposta nesta tese fornece uma estimativa do sinal de velocidade que pode ser aplicada no estudo da estabilidade a pequenas perturbações para mitigar os problemas inerentes a presença das oscilações eletromecânicas mal amortecidas nos SEPs. A abordagem desenvolvida é composta por dois métodos sendo cada um deles aplicável dependendo das características do problema a ser resolvido e das informações disponíveis para tanto. No primeiro método, uma técnica de sensibilidade da trajetória é aplicada ao sinal de diferença entre a resposta obtida pelo modelo simulado e aquela fornecida por dados amostrados no sistema real emulado. A partir desse sinal de erro e das curvas de sensibilidade, a técnica possibilita calibrar os coeficientes de um modelo linear do SEP e, consequentemente, descrever de forma precisa a resposta da velocidade do gerador em análise. No segundo método, uma técnica de filtragem é utilizada (filtro de Kalman Unscented) a qual fornece uma estimativa adequada para a velocidade angular do rotor mesmo quando elevadas discrepâncias são observadas entre a saída do modelo simulado e a resposta amostrada no sistema real. Os resultados obtidos sobre diferentes sistemas testes evidenciam a eficiência da abordagem proposta. / In this thesis, an approach is proposed to estimate the rotor speed of synchronous generators connected to an electric power system (EPS), from signals that can be easily sampled by measuring equipment, such as current and voltage in high voltage side of the step-up transformer of the power plant. Accurate information about the dynamic behavior of system is essential for effective control and reliable operation of EPS, especially with the increasing complexity of the grid. Hence, the main aim of this work is to provide an estimate of the rotor speed signal that can be applied in the area of small-signal stability, in order to mitigate the detrimental effects of poorly damped electromechanical oscillations in EPSs. The developed approach is composed of two methods, where each of them is applicable depending on the characteristics of the problem to be solved and the available information. In the first method, a trajectory sensitivity technique is applied on the mismatch between the simulated output in the system linear model and the response of the real system. Using this error signal and the sensitivity curves, this method allows to identify and to calibrate some coefficients of the linear model and, consequently, to adequately describe the speed response of the generator under analysis. In this second method, a filtering technique is used, the Unscented Kalman Filter, which provides an adequate estimate for rotor speed even when high discrepancies are observed between the linear model and the sampled response of real system. The results obtained on test systems with different characteristics show the efficiency of the proposed approach.

Optimizing the operation and maintenance of wind turbines is crucial as the wind energy sector continues to expand. Predicting the mass imbalance of wind turbines, which can seriously damage the rotor blades, gearbox, and other components, is one of the key issues in this field. In this work, we propose a machine learning-based method for predicting the mass imbalance of wind turbines utilizing information from multiple sensors and monitoring systems. We collected data and trained the model from Adwen AD8 wind turbine model and evaluated on the real wind turbine SCADA data which is located at Fraunhofer IWES, Bremerhaven. The data included various parameters such as wind speed, blade root bending moments and rotor speed. We used this data to train and test machine learning classification models based on different algorithms, including extra-tree classifiers, support vector machines, and random forest. Our results showed that the machine learning models were able to predict the mass imbalance percentage of wind turbines with high accuracy. Particularly, the extra tree classifiers with blade root bending moments outperformed other research for multiclassification problem with an F1 score of 0.91 and an accuracy of 90%. Additionally, we examined the significance of various features in predicting the mass imbalance and observed that the rotor speed and blade root bending moments were the most crucial variables. Our research has significant effects for the wind energy sector since it offers a reliable and efficient way for predicting wind turbine mass imbalance. Wind farm operators can save maintenance costs, minimize downtime of wind turbines, and increase the lifespan of turbine components by identifying and eliminating mass imbalances. Also, further investigation will allow us to apply our method to different kinds of wind turbines, and it is simple to incorporate into current monitoring systems as it supports prediction without installing additional sensors. In conclusion, our study demonstrates the potential of machine learning for predicting the percentage of mass imbalance of wind turbines. We believe that our approach can significantly benefit the wind energy industry and contribute to the development of sustainable energy sources.

The organic materials used for stator winding insulation are subject to deterioration from thermal, electrical, and mechanical stresses. Stator winding insulation breakdown due to excessive thermal stress is one of the major causes of electric machine failures; therefore, prevention of such a failure is crucial for increasing machine reliability and minimizing financial loss due to motor failure. This work focuses on the development of an efficient and reliable stator winding temperature estimation scheme for small to medium size mains-fed induction machines. The motivation for the stator winding temperature estimation is to develop a sensorless temperature monitoring scheme and provide an accurate temperature estimate that is capable of responding to the changes in the motors cooling capability. A discussion on the two major types of temperature estimation techniques, thermal model-based and parameter-based temperature techniques, reveals that neither method can protect motors without sacrificing the estimation accuracy or motor performance. Based on the evaluation of the advantages and disadvantages of these two types of temperature estimation techniques, a new online stator winding temperature estimation scheme for small to medium size mains-fed induction machines is proposed in this work. The new stator winding temperature estimation scheme is based on a hybrid thermal model. By correlating the rotor temperature with the stator temperature, the hybrid thermal model unifies the thermal model-based and the parameter-based temperature estimation techniques. Experimental results validate the proposed scheme for stator winding temperature monitoring. The entire algorithm is fast, efficient and reliable, making it suitable for implementation in real time stator winding temperature monitoring.

Energy usage evaluation and condition monitoring for electric machines are important in industry for overall energy savings. Traditionally these functions are realized only for large motors in wired systems formed by communication cables and various types of sensors. The unique characteristics of the wireless sensor networks (WSN) make them the ideal wireless structure for low-cost energy management in industrial plants. This work focuses on developing nonintrusive motor-efficiency-estimation methods, which are essential in the wireless motor-energy-management systems in a WSN architecture that is capable of improving overall energy savings in U.S. industry. This work starts with an investigation of existing motor-efficiency-evaluation methods. Based on the findings, a general approach of developing nonintrusive efficiency-estimation methods is proposed, incorporating sensorless rotor-speed detection, stator-resistance estimation, and loss estimation techniques. Following this approach, two new methods are proposed for estimating the efficiencies of in-service induction motors, using air-gap torque estimation and a modified induction motor equivalent circuit, respectively. The experimental results show that both methods achieve accurate efficiency estimates within ¡À2-3% errors under normal load conditions, using only a few cycles of input voltages and currents. The analytical results obtained from error analysis agree well with the experimental results. Using the proposed efficiency-estimation methods, a closed-loop motor-energy-management scheme for industrial plants with a WSN architecture is proposed. Besides the energy-usage-evaluation algorithms, this scheme also incorporates various sensorless current-based motor-condition-monitoring algorithms. A uniform data interface is defined to seamlessly integrate these energy-evaluation and condition-monitoring algorithms. Prototype wireless sensor devices are designed and implemented to satisfy the specific needs of motor energy management. A WSN test bed is implemented. The applicability of the proposed scheme is validated from the experimental results using multiple motors with different physical configurations under various load conditions. To demonstrate the validity of the measured and estimated motor efficiencies in the experiments presented in this work, an in-depth error analysis on motor efficiency measurement and estimation is conducted, using maximum error estimation, worst-case error estimation, and realistic error estimation techniques. The conclusions, contributions, and recommendations are summarized at the end.